Search Results - "Zell, Daniel"

Mild C−H/C−C Activation by Z-Selective Cobalt Catalysis by Zell, Daniel, Bu, Qingqing, Feldt, Milica, Ackermann, Lutz

“…Cationic cobalt complexes enable unprecedented cobalt‐catalyzed C−H/C−C functionalizations with unique selectivity features. The versatile cobalt catalyst…”
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Full Selectivity Control in Cobalt(III)‐Catalyzed C−H Alkylations by Switching of the C−H Activation Mechanism by Zell, Daniel, Bursch, Markus, Müller, Valentin, Grimme, Stefan, Ackermann, Lutz

“…Selectivity control in hydroarylation‐based C−H alkylation has been dominated by steric interactions. A conceptually distinct strategy that exploits the…”
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Ruthenium(II)-Catalyzed C–H Oxygenations of Reusable Sulfoximine Benzamides by Raghuvanshi, Keshav, Zell, Daniel, Ackermann, Lutz

“…C–H oxygenations of synthetically meaningful sulfoximine benzamides were accomplished by a versatile ruthenium catalysis regime. The ruthenium­(II) catalyst…”
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C–F/C–H Functionalization by Manganese(I) Catalysis: Expedient (Per)Fluoro-Allylations and Alkenylations by Zell, Daniel, Dhawa, Uttam, Müller, Valentin, Bursch, Markus, Grimme, Stefan, Ackermann, Lutz

“…C–F/C–H functionalizations proved to be viable within a versatile manganese­(I) catalysis manifold. Thus, a wealth of fluorinated alkenes were employed in…”
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Palladium-Catalyzed Asymmetric Allylic Fluoroalkylation/Trifluoromethylation by Trost, Barry M, Gholami, Hadi, Zell, Daniel

“…The first palladium-catalyzed asymmetric allylic trifluoromethylation is disclosed. The methodology evokes a fundamental principle by which the synergistic…”
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Enantio‐ and Diastereoselective Synthesis of Chiral Allenes by Palladium‐Catalyzed Asymmetric [3+2] Cycloaddition Reactions by Trost, Barry M., Zell, Daniel, Hohn, Christoph, Mata, Guillaume, Maruniak, Autumn

“…A protocol for the asymmetric synthesis of highly substituted chiral allenes with control of point and axial chirality has been developed. A…”
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Ketone-Assisted Ruthenium(II)-Catalyzed C–H Imidation: Access to Primary Aminoketones by Weak Coordination by Raghuvanshi, Keshav, Zell, Daniel, Rauch, Karsten, Ackermann, Lutz

“…The ruthenium­(II)-catalyzed intermolecular C–H imidation with weakly coordinating ketones provided step-economical access to synthetically useful primary…”
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Mild Cobalt(III)‐Catalyzed Allylative C−F/C−H Functionalizations at Room Temperature by Zell, Daniel, Müller, Valentin, Dhawa, Uttam, Bursch, Markus, Presa, Rubén Rubio, Grimme, Stefan, Ackermann, Lutz

“…Sustainable, cobalt‐catalyst enabled, synthetically significant C−F/C−H functionalizations were achieved with an ample substrate scope at an ambient…”
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Single-Component Phosphinous Acid Ruthenium(II) Catalysts for Versatile C−H Activation by Metal-Ligand Cooperation by Zell, Daniel, Warratz, Svenja, Gelman, Dmitri, Garden, Simon J., Ackermann, Lutz

“…Well‐defined ruthenium(II) phosphinous acid (PA) complexes enabled chemo‐, site‐, and diastereoselective C−H functionalization of arenes and alkenes with ample…”
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Asymmetric Iron‐Catalyzed C−H Alkylation Enabled by Remote Ligand meta‐Substitution by Loup, Joachim, Zell, Daniel, Oliveira, João C. A., Keil, Helena, Stalke, Dietmar, Ackermann, Lutz

“…Highly enantioselective iron‐catalyzed C−H alkylations by inner‐sphere C−H activation were accomplished with ample scope. High levels of enantiocontrol proved…”
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Total Synthesis of Kadcoccinic Acid A Trimethyl Ester by Trost, Barry M, Zhang, Guoting, Gholami, Hadi, Zell, Daniel

