Search Results - "de Araujo, Márcio P"
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Bis(diphenylphosphino)amines-containing ruthenium cymene complexes as potential anti-Mycobacterium tuberculosis agents
Published in Journal of inorganic biochemistry (01-08-2017)“…Several ruthenium complexes have been investigated regarding anti-Mycobacterium tuberculosis (anti-MTb) activity, with some diphosphine-containing ruthenium…”
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Synthesis, characterization and cytotoxic activities of the [RuCl2(NO)(dppp)(L)]PF6 complexes
Published in Journal of inorganic biochemistry (01-05-2010)“…The synthesis and characterization of ruthenium compounds of the type [RuCl(2)(NO)(dppp)(L)]PF(6) [dppp=1,3-bis(diphenylphosphino)propane; L=pyridine,…”
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Synthesis, characterization, solution chemistry and anticancer activity of [NiCl2(Ph2P–N(R)–PPh2)] (R = 2-CH2Py, CH2Ph and p-tol) complexes
Published in Journal of inorganic biochemistry (01-03-2023)“…In this work three Ni2+ complexes with general formula [NiCl2(Ph2P–N(R)–PPh2)], R = 2-CH2Py (Py = pyridine) – 1, CH2Ph (Ph = phenyl) – 2 and p-tol…”
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[RuCl2(DPEphos)(N-N)] (DPEphos = bis[(2-diphenylphosphino)phenyl]ether; N-N = 2-aminomethylpyridine or ethylenediamine): synthesis, characterization and transfer hydrogenation of aryl-ketones
Published in Journal of coordination chemistry (16-02-2023)“…The complexes trans/cis-[RuCl 2 (DPEphos)(ampy)] (trans - 1a; cis - 1b) and trans/cis-[RuCl 2 (DPEphos)(en)] (trans - 2a; cis - 2b) were obtained from the…”
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Ruthenium nitrosyl complexes [RuCl3(NO)(P–N)] bearing an oxazoline-derived P–N ligand (PHOX)
Published in Transition metal chemistry (Weinheim) (01-05-2015)“…This work presents two complexes with general formula [RuCl 3 (NO)(PHOX)] (PHOX = 2-[2-(diphenylphosphino)phenyl]-4,4-dimethyl-2-oxazoline). Reaction of the…”
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Ruthenium-cymene containing pyridine-derived aldiimine ligands: Synthesis, characterization and application in the transfer hydrogenation of aryl ketones and kinetics studies
Published in Journal of organometallic chemistry (15-08-2019)“…Five electron-rich NN′−pyridylimine ligands, which form five-membered chelate ring when coordinate to a metal center, have been synthesized by the easily…”
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Triphosphines-containing ruthenium-acetato complexes: Synthesis, characterization, DFT, mer/fac isomerization and formic acid dehydrogenation
Published in Journal of molecular structure (15-01-2020)“…The triphosphines-containing ruthenium-acetato complexes [RuCl(κ2-OAc)(triphos)] (2) and the new analogue synthesized in our research group [RuCl(κ2-OAc)(etp)]…”
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New heterobimetallic ruthenium (II) complexes [Ru(N-S)(bipy)(dppf)]PF6: Synthesis, molecular structure, electrochemistry, DFT, antioxidant and antibacterial potential
Published in Journal of organometallic chemistry (01-10-2017)“…Two new heterobimetallic ruthenium (II) complexes with general formula [Ru(N-S)(bipy)(dppf)]PF6 (bipy = 2,2’-bipyridine, N-S = 2-mercaptothiazolinate – mctz−…”
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Studies on the Ru(II) monocationic complexes [RuCl2(NO)(P–N)(PR3)]PF6, where P–N=o-diphenylphosphino-N,N-dimethylaniline, and R=Ph and p-X-C6H4 (X=OMe, Me, F)
Published in Inorganica Chimica Acta (01-01-2017)“…The monocationic Ru(II) complexes [RuCl2(NO)(P–N)(PR3)]PF6; P–N=o-diphenylphosphino-N,N′-dimethylaniline, and R=p-MeO-C6H4 (complex 2), p-Me-C6H4 (3), Ph (4),…”
