Rhodium-Catalyzed Pauson–Khand Reaction Using a Small-Bite-Angle P‑Stereogenic C 1‑Diphosphine Ligand

The asymmetric Pauson–Khand reaction catalyzed by [Rh­(COD)­(MaxPHOS)]­BF4 is described. Several 1,6-enynes have been chosen as model substrates affording moderate yields and selectivities of up to 86% ee. Besides binap-type ligands, we have demonstrated that the P-stereogenic C 1-symmetry small-bit...

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Bibliographic Details

Published in:	Organometallics Vol. 34; no. 20; pp. 4989 - 4993
Main Authors:	Cristóbal-Lecina, Edgar, Costantino, Andrea R, Grabulosa, Arnald, Riera, Antoni, Verdaguer, Xavier
Format:	Journal Article
Language:	English
Published:	American Chemical Society 26-10-2015
Online Access:	Get full text
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