“…The first total synthesis of the trimethyl ester of kadcoccinic acid A is described. The central structural element of our synthesis is a cyclopentenone motif…”
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Cobalt-catalyzed C-H cyanations: Insights into the reaction mechanism and the role of London dispersion by Detmar, Eric, Müller, Valentin, Zell, Daniel, Ackermann, Lutz, Breugst, Martin

“…Carboxylate-assisted cobalt(III)-catalyzed C-H cyanations are highly efficient processes for the synthesis of (hetero)aromatic nitriles. We have now analyzed…”
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Mild C−H/C−C Activation by Z-Selective Cobalt Catalysis by Zell, Daniel, Bu, Qingqing, Feldt, Milica, Ackermann, Lutz

“…Cationic cobalt complexes enable unprecedented cobalt‐catalyzed C−H/C−C functionalizations with unique selectivity features. The versatile cobalt catalyst…”
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Full Selectivity Control in Cobalt(III)‐Catalyzed C−H Alkylations by Switching of the C−H Activation Mechanism by Zell, Daniel, Bursch, Markus, Müller, Valentin, Grimme, Stefan, Ackermann, Lutz

“…Selectivity control in hydroarylation‐based C−H alkylation has been dominated by steric interactions. A conceptually distinct strategy that exploits the…”
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3d Transition Metals for C–H Activation by Gandeepan, Parthasarathy, Müller, Thomas, Zell, Daniel, Cera, Gianpiero, Warratz, Svenja, Ackermann, Lutz

“…C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with notable applications to material sciences, crop protection, drug…”
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Manganese-Catalyzed Synthesis of cis-β-Amino Acid Esters through Organometallic CH Activation of Ketimines by Liu, Weiping, Zell, Daniel, John, Michael, Ackermann, Lutz

“…Manganese‐catalyzed CH functionalization reactions of ketimines set the stage for the expedient synthesis of cis‐β‐amino acid esters through site‐ and…”
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N‑Acyl Amino Acid Ligands for Ruthenium(II)-Catalyzed meta-C–H tert-Alkylation with Removable Auxiliaries by Li, Jie, Warratz, Svenja, Zell, Daniel, De Sarkar, Suman, Ishikawa, Eloisa Eriko, Ackermann, Lutz

“…Acylated amino acid ligands enabled ruthenium­(II)-catalyzed C–H functionalizations with excellent levels of meta-selectivity. The outstanding catalytic…”
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Stereoconvergent and -divergent Synthesis of Tetrasubstituted Alkenes by Nickel-Catalyzed Cross-Couplings by Zell, Daniel, Kingston, Cian, Jermaks, Janis, Smith, Sleight R, Seeger, Natalie, Wassmer, Jana, Sirois, Lauren E, Han, Chong, Zhang, Haiming, Sigman, Matthew S, Gosselin, Francis

“…We report the development of a method to diastereoselectively access tetrasubstituted alkenes via nickel-catalyzed Suzuki–Miyaura cross-couplings of enol…”
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Scalable Synthesis of 6‑Chloro‑1H‑pyrazolo[3,4‑b]pyrazine via a Continuous Flow Formylation/Hydrazine Cyclization Cascade by Bass, Thomas M., Zell, Daniel, Kelly, Sean M., Malig, Thomas C., Napolitano, José G., Sirois, Lauren E., Han, Chong, Gosselin, Francis

“…Herein, we describe the development of two continuous manufacturing processes for the synthesis of 6-chloro-1H-pyrazolo­[3,4-b]­pyrazine, which is a key…”
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Data Science Guided Multiobjective Optimization of a Stereoconvergent Nickel-Catalyzed Reduction of Enol Tosylates to Access Trisubstituted Alkenes by Romer, Natalie P., Min, Daniel S., Wang, Jason Y., Walroth, Richard C., Mack, Kyle A., Sirois, Lauren E., Gosselin, Francis, Zell, Daniel, Doyle, Abigail G., Sigman, Matthew S.

“…Herein we report a method for a stereoconvergent synthesis of trisubstituted alkenes in two steps from simple ketone starting materials. The key step is a…”
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