Effect of the Number of Methyl Groups on the Cation Affinity of Oxygen, Nitrogen, and Phosphorus Sites of Lewis Bases
The effect of number of CH3 groups (n) on the cation (H+, Li+, Na+, Al+, CH3 +) affinity, polarizability, and dipole moment of 14 simple molecules was investigated. Linear correlations were observed between the polarizabilities and the number of methyl groups. The variations of the cation affinities...
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| Published in: | The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory Vol. 120; no. 45; pp. 9109 - 9116 |
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17-11-2016
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| Abstract | The effect of number of CH3 groups (n) on the cation (H+, Li+, Na+, Al+, CH3 +) affinity, polarizability, and dipole moment of 14 simple molecules was investigated. Linear correlations were observed between the polarizabilities and the number of methyl groups. The variations of the cation affinities and dipole moments with the number of methyl groups (n) were not linear, and a quadratic function was proposed for obtaining a good fit of the experimental data. Also, because the proton affinities (PA), lithium cation affinities (LCA), sodium cation affinities (SCA), aluminum cation affinity (AlCA), and methyl cation affinity (MCA) varied quadratically with polarizabilities (α), a formula of the form [cation affinities] = a + bα + cα2 was proposed. After correction of the PAs, LCAs, SCAs, AlCA, and MCA for the dipole/charge interaction (E μ), linear relationships were observed between the corrected cation affinities and n or α. The contribution of E μ to PA and MCA was small (less than 20%), and its contribution to LCA and SCA was large (>50%). The electrostatic contribution to AlCA was considerable (20–50%); however, it was smaller than the electrostatic contribution to LCA and SCA. |
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| AbstractList | The effect of number of CH
groups (n) on the cation (H
, Li
, Na
, Al
, CH
) affinity, polarizability, and dipole moment of 14 simple molecules was investigated. Linear correlations were observed between the polarizabilities and the number of methyl groups. The variations of the cation affinities and dipole moments with the number of methyl groups (n) were not linear, and a quadratic function was proposed for obtaining a good fit of the experimental data. Also, because the proton affinities (PA), lithium cation affinities (LCA), sodium cation affinities (SCA), aluminum cation affinity (AlCA), and methyl cation affinity (MCA) varied quadratically with polarizabilities (α), a formula of the form [cation affinities] = a + bα + cα
was proposed. After correction of the PAs, LCAs, SCAs, AlCA, and MCA for the dipole/charge interaction (E
), linear relationships were observed between the corrected cation affinities and n or α. The contribution of E
to PA and MCA was small (less than 20%), and its contribution to LCA and SCA was large (>50%). The electrostatic contribution to AlCA was considerable (20-50%); however, it was smaller than the electrostatic contribution to LCA and SCA. The effect of number of CH3 groups (n) on the cation (H+, Li+, Na+, Al+, CH3+) affinity, polarizability, and dipole moment of 14 simple molecules was investigated. Linear correlations were observed between the polarizabilities and the number of methyl groups. The variations of the cation affinities and dipole moments with the number of methyl groups (n) were not linear, and a quadratic function was proposed for obtaining a good fit of the experimental data. Also, because the proton affinities (PA), lithium cation affinities (LCA), sodium cation affinities (SCA), aluminum cation affinity (AlCA), and methyl cation affinity (MCA) varied quadratically with polarizabilities (α), a formula of the form [cation affinities] = a + bα + cα2 was proposed. After correction of the PAs, LCAs, SCAs, AlCA, and MCA for the dipole/charge interaction (Eμ), linear relationships were observed between the corrected cation affinities and n or α. The contribution of Eμ to PA and MCA was small (less than 20%), and its contribution to LCA and SCA was large (>50%). The electrostatic contribution to AlCA was considerable (20-50%); however, it was smaller than the electrostatic contribution to LCA and SCA. The effect of number of CH3 groups (n) on the cation (H+, Li+, Na+, Al+, CH3 +) affinity, polarizability, and dipole moment of 14 simple molecules was investigated. Linear correlations were