Search Results - "de Groot, Matheus T"

Electron Transfer and Ligand Binding to Cytochrome c‘ Immobilized on Self-Assembled Monolayers by de Groot, Matheus T, Evers, Toon H, Merkx, Maarten, Koper, Marc T. M

“…We have successfully immobilized Allochromatium vinosum cytochrome c‘ on carboxylic acid-terminated thiol monolayers on gold and have investigated its…”
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Mass transfer in 3D‐printed electrolyzers: The importance of inlet effects by Weusten, Stéphane J. C., Murrer, Luc C. E. M., Groot, Matheus T., Schaaf, John

“…This article investigates the effect of inlet shape, entrance length, and turbulence promoters on mass transfer by using 3D‐printed electrolyzers. Our results…”
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Ohmic resistance in zero gap alkaline electrolysis with a Zirfon diaphragm by de Groot, Matheus T., Vreman, Albertus W.

“…•The resistance of the Zirfon diaphragm is as expected for a porous separator.•Fitted zero gap resistances significantly exceed the diaphragm resistance.•The…”
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Reorganization of Immobilized Horse and Yeast Cytochrome c Induced by pH Changes or Nitric Oxide Binding by de Groot, Matheus T, Merkx, Maarten, Koper, Marc T. M

“…The redox properties of horse and yeast cytochrome c electrostatically immobilized on carboxylic acid-terminated self-assembled monolayers (SAMs) have been…”
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Alkaline water electrolysis: with or without iron in the electrolyte? by de Groot, Matheus T

“…The presence of iron in the electrolyte has a significant impact on the performance of the electrodes in alkaline water electrolysis. For nickel-based anodes,…”
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Nitrogen Cycle Electrocatalysis by Rosca, Victor, Duca, Matteo, de Groot, Matheus T, Koper, Marc T. M

“…The electrocatalytic reactions of several inorganic nitrogen compounds are examined. The chemical compounds examined include nitrate and ammonia…”
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Electrodialysis for the concentration of ethanolamine salts by de Groot, Matheus T., Bos, Ardina A.C.M., Lázaro, Alicia Peris, de Rooij, Ralph M., Bargeman, Gerrald

“…► Monoethanol amine salts can be concentrated up to 18wt% using electrodialysis. ► The output concentration strongly depends on the applied current density. ►…”
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Separating kinetics and mass transfer in formic acid and formate oxidation on boron doped diamond electrodes by Arts, Anke, de Groot, Matheus T., van der Schaaf, John

“…This paper describes the electrochemical oxidation of formic acid (pH 2) and formate (pH 6 and pH 10) on boron doped diamond electrodes and separates kinetic…”
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Current efficiency and mass transfer effects in electrochemical oxidation of C1 and C2 carboxylic acids on boron doped diamond electrodes by Arts, Anke, de Groot, Matheus T., van der Schaaf, John

“…•Most carboxylic acids studied can react via a direct electron transfer mechanism.•Acetic acid can only be oxidized via •OH-radicals.•Glyoxylic and glycolic…”
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Electrochemical oxidation of benzoic acid and its aromatic intermediates on boron doped diamond electrodes by Arts, Anke, van den Berg, Kevin P., de Groot, Matheus T., van der Schaaf, John

“…Electrochemical oxidation using Boron-doped diamond (BDD) electrodes is a promising purification technique to remove organic pollutants, such as benzoic acid,…”
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Redox transitions of chromium, manganese, iron, cobalt and nickel protoporphyrins in aqueous solution by de Groot, Matheus T, Koper, Marc T M

“…The electrochemical redox behavior of immobilized chromium, manganese, iron, cobalt, and nickel protoporphyrins IX has been investigated over the pH 0-14…”
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Bipolar membrane electrodialysis for the alkalinization of ethanolamine salts by de Groot, Matheus T., de Rooij, Ralph M., Bos, Ardina A.C.M., Bargeman, Gerrald

“…► Bipolar membrane electrodialysis can be used to convert monoethanolamine chloride into alkaline monoethanolamine. ► With a two compartment setup using an…”
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Advanced characterization of alkaline water electrolysis through electrochemical impedance spectroscopy and polarization curves by de Groot, Matheus T., Vermeulen, Paul

“…•EIS enables distinction between anodic and cathodic processes.•Tafel slopes can be derived from charge transfer resistances.•Capacitances can potentially…”
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Electrochemical Reduction of NO by Hemin Adsorbed at Pyrolitic Graphite by de Groot, Matheus T, Merkx, Maarten, Wonders, Ad H, Koper, Marc T. M

“…The mechanism of the electrochemical reduction of nitric oxide (NO) by hemin adsorbed at pyrolitic graphite was investigated. The selectivity of NO reduction…”
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Optimal operating parameters for advanced alkaline water electrolysis by de Groot, Matheus T., Kraakman, Joost, Garcia Barros, Rodrigo Lira

“…Advanced zero-gap alkaline electrolyzers can be operated at a significantly higher current density than traditional alkaline electrolyzers. We have…”
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Heme Release in Myoglobin−DDAB Films and Its Role in Electrochemical NO Reduction by de Groot, Matheus T, Merkx, Maarten, Koper, Marc T. M

“…Electrochemical nitric oxide (NO) reduction by heme groups incorporated in films of didodecyldimethylammonium bromide (DDAB) on pyrolitic graphite was…”
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Evidence for heme release in layer-by-layer assemblies of myoglobin and polystyrenesulfonate on pyrolitic graphite by de Groot, Matheus T, Merkx, Maarten, Koper, Marc T M

“…Layer-by-layer assemblies of myoglobin and polystyrenesulfonate (PSS) on pyrolitic graphite have been investigated with the goal of determining the origin of…”
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Unraveling the impact of reverse currents on electrode stability in anion exchange membrane water electrolysis by Guruprasad, Naveen, van der Schaaf, John, de Groot, Matheus T.

“…Anion Exchange Membrane Water Electrolysis (AEMWE) stands out as one of the promising ways of producing green hydrogen. However, significant strides in…”
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Additional evidence for heme release in myoglobin-DDAB films on pyrolitic graphite by de Groot, Matheus T., Merkx, Maarten, Koper, Marc T.M.

“…In a recent paper [1] we claimed that heme release can occur in myoglobin-DDAB films under certain conditions. Our conclusion was based on the similar…”
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Impact of power supply fluctuation and part load operation on the efficiency of alkaline water electrolysis by Amireh, Senan F., Heineman, Niels N., Vermeulen, Paul, Barros, Rodrigo Lira Garcia, Yang, Dongsheng, van der Schaaf, John, de Groot, Matheus T.

“…Contrary to traditional electrolysers which operate continuously at their nominal load, future alkaline electrolysers need to be able to operate over a wide…”
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