Search Results - "de Haan, O"
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Brown Carbon Production in Ammonium- or Amine-Containing Aerosol Particles by Reactive Uptake of Methylglyoxal and Photolytic Cloud Cycling
Published in Environmental science & technology (05-07-2017)“…The effects of methylglyoxal uptake on the physical and optical properties of aerosol containing amines or ammonium sulfate were determined before and after…”
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2
Unveiling contextual realities by microscopically entangling a neutron
Published in Nature communications (18-02-2020)“…The development of qualitatively new measurement capabilities is often a prerequisite for critical scientific and technological advances. Here we introduce an…”
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3
Glyoxal's impact on dry ammonium salts: fast and reversible surface aerosol browning
Published in Atmospheric chemistry and physics (17-08-2020)“…Alpha-dicarbonyl compounds are believed to form brown carbon in the atmosphere via reactions with ammonium sulfate (AS) in cloud droplets and aqueous aerosol…”
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4
Uptake of Glyoxal by Organic and Inorganic Aerosol
Published in Environmental science & technology (15-06-2008)“…The uptake of glyoxal by a variety of organic and inorganic aerosol types was examined in a Teflon chamber. Rapid glyoxal uptake was observed for all…”
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5
Formation of Nitrogen-Containing Oligomers by Methylglyoxal and Amines in Simulated Evaporating Cloud Droplets
Published in Environmental science & technology (01-02-2011)“…Reactions of methylglyoxal with amino acids, methylamine, and ammonium sulfate can take place in aqueous aerosol and evaporating cloud droplets. These…”
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6
Thermodynamics and Kinetics of Glyoxal Dimer Formation: A Computational Study
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (10-01-2008)“…Density functional theory (B3LYP//6-311+G*) calculations including Poisson−Boltzmann implicit solvent were used to study the hydration of glyoxal and…”
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7
Secondary Organic Aerosol Formation during Evaporation of Droplets Containing Atmospheric Aldehydes, Amines, and Ammonium Sulfate
Published in Environmental science & technology (16-12-2014)“…Reactions of carbonyl compounds in cloudwater produce organic aerosol mass through in-cloud oxidation and during postcloud evaporation. In this work, postcloud…”
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Maillard Chemistry in Clouds and Aqueous Aerosol As a Source of Atmospheric Humic-Like Substances
Published in Environmental science & technology (19-07-2016)“…The reported optical, physical, and chemical properties of aqueous Maillard reaction mixtures of small aldehydes (glyoxal, methylglyoxal, and glycolaldehyde)…”
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Secondary Organic Aerosol Formation by Glyoxal Hydration and Oligomer Formation: Humidity Effects and Equilibrium Shifts during Analysis
Published in Environmental science & technology (15-11-2005)“…Glyoxal is a significant atmospheric aldehyde formed from both anthropogenic aromatic compounds and biogenic isoprene emissions. The chemical behavior of…”
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10
Thermodynamics and Kinetics of Methylglyoxal Dimer Formation: A Computational Study
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (25-06-2009)“…Density functional theory (B3LYP//6-311+G*) calculations, including Poisson−Boltzmann implicit solvent and free energy corrections, are applied to study the…”
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11
Secondary Organic Aerosol Formation by Self-Reactions of Methylglyoxal and Glyoxal in Evaporating Droplets
Published in Environmental science & technology (01-11-2009)“…Glyoxal and methylglyoxal are scavenged by clouds, where a fraction of these compounds are oxidized during the lifetime of the droplet. As a cloud droplet…”
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12
Thermodynamics and Kinetics of Imidazole Formation from Glyoxal, Methylamine, and Formaldehyde: A Computational Study
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (10-03-2011)“…Density functional theory calculations, including Poisson−Boltzmann implicit solvent and free energy corrections, are applied to study the mechanism of…”
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13
Heterogeneous Glyoxal Oxidation: A Potential Source of Secondary Organic Aerosol
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (21-06-2012)“…Laboratory studies are described that suggest reactive uptake of glyoxal on particulate containing HNO3 could contribute to the formation of secondary organic…”
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14
Gas-phase water-mediated equilibrium between methylglyoxal and its geminal diol
Published in Proceedings of the National Academy of Sciences - PNAS (13-04-2010)“…In aqueous solution, aldehydes, and to a lesser extent ketones, hydrate to form geminal diols. We investigate the hydration of methylglyoxal (MG) in the gas…”
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15
Atmospheric condensed-phase reactions of glyoxal with methylamine
Published in Geophysical research letters (01-06-2009)“…Glyoxal reacts with methylamine in drying cloud droplet/aerosol surrogates to form high molecular mass oligomers along with smaller amounts of…”
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16
Oligomer Formation in Evaporating Aqueous Glyoxal and Methyl Glyoxal Solutions
Published in Environmental science & technology (15-10-2006)“…Glyoxal and methyl glyoxal are common secondary atmospheric pollutants, formed from aromatic and terpene precursors. Both compounds are extremely water-soluble…”
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17
Observation of the Goos-Hänchen shift with neutrons
Published in Physical review letters (08-01-2010)“…The Goos-Hänchen effect is a spatial shift along an interface resulting from an interference effect that occurs for total internal reflection. This phenomenon…”
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18
Application of a two-phase thermosyphon loop calculation method to a cold neutron source
Published in Cryogenics (Guildford) (01-01-2019)“…•Thermodynamics of two-phase thermosyphon loop verified by responses and neutronic measurements.•Pressure and void fraction during cooldown verified by…”
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Phase-object approximation in small-angle neutron scattering experiments on silicon gratings
Published in Journal of applied crystallography (01-02-2007)“…The phase‐object approximation for neutron scattering based on a one‐dimensional dynamic forward scattering theory is discussed and used to calculate the…”
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20
Methylamine’s Effects on Methylglyoxal-Containing Aerosol: Chemical, Physical, and Optical Changes
Published in ACS earth and space chemistry (19-09-2019)“…Methylamine, a common atmospheric amine species, is found in the gas, particle, and aqueous phases. It has been shown to form light-absorbing, oligomeric…”
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