Search Results - "Yufit, Dmitry"

Rupturing aromaticity by periphery overcrowding by Saha, Promeet K., Mallick, Abhijit, Turley, Andrew T., Bismillah, Aisha N., Danos, Andrew, Monkman, Andrew P., Avestro, Alyssa-Jennifer, Yufit, Dmitry S., McGonigal, Paul R.

“…The balance between strain relief and aromatic stabilization dictates the form and function of non-planar π-aromatics. Overcrowded systems are known to undergo…”
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Platinum(IV) Complexes with Tridentate, NNC-Coordinating Ligands: Synthesis, Structures, and Luminescence by Dikova, Yana M., Yufit, Dmitry S., Williams, J. A. Gareth

“…Platinum­(II) complexes of NNC-cyclometalating ligands based on 6-phenyl-2,2′-bipyridine (HL1) have been widely investigated for their luminescence properties…”
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Enantioselective synthesis of ammonium cations by Walsh, Mark P., Phelps, Joseph M., Lennon, Marc E., Yufit, Dmitry S., Kitching, Matthew O.

“…Control of molecular chirality is a fundamental challenge in organic synthesis. Whereas methods to construct carbon stereocentres enantioselectively are well…”
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In situ laser irradiation setup for a Bruker three‐circle goniometer by Yufit, Dmitry S.

“…A new design of a setup for in situ laser irradiation of single crystals during an X‐ray diffraction experiment is presented. The system is designed for use…”
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Ruthenium-catalyzed C-H/O-H and C-H/N-H bond functionalizations: oxidative annulations of cyclopropyl-substituted alkynes by Deponti, Monica, Kozhushkov, Sergei I, Yufit, Dmitry S, Ackermann, Lutz

“…The chemical behavior of cyclopropyl-substituted alkynes has been probed using the reaction conditions of ruthenium-catalyzed oxidative C-H/O-H and C-H/N-H…”
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Photoluminescent Thermometer Based on a Phase-Transition Lanthanide Silicate with Unusual Structural Disorder by Ananias, Duarte, Paz, Filipe A. Almeida, Yufit, Dmitry S, Carlos, Luís D, Rocha, João

“…The hydrothermal synthesis of the novel Na[LnSiO4] (Ln = Gd, Eu, Tb) disordered orthorhombic system is reported. At 100 K, and above, these materials are best…”
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Near-infrared electroluminescence beyond 940 nm in Pt(N^C^N)X complexes: influencing aggregation with the ancillary ligand X by Salthouse, Rebecca J, Pander, Piotr, Yufit, Dmitry S, Dias, Fernando B, Williams, J. A. Gareth

“…We present a study of aggregate excited states formed by complexes of the type Pt(N^C^N)X, where N^C^N represents a tridentate cyclometallating ligand, and X =…”
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Interplay between spin crossover and proton migration along short strong hydrogen bonds by Jornet-Mollá, Verónica, Giménez-Saiz, Carlos, Cañadillas-Delgado, Laura, Yufit, Dmitry S, Howard, Judith A. K, Romero, Francisco M

“…The iron( ii ) salt [Fe(bpp) 2 ](isonicNO) 2 ·HisonicNO·5H 2 O ( 1 ) (bpp = 2,6-bis(pyrazol-3-yl)pyridine; isonicNO = isonicotinate N-oxide anion) undergoes a…”
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Ruthenium-Catalyzed Hydroarylation of Methylenecyclopropanes through CH Bond Cleavage: Scope and Mechanism by Ackermann, Lutz, Kozhushkov, Sergei I., Yufit, Dmitry S.

“…Intermolecular hydroarylation reactions of highly strained methylenecyclopropanes 2‐phenylmethylenecyclopropane (1), 2,2‐diphenylmethylenecyclopropane (2),…”
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Scrolling in Supramolecular Gels: A Designer’s Guide by Jones, Christopher D., Kershaw Cook, Laurence J., Slater, Anna G., Yufit, Dmitry S., Steed, Jonathan W.

