Unique Applications of para-Hydrogen Matrix Isolation to Spectroscopy and Astrochemistry

Cryogenic solid para-hydrogen (p-H2) exhibits pronounced quantum effects, enabling unique experiments that are typically not possible in noble-gas matrices. The diminished cage effect facilitates the production of free radicals via in situ photolysis or photoinduced reactions. Electron bombardment d...

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Published in:	The journal of physical chemistry letters Vol. 15; no. 45; pp. 11361 - 11373
Main Authors:	Weber, Isabelle, Joshi, Prasad Ramesh, Anderson, David T., Lee, Yuan-Pern
Format:	Journal Article
Language:	English
Published:	American Chemical Society 14-11-2024
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Abstract	Cryogenic solid para-hydrogen (p-H2) exhibits pronounced quantum effects, enabling unique experiments that are typically not possible in noble-gas matrices. The diminished cage effect facilitates the production of free radicals via in situ photolysis or photoinduced reactions. Electron bombardment during deposition readily produces protonated and hydrogenated species, such as polycyclic aromatic hydrocarbons, that are important in astrochemistry. In addition, quantum diffusion delocalizes hydrogen atoms in solid p-H2, allowing efficient H atom reactions with astrochemical species and introducing new concepts in astrochemical models. Some H atom reactions display anomalous temperature behaviors, highlighting the rich chemistry in p-H2. The investigation on quantum diffusion of heavier atoms and molecules is also important for our understanding of the chemistry in interstellar ice. Additionally, matrix shifts of electronic transitions of polycyclic aromatic hydrocarbons in p-H2 are less divergent than those in solid Ne such that systematic measurements in p-H2 might help in the assignment of diffuse interstellar bands.
AbstractList	Cryogenic solid para-hydrogen (p-H2) exhibits pronounced quantum effects, enabling unique experiments that are typically not possible in noble-gas matrices. The diminished cage effect facilitates the production of free radicals via in situ photolysis or photoinduced reactions. Electron bombardment during deposition readily produces protonated and hydrogenated species, such as polycyclic aromatic hydrocarbons, that are important in astrochemistry. In addition, quantum diffusion delocalizes hydrogen atoms in solid p-H2, allowing efficient H atom reactions with astrochemical species and introducing new concepts in astrochemical models. Some H atom reactions display anomalous temperature behaviors, highlighting the rich chemistry in p-H2. The investigation on quantum diffusion of heavier atoms and molecules is also important for our understanding of the chemistry in interstellar ice. Additionally, matrix shifts of electronic transitions of polycyclic aromatic hydrocarbons in p-H2 are less divergent than those in solid Ne such that systematic measurements in p-H2 might help in the assignment of diffuse interstellar bands.Cryogenic solid para-hydrogen (p-H2) exhibits pronounced quantum effects, enabling unique experiments that are typically not possible in noble-gas matrices. The diminished cage effect facilitates the production of free radicals via in situ photolysis or photoinduced reactions. Electron bombardment during deposition readily produces protonated and hydrogenated species, such as polycyclic aromatic hydrocarbons, that are important in astrochemistry. In addition, quantum diffusion delocalizes hydrogen atoms in solid p-H2, allowing efficient H atom reactions with astrochemical species and introducing new concepts in astrochemical models. Some H atom reactions display anomalous temperature behaviors, highlighting the rich chemistry in p-H2. The investigation on quantum diffusion of heavier atoms and molecules is also important for our understanding of the chemistry in interstellar ice. Additionally, matrix shifts of electronic transitions of polycyclic aromatic hydrocarbons in p-H2 are less divergent than those in solid Ne such that systematic measurements in p-H2 might help in the assignment of diffuse interstellar bands. Cryogenic solid para -hydrogen ( p -H 2 ) exhibits pronounced quantum effects, enabling unique experiments that are typically not possible in noble-gas matrices. The diminished cage effect facilitates the production of free radicals via in situ photolysis or photoinduced reactions. Electron bombardment during deposition readily produces protonated and hydrogenated species, such as polycyclic aromatic hydrocarbons, that are important in astrochemistry. In addition, quantum diffusion delocalizes hydrogen atoms in solid p -H 2 , allowing efficient H atom reactions with astrochemical species and introducing new concepts in astrochemical models. Some H atom reactions display anomalous temperature behaviors, highlighting the rich chemistry in p -H 2 . The investigation on quantum diffusion of heavier atoms and molecules is also important for our understanding of the chemistry in interstellar ice. Additionally, matrix shifts of electronic transitions of polycyclic aromatic hydrocarbons in p -H 2 are less divergent than those in solid Ne such that systematic measurements in p -H 2 might help in the assignment of diffuse interstellar bands. Cryogenic solid para-hydrogen (p-H2) exhibits pronounced quantum effects, enabling unique experiments that are typically not possible in noble-gas matrices. The diminished cage effect facilitates the production of free radicals via in situ photolysis or photoinduced reactions. Electron bombardment during deposition readily produces protonated and hydrogenated species, such as polycyclic aromatic hydrocarbons, that are important in astrochemistry. In addition, quantum diffusion delocalizes hydrogen atoms in solid p-H2, allowing efficient H atom reactions with astrochemical species and introducing new concepts in astrochemical models. Some H atom reactions display anomalous temperature behaviors, highlighting the rich chemistry in p-H2. The investigation on quantum diffusion of heavier atoms and molecules is also important for our understanding of the chemistry in interstellar ice. Additionally, matrix shifts of electronic transitions of polycyclic aromatic hydrocarbons in p-H2 are less divergent than those in solid Ne such that systematic measurements in p-H2 might help in the assignment of diffuse interstellar bands.
Author	Anderson, David T. Weber, Isabelle Joshi, Prasad Ramesh Lee, Yuan-Pern
AuthorAffiliation	Department of Chemistry Center for Emergent Functional Matter Science National Yang Ming Chiao Tung University Department of Applied Chemistry and Institute of Molecular Science
AuthorAffiliation_xml	– name: Department of Applied Chemistry and Institute of Molecular Science – name: Department of Chemistry – name: National Yang Ming Chiao Tung University – name: Center for Emergent Functional Matter Science
Author_xml	– sequence: 1 givenname: Isabelle orcidid: 0000-0001-5142-4557 surname: Weber fullname: Weber, Isabelle organization: Department of Applied Chemistry and Institute of Molecular Science – sequence: 2 givenname: Prasad Ramesh orcidid: 0000-0003-0896-4341 surname: Joshi fullname: Joshi, Prasad Ramesh organization: Department of Applied Chemistry and Institute of Molecular Science – sequence: 3 givenname: David T. orcidid: 0000-0002-8959-7661 surname: Anderson fullname: Anderson, David T. email: danderso@uwyo.edu organization: Department of Chemistry – sequence: 4 givenname: Yuan-Pern orcidid: 0000-0001-6418-7378 surname: Lee fullname: Lee, Yuan-Pern email: yplee@nycu.edu.tw organization: National Yang Ming Chiao Tung University
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Snippet	Cryogenic solid para-hydrogen (p-H2) exhibits pronounced quantum effects, enabling unique experiments that are typically not possible in noble-gas matrices.... Cryogenic solid para -hydrogen ( p -H 2 ) exhibits pronounced quantum effects, enabling unique experiments that are typically not possible in noble-gas...
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