Search Results - "Zhang, Jitan"
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Enantioselective Synthesis of C−N Axially Chiral N‐Aryloxindoles by Asymmetric Rhodium‐Catalyzed Dual C−H Activation
Published in Angewandte Chemie International Edition (13-05-2019)“…The first enantioselective Satoh–Miura‐type reaction is reported. A variety of C−N axially chiral N‐aryloxindoles have been enantioselectively synthesized by…”
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NH4I-promoted N-acylation of amines via the transamidation of DMF and DMA under metal-free conditions
Published in Tetrahedron letters (23-05-2019)“…[Display omitted] •Inexpensive NH4I-promoted convenient and metal free N-acylation of various amines is developed.•Readily available DMF and DMA are used as…”
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Pd(II)-catalyzed C(sp2)–H carbonylation of biaryl-2-amine: synthesis of phenanthridinones
Published in Tetrahedron (05-08-2013)“…A Pd(OAc)2-catalyzed C(sp2)–H carbonylation protocol of arenes under carbon monoxide atmosphere has been developed. The scope of the carbonylation reaction is…”
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4
An Approach to Five-Membered Lactams from Aliphatic Amides and Terminal Acetylenes by Nickel Catalysis
Published in Advanced synthesis & catalysis (02-06-2016)“…A nickel‐catalyzed facile synthesis of structurally diverse five‐membered lactams from aliphatic amides and terminal acetylenes with the assistance of an…”
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Rhodium(III)-Catalyzed One-Pot Access to Isoquinolines and Heterocycle-Fused Pyridines in Aqueous Medium through C-H Cleavage
Published in European journal of organic chemistry (01-12-2014)“…An efficient RhIII‐catalyzed ortho‐C–H bond activation for the synthesis of substituted isoquinolines and heterocycle‐fused pyridines in aqueous medium has…”
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Synthesis of Benzyl Esters via Functionalization of Multiple C–H Bonds by Palladium Catalysis
Published in Organic letters (06-11-2015)“…A highly efficient, selective synthesis of benzyl esters by palladium catalysis is developed through the bidentate directing group assisted functionalization…”
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Metal-Free Synthesis of Functionalized Tetrasubstituted Alkenes by Three-Component Reaction of Alkynes, Iodine, and Sodium Sulfinates
Published in ACS omega (31-12-2018)“…An operationally simple, efficient, and metal-/peroxide-free three-component reaction of alkynes, iodine, and sodium sulfinates has been developed for the…”
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Enantioselective Synthesis of C−N Axially Chiral N‐Aryloxindoles by Asymmetric Rhodium‐Catalyzed Dual C−H Activation
Published in Angewandte Chemie (13-05-2019)“…The first enantioselective Satoh–Miura‐type reaction is reported. A variety of C−N axially chiral N‐aryloxindoles have been enantioselectively synthesized by…”
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9
Cobalt-Catalyzed Cyclization of Aliphatic Amides and Terminal Alkynes with Silver-Cocatalyst
Published in Journal of the American Chemical Society (14-10-2015)“…A new method of cobalt-catalyzed synthesis of pyrrolidinones from aliphatic amides and terminal alkynes was discovered through a C–H bond functionalization…”
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10
Construction of N–C Axial Chirality through Atroposelective C–H Olefination of N‑Arylindoles by Palladium/Amino Acid Cooperative Catalysis
Published in Organic letters (16-08-2019)“…Direct construction of N–C axial chirality via Pd-catalyzed atroposelective C–H olefination of N-arylindoles is reported. The crucial role of chiral amino acid…”
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Electrochemical Rhodium-Catalyzed C–H Cyclodimerization of Alkynes to Access Diverse Functionalized Naphthalenes: Involvement of RhIV/V and RhI Dual Catalysis
Published in Organic letters (28-10-2022)“…The first electrochemical rhodium-catalyzed C–H cyclodimerization of alkynes for the direct construction of functionalized naphthalenes was reported. The…”
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Construction of 3‑Sulfonyl Naphthalenes via Tandem Reaction of 1,4-Diyn-3-yl Esters with Sodium Sulfinates
Published in Journal of organic chemistry (07-05-2021)“…Polysubstituted 3-sulfonyl naphthalenes were constructed in good to high yields by AlCl3-mediated tandem reaction of 1,4-diyn-3-yl esters and sodium…”
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14
Acid-Controlled Access to β‑Sulfenyl Ketones and α,β-Disulfonyl Ketones by Pummerer Reaction of β‑Keto Sulfones and Sulfoxides
Published in Journal of organic chemistry (17-01-2020)“…A convenient acid-mediated reaction of β-keto sulfones with sulfoxides under metal-free conditions has been developed, thereby delivering the acid-controlled…”
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Pd-Catalyzed Atroposelective C–H Acyloxylation Enabling Access to an Axially Chiral Biaryl Phenol Organocatalyst
Published in Organic letters (22-07-2022)“…Herein, we present the Pd(II)-catalyzed atroposelective C–H acyloxylation strategy for the assembly of biaryl aldehyde atropoisomers using readily available…”
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Electrochemical Oxidation of Indoles to Access Tryptanthrins at Room Temperature
Published in Advanced synthesis & catalysis (30-01-2024)“…An electrooxidative reconstruction of the indole core under ambient conditions is reported, resulting in the construction of tryptanthrins. This…”
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Copper-Mediated Aryloxylation and Vinyloxylation of β‑C(sp3)–H Bond of Propionamides with Organosilanes
Published in Organic letters (05-06-2015)“…A novel copper-mediated method for the aryloxylation and vinyloxylation of β-C(sp3)–H bonds of propioamides with organosilanes is described. The reaction…”
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Expeditious synthesis of phenanthridines through a Pd/MnO 2 -mediated C-H arylation/oxidative annulation cascade from aldehydes, aryl iodides and amino acids
Published in Chemical communications (Cambridge, England) (03-03-2020)“…The expeditious construction of phenanthridine scaffolds via a Pd/MnO2-mediated C-H arylation/oxidative annulation cascade involving aldehydes, aryl iodides…”
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Palladium‐catalyzed Atroposelective Interannular C−H Arylation of Biaryl Aldehydes with Aryl Iodides Enabled by a Transient Directing Group Strategy
Published in Advanced synthesis & catalysis (18-10-2022)“…A concise synthesis of axially chiral biaryl aldehydes through Pd/amino acid‐catalyzed atroposelective interannular C−H arylation of biaryl aldehydes with aryl…”
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Catalytic Ring Expansion of Indole toward Dibenzoazepine Analogues Enabled by Cationic Palladium(II) Complexes
Published in ACS catalysis (20-05-2022)“…Catalytic ring expansion serves as a powerful tool for the rapid access to molecular complexity and is of significant importance for chemical synthesis…”
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