Search Results - "de Lucca Jr, Emilio"

Chemoselective methylene oxidation in aromatic molecules by Zhao, Jinpeng, Nanjo, Takeshi, de Lucca, Emilio C., White, M. Christina

“…Despite significant progress in the development of site-selective aliphatic C–H oxidations over the past decade, the ability to oxidize strong methylene C–H…”
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Enantioselective Synthesis of Phthalides and Isochromanones via Heck–Matsuda Arylation of Dihydrofurans by Kattela, Shivashankar, de Lucca, Emilio C., Correia, Carlos Roque D.

“…In this communication, the enantioselective synthesis of phthalides and isochromanones is described through a new palladium‐catalyzed Heck–Matsuda…”
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Synthetic Analogue of the Natural Product Piperlongumine as a Potent Inhibitor of Breast Cancer Cell Line Migration by Valli, Marilia, Altei, Wanessa, dos Santos, Ricardo, de Lucca Jr, Emilio, Dessoy, Marco, Pioli, Renan, Cotinguiba, Fernando, Cachet, Xavier, Michel, Sylvie, Furlan, Maysa, Dias, Luiz, Andricopulo, Adriano, Bolzani, Vanderlan

“…Piperlongumine is a natural amide alkaloid isolated from several species of Piper and is described in the literature as selectively cytotoxic to several cancer…”
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Remote, Late-Stage Oxidation of Aliphatic C–H Bonds in Amide-Containing Molecules by Nanjo, Takeshi, de Lucca, Emilio C, White, M. Christina

“…Amide-containing molecules are ubiquitous in natural products, pharmaceuticals, and materials science. Due to their intermediate electron-richness, they are…”
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Total Synthesis of (−)-Marinisporolide C by Dias, Luiz C, de Lucca, Emilio C

“…The first total synthesis of (−)-marinisporolide C is described, which establishes unequivocally the relative and absolute configuration of this oxopolyene…”
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Selective Oxidations in the Synthesis of Complex Natural ent-Kauranes and ent-Beyeranes by Santana, Victor C. S., Rocha, Eduardo C. S., Pavan, Julian C. S., Heleno, Vladimir C. G., de Lucca, Emilio C.

“…Syntheses of two natural products derived from the ent-kaurene kaurenoic acid are described for the first time using regio- and diastereoselective oxidations…”
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Total Synthesis of the Oxopolyene Macrolide (−)-Marinisporolide C by Dias, Luiz C., de Lucca, Emílio C.

“…The first total synthesis of (−)-marinisporolide C was performed in 25 steps (longest linear sequence) and an overall yield of 1%. Due to the high degree of…”
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The Role of β-Bulky Substituents in Aldol Reactions of Boron Enolates of Methylketones with Aldehydes: Experimental and Theoretical Studies by DFT Analysis by Dias, Luiz C, de Lucca, Emílio C, Ferreira, Marco A. B, Garcia, Danilo C, Tormena, Cláudio F

“…In this work, we show the influence of the volume of the β-substituents on the levels of 1,5-stereoselectivities of aldol reactions of boron enolates generated…”
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Influence of β-Substituents in Aldol Reactions of Boron Enolates of β-Alkoxy Methylketones by Dias, Luiz C, de Lucca, Emílio C, Ferreira, Marco A. B, Garcia, Danilo C, Tormena, Cláudio F

“…Moderate to good levels of substrate-based 1,5-syn-stereocontrol could be achieved in the boron-mediated aldol reactions of β-tert-butyl methylketones with…”
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Metal-catalyzed asymmetric aldol reactions by Dias, Luiz C., Lucca Jr, Emílio C. de, Ferreira, Marco A. B., Polo, Ellen C.

“…The aldol reaction is one of the most powerful and versatile methods for the construction of C-C bonds. Traditionally, this reaction was developed in a…”
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