Search Results - "de Waal, Bas"
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End Groups of Functionalized Siloxane Oligomers Direct Block-Copolymeric or Liquid-Crystalline Self-Assembly Behavior
Published in Journal of the American Chemical Society (04-05-2016)“…Monodisperse oligodimethylsiloxanes end-functionalized with the hydrogen-bonding ureidopyrimidinone (UPy) motif undergo phase separation between their aromatic…”
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Synthesis and Self-Assembly of Discrete Dimethylsiloxane–Lactic Acid Diblock Co-oligomers: The Dononacontamer and Its Shorter Homologues
Published in Journal of the American Chemical Society (30-03-2016)“…Most of the theoretical and computational descriptions of the phase behavior of block copolymers describe the chain ensembles of perfect and uniform polymers…”
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Polymorphism in the Assembly of Phase-Segregated Block Molecules: Pathway Control to 1D and 2D Nanostructures
Published in Journal of the American Chemical Society (25-09-2019)“…Nanomaterials with highly ordered, one- or two-dimensional molecular morphologies have promising properties for adaptive materials. Here, we present the…”
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Stereocomplexes of Discrete, Isotactic Lactic Acid Oligomers Conjugated with Oligodimethylsiloxanes
Published in Macromolecules (12-02-2019)“…Discrete length block co-oligomers (BCOs) comprised of a crystalline and an amorphous block are a new class of materials that gives highly ordered lamellar…”
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Anchoring Supramolecular Polymers to Human Red Blood Cells by Combining Dynamic Covalent and Non‐Covalent Chemistries
Published in Angewandte Chemie International Edition (21-09-2020)“…Understanding cell/material interactions is essential to design functional cell‐responsive materials. While the scientific literature abounds with formulations…”
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Amplifying (Im)perfection: The Impact of Crystallinity in Discrete and Disperse Block Co-oligomers
Published in Journal of the American Chemical Society (25-10-2017)“…Crystallinity is seldomly utilized as part of the microphase segregation process in ultralow-molecular-weight block copolymers. Here, we show the preparation…”
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Unraveling the Driving Forces in the Self-Assembly of Monodisperse Naphthalenediimide-Oligodimethylsiloxane Block Molecules
Published in ACS nano (25-04-2017)“…Block molecules belong to a rapidly growing research field in materials chemistry in which discrete macromolecular architectures bridge the gap between block…”
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A Versatile Method for the Preparation of Ferroelectric Supramolecular Materials via Radical End-Functionalization of Vinylidene Fluoride Oligomers
Published in Journal of the American Chemical Society (18-05-2016)“…A synthetic method for the end-functionalization of vinylidene fluoride oligomers (OVDF) via a radical reaction between terminal olefins and I-OVDF is…”
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Stimuli‐Responsive Nanostructured Viologen‐Siloxane Materials for Controllable Conductivity
Published in Advanced materials (Weinheim) (01-06-2024)“…Spontaneous phase separation is a promising strategy for the development of novel electronic materials, as the resulting well‐defined morphologies generally…”
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Dispersity under Scrutiny: Phase Behavior Differences between Disperse and Discrete Low Molecular Weight Block Co-Oligomers
Published in ACS macro letters (18-07-2017)“…An experimental study is presented in which we compare the bulk phase behavior of discrete and (partially) disperse diblock co-oligomers (BCOs) with high χ–low…”
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Highly Ordered Supramolecular Materials of Phase‐Separated Block Molecules for Long‐Range Exciton Transport
Published in Advanced materials (Weinheim) (01-06-2023)“…Efficient energy transport over long distances is essential for optoelectronic and light‐harvesting devices. Although self‐assembled nanofibers of organic…”
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Consequences of Molecular Architecture on the Supramolecular Assembly of Discrete Block Co-oligomers
Published in Macromolecules (24-11-2020)“…Supramolecular block copolymers composed of discrete blocks have promising properties for nanotechnology resulting from their ability to combine well-defined…”
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13
Self‐Assembly of Discrete Oligomers of Naphthalenediimides in Bulk and on Surfaces
Published in Chemistry : a European journal (07-02-2024)“…Here, we report on the synthesis of discrete oligomers of alkyl‐bridged naphthalenediimides (NDIs) and study their molecular nanostructures both in bulk, in…”
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Combinatorial Selection Among Geometrical Isomers of Discrete Long-Carbon-Chain Naphthalenediimides Induces Local Order at the Liquid/Solid Interface
Published in ACS nano (27-10-2020)“…We report two families of naphthalenediimides (NDIs) symmetrically functionalized with discrete carbon chains comprising up to 55 carbon atoms (C n -NDI-C n ,…”
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Choline-Functionalized Supramolecular Copolymers: Toward Antimicrobial Activity against Streptococcus pneumoniae
Published in Biomacromolecules (13-12-2021)“…Dynamic binding events are key to arrive at functionality in nature, and these events are often governed by electrostatic or hydrophobic interactions…”
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Thioamides: Versatile Bonds To Induce Directional and Cooperative Hydrogen Bonding in Supramolecular Polymers
Published in Chemistry : a European journal (24-06-2013)“…The amide bond is a versatile functional group and its directional hydrogen‐bonding capabilities are widely applied in, for example, supramolecular chemistry…”
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Nanopatterned Superlattices in Self-Assembled C2-Symmetric Oligodimethylsiloxane-Based Benzene-1,3,5-Tricarboxamides
Published in Chemistry : a European journal (02-01-2015)“…The synthesis of C3‐ and C2‐symmetric benzene‐1,3,5‐tricarboxamides (BTAs) containing well‐defined oligodimethylsiloxane (oDMS) and/or alkyl side chains has…”
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The iterative synthesis of discrete dimethylsiloxane oligomers: A practical guide
Published in Journal of polymer science (2020) (15-06-2021)“…Discrete dimethylsiloxane oligomers are interesting building blocks for the synthesis of high χ–low N block co‐oligomers (BCOs) forming highly organized…”
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A sample preparation method for recovering suppressed analyte ions in MALDI TOF MS
Published in Journal of mass spectrometry. (01-05-2015)“…In matrix‐assisted laser desorption/ionization time‐of‐flight mass spectrometry (MALDI TOF MS), analyte signals can be substantially suppressed by other…”
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Engineering Long-Range Order in Supramolecular Assemblies on Surfaces: The Paramount Role of Internal Double Bonds in Discrete Long-Chain Naphthalenediimides
Published in Journal of the American Chemical Society (26-02-2020)“…Achieving long-range order with surface-supported supramolecular assemblies is one of the pressing challenges in the prospering field of non-covalent surface…”
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