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Antibacterial activity of DPEphos-containing ruthenium-nitrosyl complexes
Published in Inorganic chemistry communications (01-04-2018)“…The complex fac-[RuCl3(NO)(κ2-P,P′-DPEphos)] (1) was synthesized and characterized by 31P {1H} and 1H NMR, vibrational spectroscopy, ESI-MS and cyclic…”
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Ruthenium (II) complexes containing 2-mercaptothiazolinates as ligands and evaluation of their antimicrobial activity
Published in Inorganica Chimica Acta (01-09-2015)“…Two complexes with general formula cis-[Ru(N–S)2(PPh3)2] (2-mercaptothiazoline – Hmctz) or 2-mercaptobenzothiazoline – Hmcbtz) were synthesized and fully…”
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Mixed phosphine/diimines and/or amines ruthenium carbonyl complexes: Synthesis, characterization and transfer-hydrogenation
Published in Polyhedron (07-10-2013)“…Complexes with the general formula trans-[RuCl2(CO)(PR3)(N–N)] (N–N=diimines and/or amines; PR3=triphenylphosphine or tri-p-tolylphosphine) were synthesized by…”
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Ruthenium-carbonyl complexes with P/O or P/N donor ligands: Effect of the chelate ring size and donor atom
Published in Polyhedron (25-07-2012)“…Six new complexes with the formula cis,trans-[RuCl2(CO)(PR3)(PPh2-X)] were synthesized and characterized. Studies on the reactivity with carbon monoxide and…”
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Observation of vinylidene emission in mixed phosphine/diimine complexes of Ru(II) at room temperature in solution
Published in Journal of organometallic chemistry (2012)“…The mixed ruthenium(II) complexes trans-[RuCl 2(PPh 3) 2(bipy)] (1), trans-[RuCl 2(PPh 3) 2(Me 2bipy)](2), cis-[RuCl 2(dcype)(bipy)](3), cis-[RuCl 2(dcype)(Me…”
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fac-/mer-[RuCl 3(NO)(P–N)] (P–N = [ o -( N, N-dimethylamino)phenyl]diphenylphosphine): Synthesis, characterization and DFT calculations
Published in Inorganica Chimica Acta (15-07-2011)“…The fac-[RuCl 3(NO)(P–N)] ( 1) complex was synthesized from reaction of [RuCl 3(H 2O) 2(NO)] and o-[( N,N-dimethylamino)phenyl]diphenylphosphine) (P–N); the…”
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p,t-[Ru(CO)(PR3)(tren)]2+ [R = Ph or p-tol; tren = tris(2-aminoethyl)amine], Ru(II) complexes bearing a simple tripodal tetradentate amine: synthesis, characterization, and antimicrobial activity
Published in Journal of coordination chemistry (16-09-2016)“…Complexes with general formula p,t-[Ru(CO)(PR 3 )(tren)]X 2 [R = Ph (1) or p-tol (2); tren = tris(2-aminoethyl)amine; X = Cl − or ] were prepared from [RuCl 2…”
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An Electrochemical Experiment to Monitor the Isomerization of trans- to cis-[RuCl2(dppb)(phen)]. An Undergraduate Cyclic Voltammetry Experiment for Inorganic Chemistry
Published in Journal of chemical education (01-01-2001)“…A cyclic voltammetric experiment for undergraduate students is presented involving the conversion of trans-[RuCl2(dppb)(phen)] to cis-[RuCl2(dppb)(phen)] (dppb…”
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Heterobimetallic [Ru(II)/Fe(II)] complexes: On the formation of trans- and cis-[RuCl 2(dppf)(diimines)]
Published in Journal of organometallic chemistry (15-11-2007)“…The synthesis and characterization of trans/ cis-[RuCl 2(dppf)(diimines)], dppf = 1,1′-bis(diphenylphosphino)ferrocene; diimines = 2,2′-bipyridine ( trans/…”
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The mer-[RuCl3(dppb)(H2O)] complex: A versatile tool for synthesis of RuII compounds
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