Search Results - "Zhou, Qi‐Lin"

Transition-Metal Catalysis and Organocatalysis: Where Can Progress Be Expected? by Zhou, Qi-Lin

“…“… Most transition‐metal catalysts and organocatalysts do not meet the requirements for modern industrial manufacturing processes. Their main limitation is low…”
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Transition-Metal-Catalyzed Enantioselective Heteroatom–Hydrogen Bond Insertion Reactions by Zhu, Shou-Fei, Zhou, Qi-Lin

“…Carbon–heteroatom bonds (C–X) are ubiquitous and are among the most reactive components of organic compounds. Therefore investigations of the construction of…”
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Iridium-Catalyzed Asymmetric Hydrogenation of Unsaturated Carboxylic Acids by Zhu, Shou-Fei, Zhou, Qi-Lin

“…Chiral carboxylic acid moieties are widely found in pharmaceuticals, agrochemicals, flavors, fragrances, and health supplements. Although they can be…”
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Intermolecular Enantioselective Benzylic C(sp3)−H Amination by Cationic Copper Catalysis by Dai, Ling, Chen, Ying‐Ying, Xiao, Li‐Jun, Zhou, Qi‐Lin

“…Chiral benzylic amines are privileged motifs in pharmacologically active molecules. Intramolecular enantioselective radical C(sp3)−H functionalization by…”
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Nickel(0)‐Catalyzed Hydroarylation of Styrenes and 1,3‐Dienes with Organoboron Compounds by Xiao, Li‐Jun, Cheng, Lei, Feng, Wei‐Min, Li, Mao‐Lin, Xie, Jian‐Hua, Zhou, Qi‐Lin

“…A Ni‐catalyzed hydroarylation of styrenes and 1,3‐dienes with organoboron compounds has been developed. The reaction offers a highly selective approach to…”
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Special Issue Dedicated to Andreas Pfaltz by Glorius, Frank, Zhou, Qi‐Lin

“…No…”
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Palladium‐Catalyzed Asymmetric Hydrosulfonylation of 1,3‐Dienes with Sulfonyl Hydrazides by Li, Ming‐Ming, Cheng, Lei, Xiao, Li‐Jun, Xie, Jian‐Hua, Zhou, Qi‐Lin

“…A highly enantio‐ and regioselective hydrosulfonylation of 1,3‐dienes with sulfonyl hydrazides has been realized by using a palladium catalyst containing a…”
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Nickel‐Catalyzed Desymmetric Reductive Cyclization/Coupling of 1,6‐Dienes: An Enantioselective Approach to Chiral Tertiary Alcohol by Zhao, Tian‐Yuan, Xiao, Li‐Jun, Zhou, Qi‐Lin

“…We have developed a nickel‐catalyzed desymmetric reductive cyclization/coupling of 1,6‐dienes. The reaction provides an efficient method for constructing a…”
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Electrochemical Synthesis of Sulfonyl Fluorides with Triethylamine Hydrofluoride by Zhang, Lei, Cheng, Xu, Zhou, Qi‐Lin

“…Comprehensive Summary Hydrofluoride is an industry‐preferred fluoride source, and finds extensively application to manufacture diverse fluoro chemicals. The…”
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Chiral Diphosphine and Monodentate Phosphorus Ligands on a Spiro Scaffold for Transition-Metal-Catalyzed Asymmetric Reactions by Xie, Jian-Hua, Zhou, Qi-Lin

“…The preparation of chiral compounds in enantiomerically pure form is a challenging goal in modern organic synthesis. The use of chiral metal complex catalysis…”
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Transition Metal-Catalyzed Enantioselective Hydrogenation of Enamines and Imines by Xie, Jian-Hua, Zhu, Shou-Fei, Zhou, Qi-Lin

“…The authors examine the enantioselective hydrogenation of enamines and imines in metal-catalyzed transitions. The enantioselective hydrogenation of several…”
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Nickel(0)-catalyzed linear-selective hydroarylation of unactivated alkenes and styrenes with aryl boronic acids by Lv, Honggui, Xiao, Li-Jun, Zhao, Dongbing, Zhou, Qi-Lin

“…Herein, we describe the first linear-selective hydroarylation reaction of unactivated alkenes and styrenes with aryl boronic acids, which was achieved by…”
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Stereoselective synthesis of medium lactams enabled by metal-free hydroalkoxylation/stereospecific [1,3]-rearrangement by Zhou, Bo, Zhang, Ying-Qi, Zhang, Kairui, Yang, Ming-Yang, Chen, Yang-Bo, Li, You, Peng, Qian, Zhu, Shou-Fei, Zhou, Qi-Lin, Ye, Long-Wu

“…Rearrangement reactions have attracted considerable interest over the past decades due to their high bond-forming efficiency and atom economy in the…”
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Palladium-Catalyzed Hydrocarboxylation of Alkynes with Formic Acid by Hou, Jing, Xie, Jian-Hua, Zhou, Qi-Lin

“…A palladium‐catalyzed hydrocarboxylation of alkynes with formic acid has been developed. The method provides acrylic acid and derivatives in good yields with…”
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Iron-catalyzed transformations of diazo compounds by Zhu, Shou-Fei, Zhou, Qi-Lin

“…Abstract Although iron-promoted diazo transformations were only discovered during the 1990s, iron can undergo facile changes in its oxidation state and…”
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Asymmetric NH Insertion Reaction Cooperatively Catalyzed by Rhodium and Chiral Spiro Phosphoric Acids by Xu, Bin, Zhu, Shou-Fei, Xie, Xiu-Lan, Shen, Jun-Jie, Zhou, Qi-Lin

“…So near so SPA: Achiral dirhodium(II) carboxylates and chiral spiro phosphoric acids (SPA) cooperatively catalyzed asymmetric NH insertion reactions with high…”
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An Additional Coordination Group Leads to Extremely Efficient Chiral Iridium Catalysts for Asymmetric Hydrogenation of Ketones by Xie, Jian-Hua, Liu, Xiao-Yan, Xie, Jian-Bo, Wang, Li-Xin, Zhou, Qi-Lin

“…What a turnover! An efficient chiral iridium catalyst that bears a tridentate spiro aminophosphine ligand catalyzes the asymmetric hydrogenation of ketones…”
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Enantioselective Synthesis of Chiral Amides by a Phosphoric Acid Catalyzed Asymmetric Wolff Rearrangement by Pan, Jia‐Bin, Yang, Zhi‐Chun, Zhang, Xuan‐Ge, Li, Mao‐Lin, Zhou, Qi‐Lin

“…The enantioselective addition of potent nucleophiles to ketenes poses challenges due to competing background reactions and poor stereocontrol. Herein, we…”
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Catalytic B–H Bond Insertion Reactions Using Alkynes as Carbene Precursors by Yang, Ji-Min, Li, Zi-Qi, Li, Mao-Lin, He, Qiao, Zhu, Shou-Fei, Zhou, Qi-Lin

“…Herein, we report transition-metal-catalyzed B–H bond insertion reactions between borane adducts and alkynes to afford organoboron compounds in excellent…”
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Chiral Spiro Phosphoramide-Catalyzed Sulfa-Michael Addition/Enantioselective Protonation of Exocyclic Enones by Li, Yi-Pan, Zhu, Shou-Fei, Zhou, Qi-Lin

“…A highly efficient asymmetric Michael addition of thiols to exocyclic enones was achieved by using chiral spiro phosphoramide catalysts. The precisely chiral…”
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