Search Results - "van Wüllen, Leo"
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Mechanism of Li-Ion Migration in the Superionic Conducting Open-Framework Structure Li6B18(Li3N)1–x (Li2O) x (0 ≤ x ≤ 1)
Published in Journal of physical chemistry. C (26-01-2023)“…Solid lithium-ion conductors are important components for all-solid-state batteries and the knowledge of the mechanism of Li diffusion is an important step in…”
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2
Structural Role of Phosphate in Metaluminous Sodium Aluminosilicate Glasses As Studied by Solid State NMR Spectroscopy
Published in The journal of physical chemistry. B (02-04-2020)“…In this contribution we present a detailed study of the effect of the addition of small to intermediate amounts of P2O5 (up to 7.5 mol %) on the network…”
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3
Structure and Dynamics of LiPON and NaPON Oxynitride Phosphate Glasses by Solid-State NMR
Published in Journal of physical chemistry. C (25-02-2021)“…Oxynitride phosphate glasses are a subfield of phosphate-based glasses, where part of the oxygen of the network has been replaced by nitrogen, in a process…”
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4
Super‐Ionic Conductivity in ω‐Li9TrP4 (Tr = Al, Ga, In) and Lithium Diffusion Pathways in Li9AlP4 Polymorphs
Published in Advanced functional materials (10-11-2022)“…Phosphide‐based compounds are promising materials for solid electrolytes. In recent times, a multiplicity of compounds featuring isolated MP4 (M =…”
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5
Investigation of the chemical changes during the thermal treatment of acrylonitrile‐co‐methyl acrylate‐polymer (polyacrylonitrile‐precursor) focusing on the fate of the methyl acrylate moiety
Published in Journal of applied polymer science (10-05-2022)“…Seventeen samples of acrylonitrile (AN)‐co‐methyl acrylate (MA)‐polymer (MA content 0–11 mol%) are examined. Several selective isotopic labelings are employed…”
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6
Novel Ternary Composite Electrolytes: Li Ion Conducting Ionic Liquids in Silica Glass
Published in Chemistry of materials (09-06-2009)“…In this contribution, we report on a novel composite solid electrolyte material, SiO2/[BMIM]BF4/LiTf ([BMIM]BF4 = 1-butyl-3-methylimidazolium…”
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7
The Color of the Elements: A Combined Experimental and Theoretical Electron Density Study of ScB2C2
Published in Angewandte Chemie International Edition (18-02-2019)“…The chemical or physical control parameters for the onset of superconductivity in MB2C2 hetero‐graphene materials are unclear. This is mainly due to the almost…”
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Syntheses, Crystal Structures, NMR Spectroscopy, and Vibrational Spectroscopy of Sr(PO3F)·H2O and Sr(PO3F)
Published in European journal of inorganic chemistry (01-03-2016)“…Single crystals of Sr(PO3F)·H2O {P21/c, Z = 4, a = 7.4844(2) Å, b = 7.0793(2) Å, c = 8.4265(2) Å, β = 108.696(1)°, V = 422.91(2) Å3, 2391 Fo2, 70 parameters,…”
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9
Long-term entrapment and temperature-controlled-release of SF6 gas in metal–organic frameworks (MOFs)
Published in Beilstein journal of nanotechnology (2019)“…In this work, a metal–organic framework (MOF), namely MFU-4, which is comprised of zinc cations and benzotriazolate ligands, was used to entrap SF6 gas…”
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10
Tribute to Hellmut Eckert
Published in Journal of physical chemistry. C (06-05-2021)Get full text
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11
An advanced NMR protocol for the structural characterization of aluminophosphate glasses
Published in Solid state nuclear magnetic resonance (01-10-2007)“…In this work a combination of complementary advanced solid-state nuclear magnetic resonance (NMR) strategies is employed to analyse the network organization in…”
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12
Enhancement of Li Ion Conductivity by Electrospun Polymer Fibers and Direct Fabrication of Solvent-Free Separator Membranes for Li Ion Batteries
Published in Inorganic chemistry (20-02-2017)“…Poly(ethylene oxide) (PEO)-based polymer fibers, containing different amounts of the conductive salt LiBF4 and the plasticizer succinonitrile, were prepared…”
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13
Fast Ionic Conductivity in the Most Lithium-Rich Phosphidosilicate Li14SiP6
Published in Journal of the American Chemical Society (11-09-2019)“…Solid electrolytes with superionic conductivity are required as a main component for all-solid-state batteries. Here we present a novel solid electrolyte with…”
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14
The First Alkaline‐Earth Fluorooxoborate Ba[B4O6F2]—Characterisation and Doping with Eu2
Published in Chemistry : a European journal (09-01-2018)“…The very first alkaline‐earth fluorooxoborate Ba[B4O6F2] was synthesised by solid state methods starting from Ba(BF4)2, β‐BaB2O4, and B2O3. The crystal…”
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15
Modifying the Properties of Fast Lithium-Ion ConductorsThe Lithium Phosphidotetrelates Li14SiP6, Li14GeP6, and Li14SnP6
Published in Chemistry of materials (25-08-2020)“…A broad repertoire of potential solid-state electrolytes is a prerequisite for the development and optimization of high-energy-density all-solid-state…”
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16
Local Cation Coordination Motifs in Polyphosphazene Based Composite Electrolytes
Published in Chemistry of materials (23-12-2008)“…Solid electrolytes in the system BMEAP/LiTf/Al2O3 (BMEAP = poly[(bis(2-methoxy-ethyl)amino)(2−x)(propylamino) x ]polyphosphazene; x = 0.4, Tf = CF3SO3) were…”
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17
Sn[B2O3F2]—The First Tin Fluorooxoborate as Possible NLO Material
Published in Advanced optical materials (04-09-2018)“…Herein, the crystal structure as well as second‐harmonic‐generation (SHG), thermal and spectroscopic properties of Sn[B2O3F2] (TFB = tin‐fluorooxo‐borate) are…”
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18
Influence of Phosphate on Network Connectivity and Glass Transition in Highly Polymerized Aluminosilicate Glasses
Published in The journal of physical chemistry. B (01-12-2022)“…Melt-derived metaluminous (Al/Na = 1) aluminosilicate glasses in the system SiO2–Al2O3–Na2O–P2O5 were prepared with P2O5 and SiO2 contents varying from 0 to…”
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Phase Separation and Nanocrystallization in KF–ZnF2–SiO2 Glasses: Lessons from Solid-State NMR
Published in The journal of physical chemistry. B (21-02-2019)“…In the present paper, we studied the structural evolution of the glass matrix and formation of crystalline fluoride phases for 15KF–15ZnF2–70SiO2 (glass A) and…”
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Lithium Phosphidogermanates α- and β‑Li8GeP4A Novel Compound Class with Mixed Li+ Ionic and Electronic Conductivity
Published in Chemistry of materials (25-09-2018)“…To utilize all-solid-state batteries as high power and energy density energy storage devices it is necessary to improve the current electrolyte materials and…”
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