Conversion from Red to Blue Photoluminescence in Alcohol Dispersions of Alkyl-Capped Silicon Nanoparticles: Insight into the Origins of Visible Photoluminescence in Colloidal Nanocrystalline Silicon
Visibly emissive silicon nanoparticles (Si NPs) were obtained via annealing of (HSiO1.5) n polymer, followed by chemical etching. The hydride-terminated Si NPs (H-Si NPs) were surface-functionalized via thermal hydrosilylation with 1-decene and were dispersed in straight chain alcohols varying in ca...
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| Published in: | Journal of physical chemistry. C Vol. 119; no. 17; pp. 9595 - 9608 |
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| Main Authors: | , , , , , , , |
| Format: | Journal Article |
| Language: | English |
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American Chemical Society
30-04-2015
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| Abstract | Visibly emissive silicon nanoparticles (Si NPs) were obtained via annealing of (HSiO1.5) n polymer, followed by chemical etching. The hydride-terminated Si NPs (H-Si NPs) were surface-functionalized via thermal hydrosilylation with 1-decene and were dispersed in straight chain alcohols varying in carbon chain length (C1–C10). The initial red photoluminescence (PL) (λmax,em ∼580 nm) observed from hexane dispersions of the decane-terminated Si NPs (dec-Si NPs) became weaker upon exposure to alcohols smaller than a minimum chain length, commensurate with appearance of strong, blue PL (λmax,em ∼450 nm). A suite of spectroscopic and microscopic techniques was employed to study and correlate the change in Si NP PL with composition and/or size changes to the Si NPs. The results of these studies support that the conversion from red to blue PL originates from dangling bond defect passivation by small alcohol molecules, resulting in an enhanced blue/red PL ratio. The dangling bond defect (Si•) is supported by reactivity studies of H-Si NPs with the stable radical (2,2,6,6-tetramethylpiperidin-1-yl)oxy (TEMPO) and with n-alkanes. We discuss these experimental results in light of current hypotheses about the origins of Si NP visible light emission, which we demonstrate is markedly influenced by the Si NP surface chemistry. An energy level diagram is proposed to account for the spectral and dynamic features observed, in which the role of surface states is highlighted. |
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| AbstractList | Visibly emissive silicon nanoparticles (Si NPs) were obtained via annealing of (HSiO1.5) n polymer, followed by chemical etching. The hydride-terminated Si NPs (H-Si NPs) were surface-functionalized via thermal hydrosilylation with 1-decene and were dispersed in straight chain alcohols varying in carbon chain length (C1–C10). The initial red photoluminescence (PL) (λmax,em ∼580 nm) observed from hexane dispersions of the decane-terminated Si NPs (dec-Si NPs) became weaker upon exposure to alcohols smaller than a minimum chain length, commensurate with appearance of strong, blue PL (λmax,em ∼450 nm). A suite of spectroscopic and microscopic techniques was employed to study and correlate the change in Si NP PL with composition and/or size changes to the Si NPs. The results of these studies support that the conversion from red to blue PL originates from dangling bond defect passivation by small alcohol molecules, resulting in an enhanced blue/red PL ratio. The dangling bond defect (Si•) is supported by reactivity studies of H-Si NPs with the stable radical (2,2,6,6-tetramethylpiperidin-1-yl)oxy (TEMPO) and with n-alkanes. We discuss these experimental results in light of current hypotheses about the origins of Si NP visible light emission, which we demonstrate is markedly influenced by the Si NP surface chemistry. An energy level diagram is proposed to account for the spectral and dynamic features observed, in which the role of surface states is highlighted. |
