Redox reactions in hydrocarbon clastic reservoirs: experimental validation of this mechanism for porosity enhancement
Oil-rock-water reactions in hydrocarbon reservoirs were evaluated experimentally. Hematitic Tensleep Sandstone samples of 10–20 cm 3 were heated with 200 ml of deionized water and 100 ml of petroleum for 3–14 days at 200–360°C. The Tensleep Sandstone samples are mature quartz arenites with 5–25% car...
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| Published in: | Chemical geology Vol. 132; no. 1; pp. 103 - 117 |
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| Main Authors: | , |
| Format: | Journal Article |
| Language: | English |
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Elsevier B.V
30-10-1996
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| Abstract | Oil-rock-water reactions in hydrocarbon reservoirs were evaluated experimentally. Hematitic Tensleep Sandstone samples of 10–20 cm
3 were heated with 200 ml of deionized water and 100 ml of petroleum for 3–14 days at 200–360°C. The Tensleep Sandstone samples are mature quartz arenites with 5–25% carbonate matrix and cement and minor amount of anhydrite pore-fillings.
Results indicate that significant potential exists for redox reactions between oxidized mineral phases and crude oil. Iron oxides (± sulfate) were reduced and hydrocarbons were oxidized to oxygenated organic compounds (such as CO
2 and organic acids). Organic acids generated during the redox reactions partitioned into the system water, dissolving framework grains and cements (primarily carbonates). Original porosity of the samples ranged from 6% to 15%, and increased by ∼ 13–20%, to 7–18%, or more after experimentation. As reactions between hydrocarbons and mineral oxidants proceed, redox reactions occur, under increasingly reducing condition as temperature increases, and result in enhanced sandstone reservoir porosity. |
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| AbstractList | Oil-rock-water reactions in hydrocarbon reservoirs were evaluated experimentally. Hematitic Tensleep Sandstone samples of 10–20 cm
3 were heated with 200 ml of deionized water and 100 ml of petroleum for 3–14 days at 200–360°C. The Tensleep Sandstone samples are mature quartz arenites with 5–25% carbonate matrix and cement and minor amount of anhydrite pore-fillings.
Results indicate that significant potential exists for redox reactions between oxidized mineral phases and crude oil. Iron oxides (± sulfate) were reduced and hydrocarbons were oxidized to oxygenated organic compounds (such as CO
2 and organic acids). Organic acids generated during the redox reactions partitioned into the system water, dissolving framework grains and cements (primarily carbonates). Original porosity of the samples ranged from 6% to 15%, and increased by ∼ 13–20%, to 7–18%, or more after experimentation. As reactions between hydrocarbons and mineral oxidants proceed, redox reactions occur, under increasingly reducing condition as temperature increases, and result in enhanced sandstone reservoir porosity. |
| Author | Surdam, R.C. Shebl, M.A. |
| Author_xml | – sequence: 1 givenname: M.A. surname: Shebl fullname: Shebl, M.A. – sequence: 2 givenname: R.C. surname: Surdam fullname: Surdam, R.C. |
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| Cites_doi | 10.1016/0146-6380(88)90262-8 10.1128/MR.55.2.259-287.1991 10.1180/minmag.1989.053.372.02 10.1098/rsta.1985.0034 10.1016/0883-2927(90)90065-D 10.1016/0016-7037(83)90262-4 10.1130/0016-7606(1969)80[535:ICOMDI]2.0.CO;2 10.1180/minmag.1987.051.362.04 10.1016/0016-7037(87)90128-1 10.1016/0016-7037(93)90541-4 10.1306/74D70466-2B21-11D7-8648000102C1865D |
