Search Results - "de Jesús, Ernesto"

Highly Stable Water-Soluble Platinum Nanoparticles Stabilized by Hydrophilic N-Heterocyclic Carbenes by Baquero, Edwin A., Tricard, Simon, Flores, Juan Carlos, de Jesús, Ernesto, Chaudret, Bruno

“…Controlling the synthesis of stable metal nanoparticles in water is a current challenge in nanochemistry. The strategy presented herein uses sulfonated…”
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Synthesis of Water‐Soluble Palladium Nanoparticles Stabilized by Sulfonated N‐Heterocyclic Carbenes by Asensio, Juan M., Tricard, Simon, Coppel, Yannick, Andrés, Román, Chaudret, Bruno, de Jesús, Ernesto

“…A strategy involving the decomposition of palladium(II) organometallic complexes with sulfonated N‐heterocyclic carbene ligands leads to the formation of…”
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Reversible Single-Electron-Transfer to Oxygen in a Stable N‑Heterocyclic Carbene Palladium(I) Metalloradical by Maties, Georgiana, Gómez-Sal, Pilar, Yebra, Cristina G., Andrés, Román, de Jesús, Ernesto

“…The chemical and electrochemical one-electron oxidation of [Pd­(IPr)2] (1) leads to the formation of mononuclear palladium­(I) complex [Pd­(IPr)2]­[PF6] (2)…”
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Water-Soluble N-Heterocyclic Carbene Platinum(0) Complexes: Recyclable Catalysts for the Hydrosilylation of Alkynes in Water at Room Temperature by Silbestri, Gustavo F, Flores, Juan Carlos, de Jesús, Ernesto

“…The synthesis and characterization of new water-soluble platinum(0) complexes bearing sulfonated N-heterocyclic carbene (NHC) and divinyltetramethylsiloxane…”
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Highly Recoverable Pd(II) Catalysts for the Mizoroki–Heck Reaction Based on N‑Heterocyclic Carbenes and Poly(benzyl ether) Dendrons by Ortiz, Alba, Gómez-Sal, Pilar, Flores, Juan C, de Jesús, Ernesto

“…Two series of bis­(imidazolylidene)­palladium complexes of general formula [PdBr2(NHC)2] have been prepared. The molecular weight of the complexes was enlarged…”
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Dendrimers : Solutions For Catalyst Separation and Recycling-A Review by DE JESUS, Ernesto, FLORES, Juan C

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Turnover Numbers and Soluble Metal Nanoparticles by Umpierre, Alexandre P., de Jesús, Ernesto, Dupont, Jairton

“…The catalytic activity expressed by turnover number (TON) and turnover frequency (TOF) in different fields of catalysis (enzymatic, homogeneous (single‐site),…”
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Sulfonated Water-Soluble N‑Heterocyclic Carbene Silver(I) Complexes: Behavior in Aqueous Medium and as NHC-Transfer Agents to Platinum(II) by Baquero, Edwin A, Silbestri, Gustavo F, Gómez-Sal, Pilar, Flores, Juan C, de Jesús, Ernesto

“…This report describes the synthesis of water-soluble silver(I) and platinum(II) complexes bearing sulfonated mono- or dianionic N-heterocyclic carbene ligands…”
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Dendrimer-Encapsulated Pd Nanoparticles versus Palladium Acetate as Catalytic Precursors in the Stille Reaction in Water by Bernechea, María, de Jesús, Ernesto, López-Mardomingo, Carmen, Terreros, Pilar

“…The performance of several palladium precatalysts, namely, palladium(II) acetate, palladium(0) nanoparticles encapsulated into poly(amidoamine) (PAMAM)…”
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Water-Soluble Palladium(II) Complexes with Sulfonated N‑Heterocyclic Carbenes in Suzuki Cross-Coupling and Hydrodehalogenation Reactions by Garrido, Roberto, Hernández-Montes, Paulo S, Gordillo, Álvaro, Gómez-Sal, Pilar, López-Mardomingo, Carmen, de Jesús, Ernesto

“…Water-soluble Pd­(II) complexes of general formula Na x [(NHC)­PdCl2L] (L = Cl– (1), PPh3 (2), PPh2(C6H4-m-SO3Na) (3), and 4-Mepy (4)), where NHC is a…”
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A Doublet State Palladium(I) N-Heterocyclic Carbene Complex as a Dopant and Stabilizer for Improved Photostability in Organic Solar Cells by El Astal-Quirós, Aliah, Carrarini, Valentina, Zarotti, Francesca, Rahman, Atiq Ur, Lledós, Agustí, Yebra, Cristina G., de Jesús, Ernesto, Reale, Andrea

