Synthesis of Improved Catalytic Materials for High-Temperature Water-gas Shift Reaction
In this investigation, we report the preparation and characterization of Co-, Cu- and Mn-substituted iron oxide catalytic materials supported on activated carbon. Co-precipitation method and low temperature treatment were used for their synthesis. The influence of chemical composition, stoichiometry...
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| Published in: | Croatica Chemica Acta Vol. 88; no. 4; pp. 475 - 480 |
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| Main Authors: | , , , , |
| Format: | Journal Article Paper |
| Language: | English |
| Published: |
Hrvatsko kemijsko društvo
01-12-2015
Croatian Chemical Society |
| Subjects: | |
| Online Access: | Get full text |
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| Summary: | In this investigation, we report the preparation and characterization of Co-, Cu- and Mn-substituted iron oxide catalytic materials supported on activated carbon. Co-precipitation method and low temperature treatment were used for their synthesis. The influence of chemical composition, stoichiometry, particle size and dispersity on their catalytic activity was studied. Samples were characterized in all stages of their co-precipitation, heating and spend samples after catalytic tests. The obtained results from room and low temperature Mössbauer spectroscopy were combined with analysis of powder X-ray diffraction patterns (XRD). They revealed the preparation of nano-sized iron oxide materials supported on activated carbon. Relaxation phenomena were registered also for the supported phases. The catalytic performance in the water-gas shift reaction was studied. The activity order was as follows: Cu0.5Fe2.5O4 > Co0.5Fe2.5O4 > Mn0.5Fe2.5O4. Catalytic tests demonstrated very promising results and potential application of studied samples due to their cost-effective composition. |
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| Bibliography: | 154304 |
| ISSN: | 0011-1643 1334-417X |
| DOI: | 10.5562/cca2789 |