Critical Descriptor for the Rational Design of Oxide-Based Catalysts in Rechargeable Li–O2 Batteries: Surface Oxygen Density

• Published in: Chemistry of materials
• Main Authors: Zheng, Yongping, Song, Kyeongse, Jung, Jaepyeong, Li, Chenzhe, Heo, Yoon-Uk, Park, Min-Sik, Cho, Maenghyo, Kang, Yong-Mook, Cho, Kyeongjae
• Format: Journal Article
• Language: English
• Published: American Chemical Society 12-05-2015
• ISSN: 0897-4756; 1520-5002
• DOI: 10.1021/acs.chemmater.5b00056

Li–O2 batteries provide high-capacity energy storage, but for aprotic Li–O2 batteries, it is reported that the charge–discharge efficiency is ultimately limited by the crystal growth of insoluble Li2O2 on the porous cathode. Catalysts have been reported to improve the nucleation and morphology of Li2O2, which helps achieve high energy densities. We provide a new insight into the catalytic mechanism of the oxygen reduction reaction (ORR) in aprotic Li–O2 batteriesthe oxygen sites on the surface play a more important role than the exposed metal sitesvia a study based on the density functional theory (DFT) examining α-MnO2 surfaces. Lithium ions from electrolytes are found to interact with the surface oxygen sites and form surface lithium sites, facilitating further growth of Li2O2. A larger number of initial growth points with uniform distribution makes Li2O2 well dispersed, forming small particles, which benefit both the ORR and oxygen evolution reactions (OER). This design concept for oxygen sites has been successfully validated by the real Li–O2 cell experiments with α-MnO2 nanowire cathodes.