Search Results - "van der Vorm, Stefan"

Characterization of glycosyl dioxolenium ions and their role in glycosylation reactions by Hansen, Thomas, Elferink, Hidde, van Hengst, Jacob M. A., Houthuijs, Kas J., Remmerswaal, Wouter A., Kromm, Alexandra, Berden, Giel, van der Vorm, Stefan, Rijs, Anouk M., Overkleeft, Hermen S., Filippov, Dmitri V., Rutjes, Floris P. J. T., van der Marel, Gijsbert A., Martens, Jonathan, Oomens, Jos, Codée, Jeroen D. C., Boltje, Thomas J.

“…Controlling the chemical glycosylation reaction remains the major challenge in the synthesis of oligosaccharides. Though 1,2- trans glycosidic linkages can be…”
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Mapping the Relationship between Glycosyl Acceptor Reactivity and Glycosylation Stereoselectivity by van der Vorm, Stefan, van Hengst, Jacob M. A., Bakker, Marloes, Overkleeft, Herman S., van der Marel, Gijsbert A., Codée, Jeroen D. C.

“…The reactivity of both coupling partners—the glycosyl donor and acceptor—is decisive for the outcome of a glycosylation reaction, in terms of both yield and…”
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Stereoselectivity of Conformationally Restricted Glucosazide Donors by van der Vorm, Stefan, Overkleeft, Herman S, van der Marel, Gijsbert A, Codée, Jeroen D. C

“…Glycosylations of 4,6-tethered glucosazide donors with a panel of model acceptors revealed the effect of acceptor nucleophilicity on the stereoselectivity of…”
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Furanosyl Oxocarbenium Ion Conformational Energy Landscape Maps as a Tool to Study the Glycosylation Stereoselectivity of 2‐Azidofuranoses, 2‐Fluorofuranoses and Methyl Furanosyl Uronates by van der Vorm, Stefan, Hansen, Thomas, van Rijssel, Erwin R., Dekkers, Rolf, Madern, Jerre M., Overkleeft, Herman S., Filippov, Dmitri V., van der Marel, Gijsbert A., Codée, Jeroen D. C.

“…The 3D shape of glycosyl oxocarbenium ions determines their stability and reactivity and the stereochemical course of SN1 reactions taking place on these…”
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Defining the SN1 Side of Glycosylation Reactions: Stereoselectivity of Glycopyranosyl Cations by Hansen, Thomas, Lebedel, Ludivine, Remmerswaal, Wouter A, van der Vorm, Stefan, Wander, Dennis P. A, Somers, Mark, Overkleeft, Herman S, Filippov, Dmitri V, Désiré, Jérôme, Mingot, Agnès, Bleriot, Yves, van der Marel, Gijsbert A, Thibaudeau, Sebastien, Codée, Jeroen D. C

“…The broad application of well-defined synthetic oligosaccharides in glycobiology and glycobiotechnology is largely hampered by the lack of sufficient amounts…”
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Titelbild: Mapping the Relationship between Glycosyl Acceptor Reactivity and Glycosylation Stereoselectivity (Angew. Chem. 27/2018) by van der Vorm, Stefan, van Hengst, Jacob M. A., Bakker, Marloes, Overkleeft, Herman S., van der Marel, Gijsbert A., Codée, Jeroen D. C.

“…Die Stereoselektivität von Glykosylierungen kann ganz zentral von der Reaktivität des Akzeptor‐Glykosids (des Nukleophils in der Reaktion) abhängen. J. D…”
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Mapping the Relationship between Glycosyl Acceptor Reactivity and Glycosylation Stereoselectivity by van der Vorm, Stefan, van Hengst, Jacob M. A., Bakker, Marloes, Overkleeft, Herman S., van der Marel, Gijsbert A., Codée, Jeroen D. C.