| Author | Radlinger, Christine M Manhat, Beth A Ellison, Rylie J Goforth, Andrea M DeBenedetti, William J. I Zhang, Jin Z Chiu, Sheng-Kuei Shi, Jianying |
| AuthorAffiliation | Department of Chemistry Department of Chemistry and Biochemistry University of California Portland State University Sun Yat-sen University School of Chemistry and Chemical Engineering |
| AuthorAffiliation_xml | – name: Sun Yat-sen University – name: University of California – name: Department of Chemistry – name: School of Chemistry and Chemical Engineering – name: Portland State University – name: Department of Chemistry and Biochemistry |
| Author_xml | – sequence: 1 givenname: William J. I surname: DeBenedetti fullname: DeBenedetti, William J. I – sequence: 2 givenname: Sheng-Kuei surname: Chiu fullname: Chiu, Sheng-Kuei – sequence: 3 givenname: Christine M surname: Radlinger fullname: Radlinger, Christine M – sequence: 4 givenname: Rylie J surname: Ellison fullname: Ellison, Rylie J – sequence: 5 givenname: Beth A surname: Manhat fullname: Manhat, Beth A – sequence: 6 givenname: Jin Z surname: Zhang fullname: Zhang, Jin Z – sequence: 7 givenname: Jianying surname: Shi fullname: Shi, Jianying email: shijying@mail.sysu.edu.cn – sequence: 8 givenname: Andrea M surname: Goforth fullname: Goforth, Andrea M email: agoforth@pdx.edu |
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| Cites_doi | 10.1021/jo101589h 10.1021/cm0519636 10.1021/nl0347334 10.1021/ja002956f 10.1002/adma.200602752 10.1021/ja300270w 10.1038/nnano.2008.7 10.1038/nnano.2010.236 10.1002/smll.200800677 10.1103/PhysRevB.60.2704 10.1209/0295-5075/91/26001 10.1063/1.114135 10.1039/c0cc02609c 10.1021/la0509394 10.1039/b902671a 10.1103/PhysRevB.83.155327 10.1021/cr000064s 10.1063/1.1725370 10.1038/nmeth.1248 10.1016/S1386-9477(00)00190-9 10.1021/jp8018606 10.1021/nn1005182 10.1021/ja409657y 10.1063/1.555698 10.1021/cm0602803 10.1021/jp971091y 10.1063/1.103561 10.1155/2009/815734 10.1007/978-1-4757-0961-2 10.1063/1.366608 10.1002/adfm.200801548 10.1021/nl0492436 10.1021/jp070908c 10.1021/cm200270d 10.1021/jp963192m 10.1021/jp054565z 10.1038/nmat2611 10.1039/b919412f 10.1103/PhysRevB.53.16338 10.1021/cm902028q 10.1021/bc700373y 10.1021/jp992298p 10.1063/1.115898 10.1063/1.1485302 10.1021/jp802095j 10.1039/C3CS60353A 10.1021/nn4000644 10.1021/jp2075836 10.1103/PhysRevLett.80.3803 10.1103/PhysRevB.49.16845 10.1021/jp960806e 10.1002/pssa.201200273 10.1021/la8024827 10.1021/nl400570p 10.1021/cm2032866 10.1002/adma.200801642 10.1103/PhysRevB.54.2548 10.1038/353335a0 10.1039/c2nr33170e 10.1021/cm5008125 10.1103/PhysRevB.75.033303 10.1897/07-637.1 10.1166/jnn.2008.18159 10.1557/jmr.2012.377 10.1016/S0022-3093(97)00437-7 10.1002/anie.200501256 10.1073/pnas.1316755110 10.1103/PhysRevB.42.9664 10.1038/nmat2398 10.1016/j.chembiol.2005.11.002 10.1021/jp002340c |
