Highly Selective Copper-Based Catalysts for Electrochemical Conversion of Carbon Monoxide to Ethylene Using a Gas-Fed Flow Electrolyzer

The perspective of developing two-step CO2 electrolytic systems, combining electroreduction of CO2 to CO and electroreduction of CO to a desired organic compound, requires the availability of catalysts and flow cell electrolyzers to achieve the second step with high selectivity and low overpotential...

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Published in:	ACS catalysis Vol. 12; no. 16; pp. 10285 - 10293
Main Authors:	Duong, Hong Phong, Tran, Ngoc-Huan, Rousse, Gwenaëlle, Zanna, Sandrine, Schreiber, Moritz W., Fontecave, Marc
Format:	Journal Article
Language:	English
Published:	American Chemical Society 19-08-2022
Subjects:	Chemical Sciences Material chemistry CO reduction flow electrolyzer CO2 reduction ethylene Cu-based electrocatalysts
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Abstract	The perspective of developing two-step CO2 electrolytic systems, combining electroreduction of CO2 to CO and electroreduction of CO to a desired organic compound, requires the availability of catalysts and flow cell electrolyzers to achieve the second step with high selectivity and low overpotentials. Here, via optimization of porous dendritic copper materials based on nine different samples, using different acidic conditions for copper electrodeposition and including a calcination step in some cases, we report a unique catalyst that allows, within a gas diffusion electrode and a flow cell, CO electroreduction to ethylene with a very high record faradic efficiency of 78%. Such a system functions with a record half-cell energy efficiency of 40.5%. Based on this value, electrical energy efficiency for CO2 conversion to ethylene can be calculated using literature data for a CO2-to-CO solid oxide electrolysis cell, yielding 37%, the highest value reported so far.
AbstractList	The perspective of developing two-step CO2 electrolytic systems, combining electroreduction of CO2 to CO and electroreduction of CO to a desired organic compound, requires the availability of catalysts and flow cell electrolyzers to achieve the second step with high selectivity and low overpotentials. Here, via optimization of porous dendritic copper materials based on nine different samples, using different acidic conditions for copper electrodeposition and including a calcination step in some cases, we report a unique catalyst that allows, within a gas diffusion electrode and a flow cell, CO electroreduction to ethylene with a very high record faradic efficiency of 78%. Such a system functions with a record half-cell energy efficiency of 40.5%. Based on this value, electrical energy efficiency for CO2 conversion to ethylene can be calculated using literature data for a CO2-to-CO solid oxide electrolysis cell, yielding 37%, the highest value reported so far.
Author	Duong, Hong Phong Rousse, Gwenaëlle Schreiber, Moritz W. Zanna, Sandrine Fontecave, Marc Tran, Ngoc-Huan
AuthorAffiliation	Laboratoire de Chimie du Solide et Energie, FRE 3677 Collège de France, Université Pierre et Marie Curie Laboratoire Laboratoire de Chimie des Processus Biologiques, CNRS UMR 8229
AuthorAffiliation_xml	– name: Laboratoire de Chimie du Solide et Energie, FRE 3677 Collège de France, Université Pierre et Marie Curie – name: Laboratoire Laboratoire de Chimie des Processus Biologiques, CNRS UMR 8229
Author_xml	– sequence: 1 givenname: Hong Phong surname: Duong fullname: Duong, Hong Phong organization: Laboratoire Laboratoire de Chimie des Processus Biologiques, CNRS UMR 8229 – sequence: 2 givenname: Ngoc-Huan surname: Tran fullname: Tran, Ngoc-Huan email: ngoc-huan.tran@college-de-france.fr organization: Laboratoire Laboratoire de Chimie des Processus Biologiques, CNRS UMR 8229 – sequence: 3 givenname: Gwenaëlle orcidid: 0000-0001-8877-0015 surname: Rousse fullname: Rousse, Gwenaëlle organization: Laboratoire de Chimie du Solide et Energie, FRE 3677 Collège de France, Université Pierre et Marie Curie – sequence: 4 givenname: Sandrine surname: Zanna fullname: Zanna, Sandrine – sequence: 5 givenname: Moritz W. surname: Schreiber fullname: Schreiber, Moritz W. – sequence: 6 givenname: Marc orcidid: 0000-0002-8016-4747 surname: Fontecave fullname: Fontecave, Marc email: marc.fontecave@college-de-france.fr organization: Laboratoire Laboratoire de Chimie des Processus Biologiques, CNRS UMR 8229
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Title	Highly Selective Copper-Based Catalysts for Electrochemical Conversion of Carbon Monoxide to Ethylene Using a Gas-Fed Flow Electrolyzer
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