“…The reactivity of both coupling partners—the glycosyl donor and acceptor—is decisive for the outcome of a glycosylation reaction, in terms of both yield and…”
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Synthesis of O‑1–O‑6 Substituted Positional Isomers of d‑Glucose–Thioether Ligands and Their Ruthenium Polypyridyl Conjugates by Lameijer, Lucien N, le Roy, Julien, van der Vorm, Stefan, Bonnet, Sylvestre

“…A library of positional isomers of d-glucose (O-1–O-6) as ligands and their 11 light-active ruthenium conjugates has been synthesized. A protecting group…”
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Anomeric Triflates versus Dioxanium Ions: Different Product-Forming Intermediates from 3‑Acyl Benzylidene Mannosyl and Glucosyl Donors by Remmerswaal, Wouter A., Elferink, Hidde, Houthuijs, Kas J., Hansen, Thomas, ter Braak, Floor, Berden, Giel, van der Vorm, Stefan, Martens, Jonathan, Oomens, Jos, van der Marel, Gijsbert A., Boltje, Thomas J., Codée, Jeroen D. C.

“…Minimal structural differences in the structure of glycosyl donors can have a tremendous impact on their reactivity and the stereochemical outcome of their…”
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Synthesis, Reactivity, and Stereoselectivity of 4‑Thiofuranosides by Madern, Jerre M, Hansen, Thomas, van Rijssel, Erwin R, Kistemaker, Hans A.V, van der Vorm, Stefan, Overkleeft, Herman S, van der Marel, Gijsbert A, Filippov, Dmitri V, Codée, Jeroen D.C

“…Thiosugars, sugars that have their endocyclic oxygen substituted for a sulfur atom, have been used as stable bioisosteres of naturally occurring glycans…”
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Mapping the effect of configuration and protecting group pattern on glycosyl acceptor reactivity by van Hengst, Jacob M. A, Hellemons, Rik J. C, Remmerswaal, Wouter A, van de Vrande, Koen N. A, Hansen, Thomas, van der Vorm, Stefan, Overkleeft, Hermen S, van der Marel, Gijsbert A, Codée, Jeroen D. C

“…The reactivity of the acceptor alcohol can have a tremendous influence on the outcome of a glycosylation reaction, both in terms of yield and…”
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Cover Picture: Mapping the Relationship between Glycosyl Acceptor Reactivity and Glycosylation Stereoselectivity (Angew. Chem. Int. Ed. 27/2018) by van der Vorm, Stefan, van Hengst, Jacob M. A., Bakker, Marloes, Overkleeft, Herman S., van der Marel, Gijsbert A., Codée, Jeroen D. C.

“…The stereoselectivity of glycosylation … … reactions can depend critically on the reactivity of the acceptor glycoside (the nucleophile in the reaction). In…”
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Cover Feature: Furanosyl Oxocarbenium Ion Conformational Energy Landscape Maps as a Tool to Study the Glycosylation Stereoselectivity of 2‐Azidofuranoses, 2‐Fluorofuranoses and Methyl Furanosyl Uronates (Chem. Eur. J. 29/2019) by van der Vorm, Stefan, Hansen, Thomas, van Rijssel, Erwin R., Dekkers, Rolf, Madern, Jerre M., Overkleeft, Herman S., Filippov, Dmitri V., van der Marel, Gijsbert A., Codée, Jeroen D. C.

“…Energy maps of the full conformational space of 5‐membered ring glycosyl oxocarbenium ions have been generated to probe the stereoelectronic effects of…”
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Defining the S N 1 Side of Glycosylation Reactions: Stereoselectivity of Glycopyranosyl Cations by Hansen, Thomas, Lebedel, Ludivine, Remmerswaal, Wouter A, van der Vorm, Stefan, Wander, Dennis P A, Somers, Mark, Overkleeft, Herman S, Filippov, Dmitri V, Désiré, Jérôme, Mingot, Agnès, Bleriot, Yves, van der Marel, Gijsbert A, Thibaudeau, Sebastien, Codée, Jeroen D C

“…The broad application of well-defined synthetic oligosaccharides in glycobiology and glycobiotechnology is largely hampered by the lack of sufficient amounts…”
Get full text