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| References | Barbagiovanni E. G. (ref58/cit58) 2012; 111 Godefroo S. (ref34/cit34) 2008; 3 Bradley D. (ref46/cit46) 2010; 75 Choi J. (ref3/cit3) 2008; 19 Kang Z. H. (ref26/cit26) 2009; 21 Gupta A. (ref20/cit20) 2009; 19 Mariotti D. (ref37/cit37) 2013; 5 Michalak D. J. (ref60/cit60) 2010; 9 Hua F. J. (ref25/cit25) 2005; 21 Li Z. F. (ref4/cit4) 2004; 4 Cooke D. W. (ref40/cit40) 1996; 68 Hessel C. M. (ref21/cit21) 2012; 24 Chatillon C. (ref73/cit73) 1975; 280 Shluger A. (ref33/cit33) 1990; 42 Hessel C. M. (ref51/cit51) 2007; 111 Park J. H. (ref5/cit5) 2009; 8 Dasog M. (ref30/cit30) 2013; 7 Buriak J. M. (ref48/cit48) 2002; 102 Liu S. M. (ref54/cit54) 2006; 18 Huber K. P. (ref72/cit72) 1979 Yang S. K. (ref29/cit29) 2011; 115 van Buuren T. (ref56/cit56) 1998; 80 Warner J. H. (ref67/cit67) 2005; 109 ref53/cit53 Henderson E. J. (ref18/cit18) 2009; 21 Trwoga P. F. (ref57/cit57) 1998; 83 Eberl K. (ref1/cit1) 2001; 9 Hessel C. M. (ref19/cit19) 2006; 18 Hessel C. M. (ref50/cit50) 2008; 112 Heintz A. S. (ref63/cit63) 2007; 19 Warner J. H. (ref64/cit64) 2005; 44 ref49/cit49 Manhat B. A. (ref27/cit27) 2011; 23 Kusova K. (ref62/cit62) 2010; 4 Lockwood R. (ref44/cit44) 2014; 26 Chiu S. K. (ref47/cit47) 2013; 28 Canham L. T. (ref16/cit16) 1990; 57 Norris D. J. (ref8/cit8) 1996; 53 Germanenko I. N. (ref41/cit41) 2001; 105 Pedley J. B. (ref75/cit75) 1983; 12 Trukhin A. N. (ref32/cit32) 1998; 223 Wilcoxon J. P. (ref65/cit65) 1999; 60 ref6/cit6 Wolf O. (ref22/cit22) 2013; 13 Dabbousi B. O. (ref7/cit7) 1997; 101 Sweryda-Krawiec B. (ref45/cit45) 1996; 100 Tsay J. M. (ref13/cit13) 2005; 12 Bouldin J. L. (ref12/cit12) 2008; 27 Derfus A. M. (ref11/cit11) 2004; 4 Thissen P. (ref61/cit61) 2012; 134 de Boer W. D. A. M. (ref39/cit39) 2010; 5 Shen P. (ref24/cit24) 2010; 20 Cullis A. G. (ref15/cit15) 1991; 353 Qin G. G. (ref31/cit31) 1996; 54 Verhaegen G. (ref74/cit74) 1964; 40 Kelly J. A. (ref52/cit52) 2010; 46 ref76/cit76 Cheng X. Y. (ref14/cit14) 2014; 43 Sweryda-Krawiec B. (ref42/cit42) 1999; 103 Holmes J. D. (ref23/cit23) 2001; 123 Anas A. (ref10/cit10) 2008; 112 Kanemitsu Y. (ref36/cit36) 1994; 49 Liu S. M. (ref38/cit38) 2008; 8 Pasternack R. M. (ref59/cit59) 2008; 24 Resch-Genger U. (ref9/cit9) 2008; 5 Dohnalova K. (ref35/cit35) 2013; 2 Yang Z. Y. (ref71/cit71) 2013; 135 Lin S. W. (ref68/cit68) 2009; 5 Dasog M. (ref28/cit28) 2012; 209 Rosso-Vasic M. (ref66/cit66) 2009; 19 Das A. (ref2/cit2) 2013; 110 Li S.-T. (ref69/cit69) 1997; 101 ref70/cit70 Ledoux G. (ref17/cit17) 2002; 80 Rehm J. M. (ref43/cit43) 1995; 66 Sattler K. (ref55/cit55) 2002; 5 |
| References_xml | – volume: 75 start-page: 8351 year: 2010 ident: ref46/cit46 publication-title: J. Org. Chem. doi: 10.1021/jo101589h contributor: fullname: Bradley D. – volume: 18 start-page: 637 year: 2006 ident: ref54/cit54 publication-title: Chem. Mater. doi: 10.1021/cm0519636 contributor: fullname: Liu S. M. – volume: 4 start-page: 11 year: 2004 ident: ref11/cit11 publication-title: Nano Lett. doi: 10.1021/nl0347334 contributor: fullname: Derfus A. M. – ident: ref70/cit70 – volume: 123 start-page: 3743 year: 2001 ident: ref23/cit23 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja002956f contributor: fullname: Holmes J. D. – volume: 19 start-page: 3984 year: 2007 ident: ref63/cit63 publication-title: Adv. Mater. doi: 10.1002/adma.200602752 contributor: fullname: Heintz A. S. – volume: 134 start-page: 8869 year: 2012 ident: ref61/cit61 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja300270w contributor: fullname: Thissen P. – volume: 3 start-page: 174 year: 2008 ident: ref34/cit34 publication-title: Nat. Nanotechnol. doi: 10.1038/nnano.2008.7 contributor: fullname: Godefroo S. – volume: 5 start-page: 878 