Search Results - "Zuzek, Ashley"
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Si–H and Si–C Bond Cleavage Reactions of Silane and Phenylsilanes with Mo(PMe3)6: Silyl, Hypervalent Silyl, Silane, and Disilane Complexes
Published in Journal of the American Chemical Society (11-06-2014)“…Mo(PMe3)6 cleaves the Si–H bonds of SiH4, PhSiH3, and Ph2SiH2 to afford a variety of novel silyl, hypervalent silyl, silane, and disilane complexes, as…”
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Journal Article -
2
Electron Transfer from Hexameric Copper Hydrides
Published in Journal of the American Chemical Society (20-11-2013)“…The octahedral core of 84-electron LCuH hexamers does not dissociate appreciably in solution, although their hydride ligands undergo rapid intramolecular…”
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Journal Article -
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σ‑Silane, Disilanyl, and [W(μ‑H)Si(μ‑H)W] Bridging Silylene Complexes via the Reactions of W(PMe3)4(η2‑CH2PMe2)H with Phenylsilanes
Published in Journal of the American Chemical Society (31-12-2014)“…W(PMe3)4(η2-CH2PMe2)H reacts with PhSiH3 to give the first examples of diphenyldisilanyl compounds, W(PMe3)4(SiH2SiHPh2)H3 and…”
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Journal Article -
4
Synthesis and Structure of Gold and Platinum Menthyl Complexes
Published in Organometallics (11-04-2011)“…A Grignard reagent derived from (−)-menthyl chloride has been reported to be a 1:1 mixture of menthyl magnesium chloride and neomenthyl magnesium chloride,…”
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Journal Article -
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Molecular structure of W(PMe3)3H6 in the solid state and in solution
Published in Inorganica Chimica Acta (01-10-2014)“…W(PMe3)3H6 has been identified as a classical hydride compound by low temperature X-ray diffraction studies in the solid state and by 1H NMR spectroscopic…”
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Journal Article -
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Application of Transition Metal Phosphine Complexes in the Modeling of Catalytic Processes: Reactivity with Hydrosilanes and Other Industrially Relevant Substrates
Published 01-01-2014“…The first two chapters of this thesis are devoted to exploring the reactivity of electron rich molybdenum and tungsten trimethylphosphine complexes with…”
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Dissertation