Search Results - "de la Hoz, Antonio"
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1
Visible‐Light‐Induced Nickel‐Catalyzed Negishi Cross‐Couplings by Exogenous‐Photosensitizer‐Free Photocatalysis
Published in Angewandte Chemie International Edition (09-07-2018)“…The merging of photoredox and transition‐metal catalysis has become one of the most attractive approaches for carbon–carbon bond formation. Such reactions…”
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2
Pushing nuclear magnetic resonance sensitivity limits with microfluidics and photo-chemically induced dynamic nuclear polarization
Published in Nature communications (09-01-2018)“…Among the methods to enhance the sensitivity of nuclear magnetic resonance (NMR) spectroscopy, small-diameter NMR coils (microcoils) are promising tools to…”
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3
Photoinduced Palladium‐Catalyzed Negishi Cross‐Couplings Enabled by the Visible‐Light Absorption of Palladium–Zinc Complexes
Published in Angewandte Chemie International Edition (01-10-2018)“…A visible‐light‐induced Negishi cross‐coupling is enabled by the activation of a Pd0–Zn complex. With this photocatalytic method, the scope of deactivated aryl…”
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4
NMR reaction monitoring in flow synthesis
Published in Beilstein journal of organic chemistry (14-02-2017)“…Recent advances in the use of flow chemistry with in-line and on-line analysis by NMR are presented. The use of macro- and microreactors, coupled with standard…”
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5
Donor–Acceptor–Donor 1H-Benzo[d]imidazole Derivatives as Optical Waveguides
Published in Molecules (Basel, Switzerland) (08-06-2023)“…A new series of donor–acceptor–donor (D–A–D) structures derived from arylethynyl 1H-benzo[d]imidazole was synthesized and processed into single crystals with…”
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6
Illumination of Nanoliter-NMR Spectroscopy Chips for Real-Time Photochemical Reaction Monitoring
Published in Analytical chemistry (Washington) (06-02-2018)“…We report the use of a small-volume nuclear-magnetic-resonance (NMR)-spectroscopy device with integrated fiber-optics for the real-time detection of…”
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7
DFT Studies on Cobalt-Catalyzed Cyclotrimerization Reactions: The Mechanism and Origin of Reaction Improvement under Microwave Irradiation
Published in Chemistry : a European journal (14-05-2012)“…A DFT computational mechanistic study of the [2+2+2] cyclotrimerization of a diyne with benzonitrile, catalyzed by a cobalt complex, has been carried out…”
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8
Influence of Polarity and Activation Energy in Microwave–Assisted Organic Synthesis (MAOS)
Published in ChemistryOpen (Weinheim) (01-06-2015)“…The aim of this work was to determine the parameters that have decisive roles in microwave‐assisted reactions and to develop a model, using computational…”
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9
Application of flow chemistry to the reduction of nitriles to aldehydes
Published in Tetrahedron letters (16-11-2011)“…Reduction of nitriles to aldehydes with diisobutylaluminium hydride (DIBAL-H) is an important transformation in organic chemistry. But the use of this reaction…”
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10
Effect of coronavirus disease 2019 (COVID-19) pandemic on catheter-related bloodstream infections: Control measures should not be relaxed
Published in Infection control and hospital epidemiology (01-09-2022)“…In this study, the CLABSI increased rate from 0.68 to 0.87 events per 1,000 catheter days.5 The Fundación Santa Fe de Bogotá (FSFB) is a teaching hospital in…”
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11
Cycloadditions under Microwave Irradiation Conditions: Methods and Applications
Published in European journal of organic chemistry (01-11-2000)“…Microwave irradiation has been applied with success to cycloaddition reactions. The special characteristics of such irradiation entails the use of new…”
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12
Diels-Alder reactions in confined spaces: the influence of catalyst structure and the nature of active sites for the retro-Diels-Alder reaction
Published in Beilstein journal of organic chemistry (13-10-2016)“…Diels-Alder cycloaddition between cyclopentadiene and -benzoquinone has been studied in the confined space of a pure silica zeolite Beta and the impact on…”
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13
The mechanism of the reaction of hydrazines with α,β-unsaturated carbonyl compounds to afford hydrazones and 2-pyrazolines (4,5-dihydro-1H-pyrazoles): Experimental and theoretical results
Published in Tetrahedron (24-09-2021)“…The reaction of hydrazines with α,β-unsaturated carbonyl compounds to afford 2-pyrazolines was studied using a dissymmetric chalcone (phenyl/p-tolyl) and three…”
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14
Mechanical Processing of Naturally Bent Organic Crystalline Microoptical Waveguides and Junctions
Published in Small (Weinheim an der Bergstrasse, Germany) (01-01-2021)“…Precise mechanical processing of optical microcrystals involves complex microscale operations viz. moving, bending, lifting, and cutting of crystals. Some of…”
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15
Synthesis of Bright Alkenyl-1H-1,2,4-triazoles: A Theoretical and Photophysical Study
Published in ChemPlusChem (Weinheim, Germany) (01-10-2014)“…A sustainable synthesis of alkenyl‐1H‐1,2,4‐triazoles through the Hiyama reaction is reported, which employs water as solvent and sodium hydroxide to activate…”
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16
Solvent-free microwave-assisted synthesis of new 2,4-dimethoxybenzylaminotriazines
Published in ARKIVOC (06-11-2013)Get full text
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Microwaves in organic synthesis. Thermal and non-thermal microwave effects
Published in Chemical Society reviews (01-01-2005)“…Microwave irradiation has been successfully applied in organic chemistry. Spectacular accelerations, higher yields under milder reaction conditions and higher…”
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18
3-Pyrazolines (2,3-dihydro-1H-pyrazoles): synthesis, reactivity, and physical and biological properties
Published in ARKIVOC free online journal of organic chemistry (01-01-2021)Get full text
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19
Limited Renal Intravascular Lymphoma: A Case Report and Review of the Literature
Published in Case reports in oncological medicine (07-10-2020)“…Intravascular large B-cell lymphoma (IVLBCL) is a rare subtype of non-Hodgkin lymphoma. It is characterized by the proliferation of cancerous cells into the…”
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20
Solvent-Free Benzylations of 2-Pyridone. Regiospecific N- or C-Alkylation
Published in Chemistry letters (01-05-1996)“…Regiospecific N- or C-benzylations of 2-pyridone are observed in solvent-free conditions in the absence of base. The regioselectivity is controlled by the…”
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