Search Results - "van Leeuwen, M. W."
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1
Phosphite-Containing Ligands for Asymmetric Catalysis
Published in Chemical reviews (09-03-2011)“…Van Leeuwen et al examine the use of phosphite-containing ligands for asymmetric catalysis…”
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2
Tunable Asymmetric Catalysis through Ligand Stacking in Chiral Rigid Rods
Published in Journal of the American Chemical Society (27-11-2013)“…Chiral benzene-1,3,5-tricarboxamide (BTA) ligands, comprising one diphenylphosphino group and one or two remote chiral 1-methylheptyl side chains, were…”
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3
Dinuclear Iron Complexes of Iminopyridine-Based Ligands as Selective Cytotoxins for Tumor Cells and Inhibitors of Cancer Cell Migration
Published in Pharmaceutics (01-12-2022)“…A family of dinuclear iron (II) compounds with iminopyridine-based ligands displays selective cytotoxic activity against cancer cell lines. All compounds have…”
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Ortho-Phosphinobenzenesulfonate: A Superb Ligand for Palladium-Catalyzed Coordination–Insertion Copolymerization of Polar Vinyl Monomers
Published in Accounts of chemical research (16-07-2013)“…Ligands, Lewis bases that coordinate to the metal center in a complex, can completely change the catalytic behavior of the metal center. In this Account, we…”
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5
Hydrodeoxygenation Using Magnetic Induction: High‐Temperature Heterogeneous Catalysis in Solution
Published in Angewandte Chemie International Edition (12-08-2019)“…Magnetic heating has recently been demonstrated as an efficient way to perform catalytic reactions after deposition of the heating agent and the catalyst on a…”
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Correlation between the Selectivity and the Structure of an Asymmetric Catalyst Built on a Chirally Amplified Supramolecular Helical Scaffold
Published in Journal of the American Chemical Society (13-04-2016)“…For the first time, supramolecular helical rods composed of an achiral metal complex and a complementary enantiopure monomer provided a good level of…”
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Air-Stable Gold Nanoparticles Ligated by Secondary Phosphine Oxides for the Chemoselective Hydrogenation of Aldehydes: Crucial Role of the Ligand
Published in Journal of the American Chemical Society (12-02-2014)“…The synthesis of air-stable and homogeneous gold nanoparticles (AuNPs) employing tert-butyl(naphthalen-1-yl)phosphine oxide as supporting ligand is described…”
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Air-Stable Gold Nanoparticles Ligated by Secondary Phosphine Oxides as Catalyst for the Chemoselective Hydrogenation of Substituted Aldehydes: a Remarkable Ligand Effect
Published in Journal of the American Chemical Society (24-06-2015)“…Air-stable and homogeneous gold nanoparticles (AuNPs, 1a–5a) ligated by various secondary phosphine oxides (SPOs), [R1R2P(O)H] (R1 = Naph, R2 = t Bu, L1; R1…”
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Palladium Nanoparticles in Allylic Alkylations and Heck Reactions: The Molecular Nature of the Catalyst Studied in a Membrane Reactor
Published in Advanced synthesis & catalysis (03-11-2008)“…A series of palladium nanoparticles stabilized by five chiral sugar‐based oxazolinyl‐phosphite ligands, containing various substituents at the oxazoline and…”
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Soluble Platinum Nanoparticles Ligated by Long‐Chain N‐Heterocyclic Carbenes as Catalysts
Published in Chemistry : a European journal (18-09-2017)“…Soluble platinum nanoparticles (Pt NPs) ligated by two different long‐chain N‐heterocyclic carbenes (LC‐IPr and LC‐IMe) were synthesized and fully…”
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High-Precision Catalysts: Regioselective Hydroformylation of Internal Alkenes by Encapsulated Rhodium Complexes
Published in Journal of the American Chemical Society (06-09-2006)“…We report the formation of high-precision catalysts using encapsulated rhodium complexes. In the current example, the encapsulated rhodium catalyst shows…”
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12
Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation
Published in Chemical reviews (09-08-2000)“…Van Leeuwen et al summarize the effect of the bite angle of bidentate ligands on the catalytic formation of carbon-to-carbon bonds. Their data show that the…”
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13
Iridium versus Iridium: Nanocluster and Monometallic Catalysts Carrying the Same Ligand Behave Differently
Published in Chemistry : a European journal (26-01-2017)“…A specific secondary phosphine oxide (SPO) ligand (tert‐butyl(phenyl)phosphine oxide) was employed to generate two iridium catalysts, an Ir–SPO complex and…”
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Synthesis, Application and Kinetic Studies of Chiral Phosphite‐Oxazoline Palladium Complexes as Active and Selective Catalysts in Intermolecular Heck Reactions
Published in Advanced synthesis & catalysis (17-04-2018)“…This study identifies new phosphite‐oxazoline ligands that have been successfully applied in the palladium‐catalyzed intermolecular asymmetric Heck reaction…”
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Effects of clopidogrel therapy on whole blood platelet aggregation, the Plateletworks® assay and coagulation parameters in cats with asymptomatic hypertrophic cardiomyopathy: a pilot study
Published in The Veterinary quarterly (01-01-2017)“…Background: Although scientific evidence is limited, clopidogrel is frequently used as prophylaxis for arterial thromboembolism in cats with hypertrophic…”
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Phosphinothiolates as Ligands for Polyhydrido Copper Nanoclusters
Published in Chemistry : a European journal (01-12-2014)“…The reaction of [CuI(HSC6H4PPh2)]2 with NaBH4 in CH2Cl2/EtOH led to air‐ and moisture‐stable copper hydride nanoparticles (CuNPs) containing phosphinothiolates…”
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17
Supramolecular catalysis. Part 2: artificial enzyme mimics
Published in Chemical Society reviews (07-03-2014)“…The design of artificial catalysts able to compete with the catalytic proficiency of enzymes is an intense subject of research. Non-covalent interactions are…”
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Secondary Phosphine Oxides: Bifunctional Ligands in Catalysis
Published in ChemCatChem (20-08-2020)“…Metal complexes of secondary phosphine oxides (SPOs) were introduced as homogeneous catalysts in the 1980s for hydroformylation and hydrogenation with platinum…”
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“Clickphine”: A Novel and Highly Versatile P,N Ligand Class via Click Chemistry
Published in Organic letters (20-07-2006)“…A novel P,N-type ligand family (ClickPhine) is disclosed that is easily accessible using the Cu(I)-catalyzed azide−alkyne “click” cycloaddition. A diverse set…”
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New directions in supramolecular transition metal catalysis
Published in Organic & biomolecular chemistry (07-07-2005)“…Supramolecular chemistry has grown into a major scientific field over the last thirty years and has fueled numerous developments at the interfaces with biology…”
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