year: 2010 ident: ref39/cit39 publication-title: Nat. Nanotechnol. doi: 10.1038/nnano.2010.236 contributor: fullname: de Boer W. D. A. M. – volume: 5 start-page: 72 year: 2009 ident: ref68/cit68 publication-title: Small doi: 10.1002/smll.200800677 contributor: fullname: Lin S. W. – volume: 60 start-page: 2704 year: 1999 ident: ref65/cit65 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.60.2704 contributor: fullname: Wilcoxon J. P. – ident: ref53/cit53 doi: 10.1209/0295-5075/91/26001 – volume: 66 start-page: 3669 year: 1995 ident: ref43/cit43 publication-title: Appl. Phys. Lett. doi: 10.1063/1.114135 contributor: fullname: Rehm J. M. – volume: 2 start-page: 1 issue: 47 year: 2013 ident: ref35/cit35 publication-title: Light Sci. Appl. contributor: fullname: Dohnalova K. – volume: 46 start-page: 8704 year: 2010 ident: ref52/cit52 publication-title: Chem. Commun. doi: 10.1039/c0cc02609c contributor: fullname: Kelly J. A. – volume: 21 start-page: 6054 year: 2005 ident: ref25/cit25 publication-title: Langmuir doi: 10.1021/la0509394 contributor: fullname: Hua F. J. – volume: 19 start-page: 5926 year: 2009 ident: ref66/cit66 publication-title: J. Mater. Chem. doi: 10.1039/b902671a contributor: fullname: Rosso-Vasic M. – ident: ref49/cit49 doi: 10.1103/PhysRevB.83.155327 – volume: 102 start-page: 1271 year: 2002 ident: ref48/cit48 publication-title: Chem. Rev. doi: 10.1021/cr000064s contributor: fullname: Buriak J. M. – volume: 40 start-page: 1622 year: 1964 ident: ref74/cit74 publication-title: J. Chem. Phys. doi: 10.1063/1.1725370 contributor: fullname: Verhaegen G. – volume: 5 start-page: 763 year: 2008 ident: ref9/cit9 publication-title: Nat. Methods doi: 10.1038/nmeth.1248 contributor: fullname: Resch-Genger U. – volume: 9 start-page: 164 year: 2001 ident: ref1/cit1 publication-title: Physica E doi: 10.1016/S1386-9477(00)00190-9 contributor: fullname: Eberl K. – volume: 112 start-page: 10005 year: 2008 ident: ref10/cit10 publication-title: J. Phys. Chem. B doi: 10.1021/jp8018606 contributor: fullname: Anas A. – volume: 4 start-page: 4495 year: 2010 ident: ref62/cit62 publication-title: ACS Nano doi: 10.1021/nn1005182 contributor: fullname: Kusova K. – volume: 135 start-page: 17595 year: 2013 ident: ref71/cit71 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja409657y contributor: fullname: Yang Z. Y. – volume: 12 start-page: 967 year: 1983 ident: ref75/cit75 publication-title: J. Phys. Chem. Ref. Data doi: 10.1063/1.555698 contributor: fullname: Pedley J. B. – volume: 18 start-page: 6139 year: 2006 ident: ref19/cit19 publication-title: Chem. Mater. doi: 10.1021/cm0602803 contributor: fullname: Hessel C. M. – volume: 101 start-page: 9463 year: 1997 ident: ref7/cit7 publication-title: J. Phys. Chem. B doi: 10.1021/jp971091y contributor: fullname: Dabbousi B. O. – volume: 57 start-page: 1046 year: 1990 ident: ref16/cit16 publication-title: Appl. Phys. Lett. doi: 10.1063/1.103561 contributor: fullname: Canham L. T. – ident: ref6/cit6 doi: 10.1155/2009/815734 – volume-title: Molecular Spectra and Molecular Structure Constants of Diatomic Molecules year: 1979 ident: ref72/cit72 doi: 10.1007/978-1-4757-0961-2 contributor: fullname: Huber K. P. – volume: 83 start-page: 3789 year: 1998 ident: ref57/cit57 publication-title: J. Appl. Phys. doi: 10.1063/1.366608 contributor: fullname: Trwoga P. F. – volume: 19 start-page: 696 year: 2009 ident: ref20/cit20 publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.200801548 contributor: fullname: Gupta A. – volume: 4 