observed between the polarizabilities and the number of methyl groups. The variations of the cation affinities and dipole moments with the number of methyl groups (n) were not linear, and a quadratic function was proposed for obtaining a good fit of the experimental data. Also, because the proton affinities (PA), lithium cation affinities (LCA), sodium cation affinities (SCA), aluminum cation affinity (AlCA), and methyl cation affinity (MCA) varied quadratically with polarizabilities (α), a formula of the form [cation affinities] = a + bα + cα2 was proposed. After correction of the PAs, LCAs, SCAs, AlCA, and MCA for the dipole/charge interaction (E μ), linear relationships were observed between the corrected cation affinities and n or α. The contribution of E μ to PA and MCA was small (less than 20%), and its contribution to LCA and SCA was large (>50%). The electrostatic contribution to AlCA was considerable (20–50%); however, it was smaller than the electrostatic contribution to LCA and SCA. |
| Author | Gal, Jean-François Valadbeigi, Younes |
| AuthorAffiliation | Université Côte d’Azur, CNRS Islamic Azad University Institut de Chimie de Nice, UMR 7272 Department of Chemistry, Science and Research Branch |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/27934334$$D View this record in MEDLINE/PubMed |
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| CitedBy_id | crossref_primary_10_1007_s11164_017_3101_6 crossref_primary_10_1021_acsomega_8b01644 crossref_primary_10_1080_00268976_2019_1662507 crossref_primary_10_1016_j_comptc_2020_113054 crossref_primary_10_1007_s00894_022_05387_2 crossref_primary_10_1021_acs_jpca_7b04474 crossref_primary_10_1016_j_ijms_2018_06_007 crossref_primary_10_1016_j_cplett_2020_137764 crossref_primary_10_3233_MGC_180257 crossref_primary_10_1016_j_ijms_2020_116389 |
| Cites_doi | 10.1002/qua.24391 10.1021/ed300128y 10.1007/978-1-4899-7588-1 10.1021/cr800364q 10.1021/ja00396a001 10.1021/j100347a014 10.1021/ja00745a016 10.6028/NBS.NSRDS.10 10.1021/jp037594n 10.1201/9781439894620 10.1007/s13361-011-0302-x 10.1021/cr4006654 10.1021/ja00746a049 10.1002/1521-3765(20000818)6:16<2931::AID-CHEM2931>3.0.CO;2-7 10.1021/ja00768a049 10.1021/ja00768a050 10.1016/j.atmosenv.2004.01.019 10.1021/jp9931399 10.1021/jo00267a034 10.1016/j.ijms.2015.12.002 10.1016/S0021-9614(02)00316-6 10.1016/S0009-2614(97)01280-3 10.1063/1.556018 10.1021/jp0554487 10.1039/P29850001583 10.1021/ja00180a047 10.1021/ja9841198 10.3176/chem.2007.3.01 10.1016/j.comptc.2016.07.020 10.1021/ja00792a010 10.1002/9780470171950.ch1 10.1016/S0022-2836(03)00903-3 10.1021/jp4090316 10.1021/jp055219k 10.1002/1098-2787(200005/06)19:3<111::AID-MAS1>3.3.CO;2-B 10.1007/s13361-014-0970-4 10.1021/jo0708902 10.1021/ja00853a050 10.1021/ja00905a001 10.1255/ejms.1321 10.1351/pac199062010017 10.1021/ci0498362 10.1021/jp012291j 10.1002/9781118682883 10.1021/ja00769a081 10.1021/ja00516a006 10.1021/ja00470a024 |
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| References | ref9/cit9 ref45/cit45 ref3/cit3 ref16/cit16 Laurence C. (ref28/cit28) 2010 Frisch M. J. (ref51/cit51) 2009 ref52/cit52 ref23/cit23 ref31/cit31 Meot-Ner M. M. (ref32/cit32) 2014 ref2/cit2 ref34/cit34 ref37/cit37 ref20/cit20 ref48/cit48 ref17/cit17 ref35/cit35 ref53/cit53 ref19/cit19 ref21/cit21 ref42/cit42 ref46/cit46 ref49/cit49 Smith M. B. (ref6/cit6) 2010 ref13/cit13 Drago R. S. (ref1/cit1) 1994 Hunter E. P. L. (ref15/cit15) 2014 Fujii T. (ref10/cit10) 2015 ref24/cit24 ref38/cit38 Aue D. H. (ref43/cit43) 1979 ref50/cit50 ref36/cit36 Burk P. (ref27/cit27) 2007; 56 ref18/cit18 Ellis A. M. (ref8/cit8) 2014 ref11/cit11 ref25/cit25 ref29/cit29 ref39/cit39 ref14/cit14 ref5/cit5 ref40/cit40 ref26/cit26 ref12/cit12 ref41/cit41 ref22/cit22 ref33/cit33 ref4/cit4 ref30/cit30 ref47/cit47 ref44/cit44 ref7/cit7 |
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| Snippet | The effect of number of CH3 groups (n) on the cation (H+, Li+, Na+, Al+, CH3 +) affinity, polarizability, and dipole moment of 14 simple molecules was... The effect of number of CH groups (n) on the cation (H , Li , Na , Al , CH ) affinity, polarizability, and dipole moment of 14 simple molecules was... The effect of number of CH3 groups (n) on the cation (H+, Li+, Na+, Al+, CH3+) affinity, polarizability, and dipole moment of 14 simple molecules was... |
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| Title | Effect of the Number of Methyl Groups on the Cation Affinity of Oxygen, Nitrogen, and Phosphorus Sites of Lewis Bases |
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