Nitration of cyclopentenecarboxaldehyde: Studies toward 1-amino-2-nitrocyclopentanecarboxylic acid

The formation of 2,2-dinitrocyclopentanone oxime is described during an attempted nitroacetamidation of cyclopentenecarboxaldehyde using ceric ammonium nitrate and sodium nitrite in acetonitrile. Progress towards the total synthesis of 1-amino-2-nitrocyclopentanecarboxylic acid is also discussed. Th...

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Bibliographic Details

Published in:	Tetrahedron letters Vol. 39; no. 37; pp. 6617 - 6620
Main Authors:	Smith, Chase C., Jacyno, John M., Zeiter, Kendra K., Parkanzky, Paul D., Paxson, Chad E., Pekelnicky, Peter, Harwood, John S., Hunter, Allen D., Lucarelli, Vincent G., Lufaso, Michael W., Cutler, Horace G.
Format:	Journal Article
Language:	English
Published:	Elsevier Ltd 10-09-1998
Subjects:	Aldehydes Decarbonylation Nitro compounds Oximes Oximes Nitro compounds Decarbonylation Aldehydes
Online Access:	Get full text
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