start-page: 1463 year: 2004 ident: ref4/cit4 publication-title: Nano Lett. doi: 10.1021/nl0492436 contributor: fullname: Li Z. F. – volume: 111 start-page: 6956 year: 2007 ident: ref51/cit51 publication-title: J. Phys. Chem. C doi: 10.1021/jp070908c contributor: fullname: Hessel C. M. – volume: 23 start-page: 2407 year: 2011 ident: ref27/cit27 publication-title: Chem. Mater. doi: 10.1021/cm200270d contributor: fullname: Manhat B. A. – volume: 280 start-page: 1505 year: 1975 ident: ref73/cit73 publication-title: C. R. Seances Acad. Sci., Ser. C contributor: fullname: Chatillon C. – volume: 101 start-page: 1794 year: 1997 ident: ref69/cit69 publication-title: J. Phys. Chem. B doi: 10.1021/jp963192m contributor: fullname: Li S.-T. – volume: 109 start-page: 19064 year: 2005 ident: ref67/cit67 publication-title: J. Phys. Chem. B doi: 10.1021/jp054565z contributor: fullname: Warner J. H. – volume: 111 start-page: 1 issue: 034307 year: 2012 ident: ref58/cit58 publication-title: J. Appl. Phys. contributor: fullname: Barbagiovanni E. G. – volume: 9 start-page: 266 year: 2010 ident: ref60/cit60 publication-title: Nat. Mater. doi: 10.1038/nmat2611 contributor: fullname: Michalak D. J. – volume: 20 start-page: 1669 year: 2010 ident: ref24/cit24 publication-title: J. Mater. Chem. doi: 10.1039/b919412f contributor: fullname: Shen P. – volume: 53 start-page: 16338 year: 1996 ident: ref8/cit8 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.53.16338 contributor: fullname: Norris D. J. – volume: 21 start-page: 5426 year: 2009 ident: ref18/cit18 publication-title: Chem. Mater. doi: 10.1021/cm902028q contributor: fullname: Henderson E. J. – volume: 19 start-page: 680 year: 2008 ident: ref3/cit3 publication-title: Bioconjugate Chem. doi: 10.1021/bc700373y contributor: fullname: Choi J. – volume: 103 start-page: 9524 year: 1999 ident: ref42/cit42 publication-title: J. Phys. Chem. B doi: 10.1021/jp992298p contributor: fullname: Sweryda-Krawiec B. – volume: 68 start-page: 1663 year: 1996 ident: ref40/cit40 publication-title: Appl. Phys. Lett. doi: 10.1063/1.115898 contributor: fullname: Cooke D. W. – volume: 80 start-page: 4834 year: 2002 ident: ref17/cit17 publication-title: Appl. Phys. Lett. doi: 10.1063/1.1485302 contributor: fullname: Ledoux G. – volume: 112 start-page: 14247 year: 2008 ident: ref50/cit50 publication-title: J. Phys. Chem. C doi: 10.1021/jp802095j contributor: fullname: Hessel C. M. – volume: 43 start-page: 2680 year: 2014 ident: ref14/cit14 publication-title: Chem. Soc. Rev. doi: 10.1039/C3CS60353A contributor: fullname: Cheng X. Y. – volume: 7 start-page: 2676 year: 2013 ident: ref30/cit30 publication-title: ACS Nano doi: 10.1021/nn4000644 contributor: fullname: Dasog M. – volume: 115 start-page: 21056 year: 2011 ident: ref29/cit29 publication-title: J. Phys. Chem. C doi: 10.1021/jp2075836 contributor: fullname: Yang S. K. – volume: 80 start-page: 3803 year: 1998 ident: ref56/cit56 publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.80.3803 contributor: fullname: van Buuren T. – volume: 49 start-page: 16845 year: 1994 ident: ref36/cit36 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.49.16845 contributor: fullname: Kanemitsu Y. – volume: 100 start-page: 13776 year: 1996 ident: ref45/cit45 publication-title: J. Phys. Chem. doi: 10.1021/jp960806e contributor: fullname: Sweryda-Krawiec B. – volume: 209 start-page: 1844 year: 2012 ident: ref28/cit28 publication-title: Phys. Status Solidi A doi: 10.1002/pssa.201200273 contributor: fullname: Dasog