Search Results - "de Vries, Timothy"

Cationic Tricoordinate Boron Intermediates: Borenium Chemistry from the Organic Perspective by De Vries, Timothy S, Prokofjevs, Aleksandrs, Vedejs, Edwin

“…Cationic tricoordinate boron intermediaries are examined, focusing on enantioselective catalysis, chiral borenium irons and Lewis acidity catalysis…”
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Superelectrophilic Intermediates in Nitrogen-Directed Aromatic Borylation by De Vries, Timothy S, Prokofjevs, Aleksandrs, Harvey, Jeremy N, Vedejs, Edwin

“…The first examples of borylation under conditions of borenium ion generation from hydrogen-bridged boron cations are described. The observable H-bridged…”
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Kinetics of the Cationization of Cotton by De Vries, Timothy S, Davies, Dan R, Miller, Michelle C, Cynecki, William A

“…Cationic cotton has a greater affinity for reactive dyes than untreated cotton, providing economic and environmental advantages for the textile industry. The…”
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Lithium Phenolates Solvated by Tetrahydrofuran and 1,2-Dimethoxyethane: Structure Determination Using the Method of Continuous Variation by De Vries, Timothy S, Goswami, Anandarup, Liou, Lara R, Gruver, Jocelyn M, Jayne, Emily, Collum, David B

“…The method of continuous variation in conjunction with 6Li NMR spectroscopy was used to characterize lithium phenolates solvated by tetrahydrofuran and…”
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P‑Directed Borylation of Phenols by Cazorla, Clément, De Vries, Timothy S, Vedejs, Edwin

“…Internal borylation occurs upon activation of aryl di-isopropylphosphinite boranes with HNTf2 to give heterocyclic intermediates that can be reductively…”
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Resolving and Controlling Photoinduced Ultrafast Solvation in the Solid State by Delor, Milan, McCarthy, Dannielle G, Cotts, Benjamin L, Roberts, Trevor D, Noriega, Rodrigo, Devore, David D, Mukhopadhyay, Sukrit, De Vries, Timothy S, Ginsberg, Naomi S

“…Solid-state solvation (SSS) is a solid-state analogue of solvent–solute interactions in the liquid state. Although it could enable exceptionally fine control…”
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Tuning Thermally Activated Delayed Fluorescence Emitter Photophysics through Solvation in the Solid State by Cotts, Benjamin L, McCarthy, Dannielle G, Noriega, Rodrigo, Penwell, Samuel B, Delor, Milan, Devore, David D, Mukhopadhyay, Sukrit, De Vries, Timothy S, Ginsberg, Naomi S

“…Solid-state solvation (SSS) is analogous to liquid-phase solvation but occurs within glassy matrices. Organic solutes with singlet charge transfer (1CT)…”
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Degradation of Hole Transport Materials via Exciton-Driven Cyclization by Bell, Bruce M, Clark, Michael B, Devore, David D, De Vries, Timothy S, Froese, Robert D, Gray, Kaitlyn C, Jackson, David H. K, Kuech, T. F, Na, Hong-Yeop, Kearns, Kenneth L, Lee, Kyung-Joo, Mukhopadhyay, Sukrit, Rachford, Aaron A, Spencer, Liam P, Woodward, W. H. Hunter

“…Organic light-emitting diode (OLED) displays have been an active and intense area of research for well over a decade and have now reached commercial success…”
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Density-preserving projections for large-scale local anomaly detection by de Vries, Timothy, Chawla, Sanjay, Houle, Michael E.

“…Outlier or anomaly detection is a fundamental data mining task with the aim to identify data points, events, transactions which deviate from the norm. The…”
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Azaaldol Condensation of a Lithium Enolate Solvated by N,N,N′,N′-Tetramethylethylenediamine: Dimer-Based 1,2-Addition to Imines by De Vries, Timothy S, Bruneau, Angela M, Liou, Lara R, Subramanian, Hariharaputhiran, Collum, David B

“…The lithium enolate of tert-amylacetate solvated by N,N,N′,N′-tetramethylethylenediamine (TMEDA) is shown to be a doubly chelated dimer. Adding the dimeric…”
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Mechanistic Variations in Ionic Hydrogenation of Unsaturated Phosphine and Amine Boranes by De Vries, Timothy S, Majumder, Supriyo, Sandelin, Angela M, Wang, Guoqiang, Vedejs, Edwin

“…Internal hydride transfer occurs when tethered carbocations are generated from unsaturated phosphine or phosphinite boranes. 3-Methylenecyclohexyl-derived…”
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Electrophilic Activation of Lewis Base Complexes of Borane with Trityl Tetrakis(pentafluorophenyl)borate by De Vries, Timothy S, Vedejs, Edwin

“…Borenium ions do not accumulate under the conditions of hydride abstraction from Lewis base borane complexes (L·BH3) using trityl cation because subsequent…”
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Boron-based TADF emitters with improved OLED device efficiency roll-off and long lifetime by Bell, Bruce M., Clark, Thomas P., De Vries, Timothy S., Lai, Yuming, Laitar, David S., Gallagher, Timothy J., Jeon, Jeong-Hwan, Kearns, Kenneth L., McIntire, Travis, Mukhopadhyay, Sukrit, Na, Hong-Yeop, Paine, Tomas D., Rachford, Aaron A.

“…A class of four-coordinate boron complexes is reported that contain both electron-rich and electron-poor functional groups. Judicious selection of donor and…”
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Finding Local Anomalies in Very High Dimensional Space by de Vries, T, Chawla, S, Houle, M E

“…Time, cost and energy efficiency are critical factors for many data analysis techniques when the size and dimensionality of data is very large. We investigate…”
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