Search Results - "Zilbermann, Israel"
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Metallophthalocyanines: Versatile Electron-Donating Building Blocks for Fullerene Dyads
Published in The journal of physical chemistry. B (02-12-2004)“…A thorough investigation on the physicochemical properties, including electrochemisty and photophysics, of a new class of donor−acceptor hybrids, namely,…”
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Redox Chemistry of Nickel Complexes in Aqueous Solutions
Published in Chemical reviews (01-06-2005)“…The requirements for the stabilization of the d6-d9 nickel ions, NiI and NiIV, have been reviewed several times in the last 20 years. Zibermann, et al discuss…”
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Radicals in ‘biologically relevant’ concentrations behave differently: Uncovering new radical reactions following the reaction of hydroxyl radicals with DMSO
Published in Free radical biology & medicine (01-01-2021)“…Methyl radicals play key roles in various chemical and biological processes. Mechanistic studies of methyl radicals with their precursor, Dimethyl Sulfoxide…”
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Pyrophosphate and ATP as Stabilizing Ligands for High-Valent Nickel Complexes
Published in European Journal of Inorganic Chemistry (01-02-2006)“…ATP stabilizes trivalent nickel complexes which suggests that another plausible role of ATP in biological systems is the stabilization of high‐valent…”
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Macrocyclic Ligand Coordinating Amide-Arm Hydrolysis Reaction Activation in Aqueous Solutions: Tetravalent Uranium Does It Better
Published in Inorganic chemistry (08-01-2024)“…Chelation of lanthanide and actinide cations within a suitable macrocyclic ligand often results in a rigid, kinetically inert, and thermodynamically stable…”
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On the reactions of Cu(II/I)ATP complexes with methyl radicals
Published in Journal of inorganic biochemistry (01-09-2022)“…The CuI/IIATP react with methyl radicals to form methane and methanol, where CuIATP reacts with •CH3 in a process that is surprisingly slow. The low-rate…”
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Reactions of methyl, hydroxyl and peroxyl radicals with the DOTA chelating agent used in medical imaging
Published in Free radical biology & medicine (20-02-2022)“…The mechanism of reaction of DOTA (1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetic acid) with ·CH3, CH3O2· and ·OH radicals were studied. The radicals were…”
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Cover Feature: DOTP versus DOTA as Ligands for Lanthanide Cations: Novel Structurally Characterized CeIV and CeIII Cyclen‐Based Complexes and Clusters in Aqueous Solutions (Chem. Eur. J. 61/2022)
Published in Chemistry : a European journal (02-11-2022)“…A group of researchers from NRCN, Ben Gurion University and the CEA shows that cyclen‐derived, hard‐bonding ligands facilitate the formation of tetravalent…”
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Electronic Coupling and Electrocatalysis in Redox Active Fused Iron Corroles
Published in Inorganic chemistry (26-12-2022)“…Conjugated arrays composed of corrole macrocycles are increasingly more common, but their chemistry still lags behind that of their porphyrin counterparts…”
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Mechanisms of Reaction Between Co(II) Complexes and Peroxymonosulfate
Published in European journal of inorganic chemistry (11-01-2022)“…Advanced oxidation technologies often use peroxymonosulfate in the presence of CoIIaq. It is commonly assumed that the reaction of Co(H2O)62+ with HSO5− yields…”
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DOTP versus DOTA as Ligands for Lanthanide Cations: Novel Structurally Characterized CeIV and CeIII Cyclen‐Based Complexes and Clusters in Aqueous Solutions
Published in Chemistry : a European journal (02-11-2022)“…The coordination and redox chemistry of aqueous CeIV/III macrocyclic compounds were studied by using the ligands DOTA and DOTP…”
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DOTP versus DOTA as Ligands for Lanthanide Cations: Novel Structurally Characterized Ce IV and Ce III Cyclen‐Based Complexes and Clusters in Aqueous Solutions
Published in Chemistry : a European journal (02-11-2022)“…Abstract The coordination and redox chemistry of aqueous Ce IV/III macrocyclic compounds were studied by using the ligands DOTA and DOTP…”
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The reactions of the Cu(II)-nitrilotris(methylenephosphonic acid) complex with alkyl radicals in aqueous solutions
Published in Inorganica Chimica Acta (01-10-2020)“…[Display omitted] •The radicals R = CH3 or CH2OH, react with the complex CuII(ntp)(H2O).•The kinetics of formation of (ntp)CuIII-R fit pseudo first order rate…”
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Redox Properties of CeIVDOTA in Carbonated Aqueous Solutions. A Radiolytic and an Electrochemical Study
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (25-02-2021)“…The redox chemistry of CeIIIDOTA in cage in carbonate solutions was studied using electrochemistry and radiolysis techniques (continuous radiolysis and pulse…”
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Redox Properties of Ce IV DOTA in Carbonated Aqueous Solutions. A Radiolytic and an Electrochemical Study
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (25-02-2021)“…The redox chemistry of Ce DOTA in carbonate solutions was studied using electrochemistry and radiolysis techniques (continuous radiolysis and pulse…”
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On the Aqueous Chemistry of the U IV -DOTA Complex
Published in Chemistry : a European journal (12-03-2020)“…The 1,4,7,10-tetrazacyclodecane-1,4,7,10-tetraacetic acid (DOTA) aqueous complex of U with H O, OH , and F as axial ligands was studied by using UV/Vis…”
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Mechanistic Studies on the Role of [CuII(CO3)n]2−2n as a Water Oxidation Catalyst: Carbonate as a Non‐Innocent Ligand
Published in Chemistry : a European journal (24-01-2018)“…Recently it was reported that copper bicarbonate/carbonate complexes are good electro‐catalysts for water oxidation. However, the results did not enable a…”
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Cover Feature: Mechanistic Studies on the Role of [CuII(CO3)n]2−2n as a Water Oxidation Catalyst: Carbonate as a Non‐Innocent Ligand (Chem. Eur. J. 5/2018)
Published in Chemistry : a European journal (24-01-2018)“…Inorganic chemists from the Nuclear Research Centre Negev, Ariel University, and Ben‐Gurion University elucidate the high‐valent copper species responsible for…”
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