M. – volume: 24 start-page: 12963 year: 2008 ident: ref59/cit59 publication-title: Langmuir doi: 10.1021/la8024827 contributor: fullname: Pasternack R. M. – volume: 13 start-page: 2516 year: 2013 ident: ref22/cit22 publication-title: Nano Lett. doi: 10.1021/nl400570p contributor: fullname: Wolf O. – volume: 5 volume-title: Nanomaterials and Magnetic Thin Films year: 2002 ident: ref55/cit55 contributor: fullname: Sattler K. – volume: 24 start-page: 393 year: 2012 ident: ref21/cit21 publication-title: Chem. Mater. doi: 10.1021/cm2032866 contributor: fullname: Hessel C. M. – volume: 21 start-page: 661 year: 2009 ident: ref26/cit26 publication-title: Adv. Mater. doi: 10.1002/adma.200801642 contributor: fullname: Kang Z. H. – volume: 54 start-page: 2548 year: 1996 ident: ref31/cit31 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.54.2548 contributor: fullname: Qin G. G. – volume: 353 start-page: 335 year: 1991 ident: ref15/cit15 publication-title: Nature doi: 10.1038/353335a0 contributor: fullname: Cullis A. G. – volume: 5 start-page: 1385 year: 2013 ident: ref37/cit37 publication-title: Nanoscale doi: 10.1039/c2nr33170e contributor: fullname: Mariotti D. – volume: 26 start-page: 5467 year: 2014 ident: ref44/cit44 publication-title: Chem. Mater. doi: 10.1021/cm5008125 contributor: fullname: Lockwood R. – ident: ref76/cit76 doi: 10.1103/PhysRevB.75.033303 – volume: 27 start-page: 1958 year: 2008 ident: ref12/cit12 publication-title: Environ. Toxicol. Chem. doi: 10.1897/07-637.1 contributor: fullname: Bouldin J. L. – volume: 8 start-page: 1110 year: 2008 ident: ref38/cit38 publication-title: J. Nanosci. Nanotechnol. doi: 10.1166/jnn.2008.18159 contributor: fullname: Liu S. M. – volume: 28 start-page: 216 year: 2013 ident: ref47/cit47 publication-title: J. Mater. Res. doi: 10.1557/jmr.2012.377 contributor: fullname: Chiu S. K. – volume: 223 start-page: 114 year: 1998 ident: ref32/cit32 publication-title: J. Non-Cryst. Solids doi: 10.1016/S0022-3093(97)00437-7 contributor: fullname: Trukhin A. N. – volume: 44 start-page: 4550 year: 2005 ident: ref64/cit64 publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.200501256 contributor: fullname: Warner J. H. – volume: 110 start-page: 16716 year: 2013 ident: ref2/cit2 publication-title: Proc. Natl. Acad. Sci. U.S.A. doi: 10.1073/pnas.1316755110 contributor: fullname: Das A. – volume: 42 start-page: 9664 year: 1990 ident: ref33/cit33 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.42.9664 contributor: fullname: Shluger A. – volume: 8 start-page: 331 year: 2009 ident: ref5/cit5 publication-title: Nat. Mater. doi: 10.1038/nmat2398 contributor: fullname: Park J. H. – volume: 12 start-page: 1159 year: 2005 ident: ref13/cit13 publication-title: Chem. Biol. doi: 10.1016/j.chembiol.2005.11.002 contributor: fullname: Tsay J. M. – volume: 105 start-page: 59 year: 2001 ident: ref41/cit41 publication-title: J. Phys. Chem. B doi: 10.1021/jp002340c contributor: fullname: Germanenko I. N. |
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| Snippet | Visibly emissive silicon nanoparticles (Si NPs) were obtained via annealing of (HSiO1.5) n polymer, followed by chemical etching. The hydride-terminated Si NPs... |
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| Title | Conversion from Red to Blue Photoluminescence in Alcohol Dispersions of Alkyl-Capped Silicon Nanoparticles: Insight into the Origins of Visible Photoluminescence in Colloidal Nanocrystalline Silicon |
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