Search Results - "de Groot, Frank M F"
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Rational strain engineering of single-atom ruthenium on nanoporous MoS2 for highly efficient hydrogen evolution
Published in Nature communications (16-03-2021)“…Maximizing the catalytic activity of single-atom catalysts is vital for the application of single-atom catalysts in industrial water-alkali electrolyzers, yet…”
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2
Dynamic active-site generation of atomic iridium stabilized on nanoporous metal phosphides for water oxidation
Published in Nature communications (01-06-2020)“…Designing efficient single-atom catalysts (SACs) for oxygen evolution reaction (OER) is critical for water-splitting. However, the self-reconstruction of…”
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3
Single platinum atoms embedded in nanoporous cobalt selenide as electrocatalyst for accelerating hydrogen evolution reaction
Published in Nature communications (15-04-2019)“…Designing efficient electrocatalysts for hydrogen evolution reaction is significant for renewable and sustainable energy conversion. Here, we report…”
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4
Self-Activated Catalytic Sites on Nanoporous Dilute Alloy for High-Efficiency Electrochemical Hydrogen Evolution
Published in ACS nano (23-03-2021)“…Design and synthesis of effective electrocatalysts for hydrogen evolution reaction (HER) in wide pH environments are critical to reduce energy losses in water…”
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5
Single Au Atom Doping of Silver Nanoclusters
Published in ACS nano (26-12-2018)“…Ag29 nanoclusters capped with lipoic acid (LA) can be doped with Au. The doped clusters show enhanced stability and increased luminescence efficiency. We…”
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6
Electronic parameters in cobalt-based perovskite-type oxides as descriptors for chemocatalytic reactions
Published in Nature communications (31-01-2020)“…Perovskite-type transition metal (TM) oxides are effective catalysts in oxidation and decomposition reactions. Yet, the effect of compositional variation on…”
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7
Femtosecond Soft X-ray Spectroscopy of Solvated Transition-Metal Complexes: Deciphering the Interplay of Electronic and Structural Dynamics
Published in The journal of physical chemistry letters (21-04-2011)“…We present the first implementation of femtosecond soft X-ray spectroscopy as an ultrafast direct probe of the excited-state valence orbitals in solution-phase…”
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Direct Observation of Cr3+ 3d States in Ruby: Toward Experimental Mechanistic Evidence of Metal Chemistry
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (10-05-2018)“…The role of transition metals in chemical reactions is often derived from probing the metal 3d states. However, the relation between metal site geometry and 3d…”
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9
Spin polarized electron dynamics enhance water splitting efficiency by yttrium iron garnet photoanodes: a new platform for spin selective photocatalysis
Published in Chemical science (Cambridge) (28-02-2024)“…This work presents a spectroscopic and photocatalytic comparison of water splitting using yttrium iron garnet (Y 3 Fe 5 O 12 , YIG) and hematite (α-Fe 2 O 3 )…”
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10
Nanoscale chemical imaging of a working catalyst by scanning transmission X-ray microscopy
Published in Nature (London) (13-11-2008)“…The modern chemical industry uses heterogeneous catalysts in almost every production process. They commonly consist of nanometre-size active components…”
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11
Photo-Induced Spin-State Conversion in Solvated Transition Metal Complexes Probed via Time-Resolved Soft X-ray Spectroscopy
Published in Journal of the American Chemical Society (19-05-2010)“…Solution-phase photoinduced low-spin to high-spin conversion in the FeII polypyridyl complex [Fe(tren(py)3)]2+ (where tren(py)3 is…”
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12
Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X‐ray Nanospectroscopy
Published in Angewandte Chemie International Edition (10-09-2018)“…A state‐of‐the‐art operando spectroscopic technique is applied to Co/TiO2 catalysts, which account for nearly half of the world's transportation fuels produced…”
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13
Magnetic Contrast at Spin-Flip Excitations: An Advanced X‑Ray Spectroscopy Tool to Study Magnetic-Ordering
Published in ACS applied materials & interfaces (02-10-2019)“…The determination of the local orientation and magnitude of the magnetization in spin textures plays a pivotal role in understanding and harnessing magnetic…”
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14
Charge-Transfer Analysis of 2p3d Resonant Inelastic X‑ray Scattering of Cobalt Sulfide and Halides
Published in Journal of physical chemistry. C (16-11-2017)“…We show that with 2p3d resonant inelastic X-ray scattering (RIXS) we can accurately determine the charge-transfer parameters of CoF2, CoCl2, CoBr2, and CoS…”
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15
Supramolecular control of the magnetic anisotropy in two-dimensional high-spin Fe arrays at a metal interface
Published in Nature materials (01-03-2009)“…Magnetic atoms at surfaces are a rich model system for solid-state magnetic bits exhibiting either classical or quantum behaviour. Individual atoms, however,…”
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16
Oxygen K‑edge X‑ray Absorption Spectra
Published in Chemical reviews (13-05-2020)“…We review oxygen K-edge X-ray absorption spectra of both molecules and solids. We start with an overview of the main experimental aspects of oxygen K-edge…”
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17
Hard X-ray Nanotomography of Catalytic Solids at Work
Published in Angewandte Chemie International Edition (26-11-2012)“…A closer look at catalysis: In situ hard X‐ray nanotomography has been developed (see picture) as a method to investigate an individual iron‐based…”
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18
In‐situ X‐Ray Absorption Near Edge Structure Spectroscopy of a Solid Catalyst using a Laboratory‐Based Set‐up
Published in ChemCatChem (06-02-2019)“…An in‐situ laboratory‐based X‐ray Absorption Near Edge Structure (XANES) Spectroscopy set‐up is presented, which allows performing long‐term experiments on a…”
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19
Spectroscopic characterization of electronic structures of ultra-thin single crystal La0.7Sr0.3MnO3
Published in Scientific reports (04-03-2021)“…We have successfully fabricated high quality single crystalline La 0.7 Sr 0.3 MnO 3 (LSMO) film in the freestanding form that can be transferred onto silicon…”
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Saturation and self‐absorption effects in the angle‐dependent 2p3d resonant inelastic X‐ray scattering spectra of Co3
Published in Journal of synchrotron radiation (01-07-2020)“…Angle‐dependent 2p3d resonant inelastic X‐ray scattering spectra of a LaCoO3 single crystal and a 55 nm LaCoO3 film on a SrTiO3 substrate are presented…”
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