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A doi: 10.1098/rsta.1985.0034 contributor: fullname: Surdam – volume: 68 start-page: 532 year: 1984 ident: 10.1016/S0009-2541(96)00045-9_BIB21 article-title: Mineral oxidants and porosity enhancement publication-title: Am. Assoc. Pet. Geol. Bull. contributor: fullname: Surdam – start-page: 437 year: 1988 ident: 10.1016/S0009-2541(96)00045-9_BIB5 article-title: The Geochemistry of Natural Water contributor: fullname: Drever – volume: 5 start-page: 687 year: 1990 ident: 10.1016/S0009-2541(96)00045-9_BIB15 article-title: Carboxylic acid anions in formation waters, San Joaquin Basin and Louisiana Gulf Coast, U.S.A. — Implication for clastic diagenesis publication-title: Appl. Geochem. doi: 10.1016/0883-2927(90)90065-D contributor: fullname: MacGowan – start-page: 538 year: 1978 ident: 10.1016/S0009-2541(96)00045-9_BIB25 article-title: Petroleum Formation and Occurrence contributor: fullname: Tissot – volume: 47 start-page: 397 year: 1983 ident: 10.1016/S0009-2541(96)00045-9_BIB11 article-title: Thermal decarboxylation of acetic acid, implications for origin of natural gas publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(83)90262-4 contributor: fullname: Kharaka – volume: 38 start-page: 111 year: 1986 ident: 10.1016/S0009-2541(96)00045-9_BIB12 article-title: Role of organic species dissolved in formation waters from sedimentary basins in mineral diagenesis contributor: fullname: Kharaka – start-page: 628 year: 1975 ident: 10.1016/S0009-2541(96)00045-9_BIB17 article-title: Sedimentary Rocks contributor: fullname: Pettijohn – volume: 80 start-page: 535 year: 1969 ident: 10.1016/S0009-2541(96)00045-9_BIB26 article-title: Iron content of Modern Desert in the Sonoran Desert, A contribution to the origin of Red Beds publication-title: Geol. Soc. Am. Bull. doi: 10.1130/0016-7606(1969)80[535:ICOMDI]2.0.CO;2 contributor: fullname: Walker – year: 1989 ident: 10.1016/S0009-2541(96)00045-9_BIB27 article-title: Hydrocarbon production of the Wind River and Bighorn Basins contributor: fullname: Wyoming Geological Association – volume: 62 start-page: 2441 year: 1978 ident: 10.1016/S0009-2541(96)00045-9_BIB3 article-title: Aliphatic acid anions in oil field waters— implication for origin of natural gas publication-title: Am. Assoc. Pet. Geol. Bull. contributor: fullname: Carothers – volume: 51 start-page: 495 year: 1987 ident: 10.1016/S0009-2541(96)00045-9_BIB6 article-title: Generation of water-soluble organic acids from kerogen during hydrous pyrolysis, implication for porosity development publication-title: Mineral. Mag. doi: 10.1180/minmag.1987.051.362.04 contributor: fullname: Eglinton – year: 1995 ident: 10.1016/S0009-2541(96)00045-9_BIB18 article-title: Geochemical and diagenetic investigations of the Tensleep Sandstone Reservoirs, Bighorn Basin, Wyoming contributor: fullname: Shebl – volume: 51 start-page: 3201 year: 1987 ident: 10.1016/S0009-2541(96)00045-9_BIB10 article-title: Dicarboxylic acids generated by thermal alteration of kerogen and hurnic acids publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(87)90128-1 contributor: fullname: Kawamaura – volume: 57 start-page: 3295 year: 1993 ident: 10.1016/S0009-2541(96)00045-9_BIB8 article-title: Petroleum, oil field waters and authigenic mineral assemblage: are they in metastable equilibrium in hydrocarbon reservoirs? publication-title: Geochim. Cosmochim. Acta doi: 10.1016/0016-7037(93)90541-4 contributor: fullname: Helgeson – volume: 25 start-page: 229 year: 1955 ident: 10.1016/S0009-2541(96)00045-9_BIB24 article-title: Summary of “Concerning some additional aids in studying sedimentary formations”, by M.S. Shvetson publication-title: J. Sediment. Petrol. doi: 10.1306/74D70466-2B21-11D7-8648000102C1865D contributor: fullname: Terry |
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| Title | Redox reactions in hydrocarbon clastic reservoirs: experimental validation of this mechanism for porosity enhancement |
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