“…The effect of doublet state metalloradical complex in a solar cell inside the common active layer poly(3-hexylthiophene)/[6,6]-phenyl-C61-butyric acid methyl…”
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Mechanistic Studies on the Pd-Catalyzed Vinylation of Aryl Halides with Vinylalkoxysilanes in Water: The Effect of the Solvent and NaOH Promoter by Gordillo, Alvaro, Ortuño, Manuel A, López-Mardomingo, Carmen, Lledós, Agustí, Ujaque, Gregori, de Jesús, Ernesto

“…The mechanism of the Pd-catalyzed vinylation of aryl halides with vinylalkoxysilanes in water has been studied using different catalytic precursors. The NaOH…”
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Solvent-Reversible Addition of Alkyne C–H Bonds to Water-Soluble NHC Platinum(0) Complexes by Baquero, Edwin A, Silbestri, Gustavo F, Flores, Juan C, de Jesús, Ernesto

“…Oxidative addition of CH3I and alkynes to the platinum(0) complex [Pt­(AE)­NHC] (1), in which the NHC ligand is a sulfonated version of the IPr ligand…”
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Water-Soluble Mono- and Dimethyl N‑Heterocyclic Carbene Platinum(II) Complexes: Synthesis and Reactivity by Baquero, Edwin A, Flores, Juan C, Perles, Josefina, Gómez-Sal, Pilar, de Jesús, Ernesto

“…A family of water-soluble dimethyl complexes of formula cis-[PtMe2(dmso)(NHC·Na)] (2), in which NHC is an anionic N-heterocyclic carbene bearing a…”
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Poly(benzyl ether) Dendrimers Functionalized at the Core with Palladium Bis(N‑Heterocyclic Carbene) Complexes as Catalysts for the Heck Coupling Reaction by Ortiz, Alba M, Sánchez-Méndez, Alberto, de Jesús, Ernesto, Flores, Juan C, Gómez-Sal, Pilar, Mendicuti, Francisco

“…Bis­(imidazolylidene)palladium complexes 9–12 containing a sterically hindered aryl group (mesityl or 2,6-diisopropylphenyl) and a poly­(benzyl ether) dendron…”
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Knight Shift in 13C NMR Resonances Confirms the Coordination of N‐Heterocyclic Carbene Ligands to Water‐Soluble Palladium Nanoparticles by Asensio, Juan M., Tricard, Simon, Coppel, Yannick, Andrés, Román, Chaudret, Bruno, de Jesús, Ernesto

“…The coordination of N‐heterocyclic carbene (NHC) ligands to the surface of 3.7 nm palladium nanoparticles (PdNPs) can be unambiguously established by…”
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Synthesis of Core−Shell PtRu Dendrimer-Encapsulated Nanoparticles. Relevance as Electrocatalysts for CO Oxidation by Bernechea, María, García-Rodríguez, Sergio, Terreros, Pilar, de Jesús, Ernesto, Fierro, José L. G, Rojas, Sergio

“…The synthesis of PtRu nanoparticles has been accomplished by using the dendrimer-encapsulated nanoparticle (DEN) approach. We report that the surface…”
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On the Pd-Catalyzed Vinylation of Aryl Halides with Tris(alkoxy)vinylsilanes in Water by Gordillo, Álvaro, de Jesús, Ernesto, López-Mardomingo, Carmen

“…Pd-catalyzed vinylation of aryl halides with tris(alkoxy)vinylsilanes occurs in aqueous NaOH solution through Heck coupling of the aryl halide with the silyl…”
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Smart Hydrant Monitoring System Prototype by Saavedra García, Helmut Antonio, Mendoza Vallecillo, Ernesto de Jesús

“…In this article, we will develop a system that allows the monitoring of hydrants through an Arduino microcontroller in the city of Managua. Which will consist…”
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Revisiting the synthesis of trans-[Pt(dmso)2ClMe] and cis-[Pt(dmso)2Me2]: Experimental and DFT studies by Baquero, Edwin A., Rodríguez-Zúñiga, Ana, Flores, Juan C., Temprado, Manuel, de Jesús, Ernesto

“…The preparation of trans-[Pt(dmso)2ClMe] (2) and cis-[Pt(dmso)2Me2] (3) from cis-[Pt(dmso)2Cl2] (1) and SnMe4 has been reexamined (dmso = dimethyl sulfoxide)…”
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