“…Gelation by small molecules is a topic of enormous importance in catalysis, nanomaterials, drug delivery, and pharmaceutical crystallization. The mechanism by…”
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The crystal engineering of radiation-sensitive diacetylene cocrystals and salts by Hall, Amy V, Yufit, Dmitry S, Apperley, David C, Senak, Larry, Musa, Osama M, Hood, David K, Steed, Jonathan W

“…In this work we develop photoreactive cocrystals/salts of a commercially-important diacetylene, 10,12-pentacosadiynoic acid (PCDA, 1 ) and report the first…”
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Platinum(II) Complexes of Nonsymmetrical NCN-Coordinating Ligands: Unimolecular and Excimeric Luminescence Properties and Comparison with Symmetrical Analogues by Salthouse, Rebecca J., Sil, Amit, Gildea, Louise F., Yufit, Dmitry S., Williams, J. A. Gareth

“…A series of seven new platinum­(II) complexes PtL n Cl have been prepared, where L n is an NCN-coordinating ligand comprising a benzene ring 1,3-disubstituted…”
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A Reversible Hydrogen‐Bond Isomerization Triggered by an Abrupt Spin Crossover near Room Temperature by Jornet‐Mollá, Verónica, Giménez‐Saiz, Carlos, Yufit, Dmitry S., Howard, Judith A. K., Romero, Francisco M.

“…The spin crossover salt [Fe(bpp)2](isonicNO)2⋅ 2.4 H2O (1⋅2.4 H2O) (bpp=2,6‐bis(pyrazol‐3‐yl)pyridine; isonicNO=isonicotinate N‐oxide anion) exhibits a very…”
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α‐Fluorotricarbonyl Derivatives as Versatile Fluorinated Building Blocks: Synthesis of Fluoroacetophenone, Fluoroketo Ester and Fluoropyran‐4‐one Derivatives by Harsanyi, Antal, Lückener, Anne, Pasztor, Hedvig, Yilmaz, Zahide, Tam, Lawrence, Yufit, Dmitry S., Sandford, Graham

“…Fluorinated acyl‐Meldrum's acid derivatives were synthesized by electrophilic fluorination of appropriate phenacyl Meldrum's acid substrates using Selectfluor…”
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Chiral transcription in self-assembled tetrahedral Eu4L6 chiral cages displaying sizable circularly polarized luminescence by Yeung, Chi-Tung, Yim, King-Him, Wong, Ho-Yin, Pal, Robert, Lo, Wai-Sum, Yan, Siu-Cheong, Yee-Man Wong, Melody, Yufit, Dmitry, Smiles, Danil E., McCormick, Laura J., Teat, Simon J., Shuh, David K., Wong, Wing-Tak, Law, Ga-Lai

“…Predictable stereoselective formation of supramolecular assembly is generally believed to be an important but complicated process. Here, we show that point…”
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Understanding the Interaction of Gluconamides and Gluconates with Amino Acids in Hair Care by Chambers, Luke I., Yufit, Dmitry S., Musa, Osama M., Steed, Jonathan W.

“…A hair care mixture formed from a gluconamide derivative and 3-hydroxypropyl ammonium gluconate is known to strengthen hair fibers; however, the mechanism by…”
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The “Magic Linker”: Highly Effective Gelation from Sterically Awkward Packing by Smith, James P, Yufit, Dmitry S, McCabe, James F, Steed, Jonathan W

“…Bis­(urea)­s based on the 4,4′-methylenebis­(2,6-diethylphenylene) (4,4′-MDEP) spacer are highly effective low molecular weight gelators, and the first single…”
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Designer Gelators for the Crystallization of a Salt Active Pharmaceutical IngredientMexiletine Hydrochloride by Andrews, Jessica L., Kennedy, Stuart R., Yufit, Dmitry S., McCabe, James F., Steed, Jonathan W.

“…We report an approach to obtain drug-mimetic supramolecular gelators, which are capable of stabilizing metastable polymorphs of the pharmaceutical salt…”
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Combined Spectroscopic and Quantum Chemical Study of [trans-Ru(CCC6H4R1‑4)2(dppe)2] n+ and [trans-Ru(CCC6H4R1‑4)(CCC6H4R2‑4)(dppe)2] n+ (n = 0, 1) Complexes: Interpretations beyond the Lowest Energy Conformer Paradigm by Marqués-González, Santiago, Parthey, Matthias, Yufit, Dmitry S, Howard, Judith A. K, Kaupp, Martin, Low, Paul J

“…The reaction of trans-RuCl­(CCC6H4R1-4)­(dppe)2 (2: R1 = Me (a), C5H11 (b), OMe (c), CO2Me (d), NO2 (e), CCSiMe3 (f), CCBut (g), NH2 (h)), prepared in situ…”
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Supramolecular Gelation as the First Stage in Ostwald’s Rule by Andrews, Jessica L, Pearson, Emma, Yufit, Dmitry S, Steed, Jonathan W, Edkins, Katharina

“…Ostwald’s rule of stages describes the observation that a metastable polymorph of a particular compound will crystallize before the thermodynamically stable…”
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