Structural Comparison of Iron Tetrapolyvanadate Fe2V4O13 and Iron Polyvanadomolybdate Fe2V3.16Mo0.84O13.42: A New Substitution Mechanism of Molybdenum(VI) for Vanadium(V)
Single crystals of the iron tetrapolyvanadate Fe2V4O13 and the iron polyvanadomolybdate Fe2V3.16Mo0.84O13.42 were grown from Fe2O3/V2O5 and Fe2O3/V2O5/MoO3 melts, respectively. Single-crystal X-ray diffraction revealed that the two structures are closely related. Both contained isolated Fe2O10 octah...
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| Published in: | Inorganic chemistry Vol. 37; no. 26; pp. 6921 - 6927 |
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| Main Authors: | , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
American Chemical Society
28-12-1998
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| Online Access: | Get full text |
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