Search Results - "Young, Ralph H."
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Solvent Dependence of Cationic-Exciplex Emission: Limitation of Solvent Polarity Functions and the Role of Hydrogen Bonding
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14-05-2020)“…Conventional exciplexes are products of excited-state charge generation reactions between neutral reactants (e.g., A* + D → A•–D•+), whereas cationic…”
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Reexamination of the Rehm–Weller Data Set Reveals Electron Transfer Quenching That Follows a Sandros–Boltzmann Dependence on Free Energy
Published in Journal of the American Chemical Society (03-08-2011)“…In a landmark publication over 40 years ago, Rehm and Weller (RW) showed that the electron transfer quenching constants for excited-state molecules in…”
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Narrow-Line and Broadband Spectra of Iridium(III) Complexes in a Shpol'skii Matrix and an Amorphous Host
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (17-08-2006)“…Narrow-line emission and excitation spectra of the lowest triplet state have been studied in a Shpol'skii host (n-octane) for three cyclometalated IrL2acac…”
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Mechanisms of Exciplex Formation. Roles of Superexchange, Solvent Polarity, and Driving Force for Electron Transfer
Published in Journal of the American Chemical Society (01-09-1994)Get full text
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Bimolecular Electron Transfers That Follow a Sandros−Boltzmann Dependence on Free Energy
Published in Journal of the American Chemical Society (06-04-2011)“…Rate constants (k) for exergonic and endergonic electron-transfer reactions of equilibrating radical cations (A•+ + B ⇌ A + B•+) in acetonitrile could be fit…”
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Transition from Charge-Transfer to Largely Locally Excited Exciplexes, from Structureless to Vibrationally Structured Emissions
Published in Photochemistry and photobiology (01-05-2015)“…Exciplexes of 9,10‐dicyanoanthracene (DCA) with alkylbenzene donors in cyclohexane show structureless emission spectra, typical of exciplexes with…”
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Bimolecular Electron Transfers That Deviate from the Sandros–Boltzmann Dependence on Free Energy: Steric Effect
Published in Journal of organic chemistry (17-02-2012)“…As we reported recently, endergonic to mildly exergonic electron transfer between neutral aromatics (benzenes and biphenyls) and their radical cations in…”
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Current-induced fluorescence quenching in organic light-emitting diodes
Published in Applied physics letters (04-02-2002)“…The electroluminescence quantum efficiency of organic light-emitting diodes with a doped Alq [tris(8-quinolinolato)aluminum] emitting layer is found to…”
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Reducing Power of Photogenerated α-Hydroxy Radicals. Proton-Coupled Electron Transfer
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (25-11-2004)“…Proton-coupled electron transfer (PCET) has been reported in a number of systems. The oxidation product of a disubstituted α-hydroxy radical is a protonated…”
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Photophysical Properties of the Series fac- and mer-(1-Phenylisoquinolinato-N∧C2′ ) x (2-phenylpyridinato-N∧C2′ )3−x Iridium(III) (x = 1−3)
Published in Inorganic chemistry (18-10-2010)“…The photophysical properties of tris-cyclometalated iridium(III) complexes have been probed by chemical and geometric variation through the series fac- and…”
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Contact and solvent-separated geminate radical ion pairs in electron-transfer photochemistry
Published in Journal of physical chemistry (1952) (01-03-1991)“…The two primary intermediates that play a major role in determining the efficiencies of bimolecular photoinduced electron-transfer reactions are the contact…”
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Charge carriers and charge-transfer reactions in OLED devices studied by electron paramagnetic resonance
Published in Journal of the Society for Information Display (01-04-2010)“…— Electron paramagnetic resonance (EPR) was used as a quantitative method to measure charge carriers that are present in OLED devices under various bias…”
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Charge-retraction time-of-flight measurement for organic charge transport materials
Published in Applied physics letters (08-10-2007)“…This letter describes an all-electrical technique, charge-retraction time-of-flight (CR-TOF), to measure charge carrier mobility through an organic layer…”
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E-Type Delayed Fluorescence of a Phosphine-Supported Cu2(μ-NAr2)2 Diamond Core: Harvesting Singlet and Triplet Excitons in OLEDs
Published in Journal of the American Chemical Society (14-07-2010)“…A highly emissive bis(phosphine)diarylamido dinuclear copper(I) complex (quantum yield = 57%) was shown to exhibit E-type delayed fluorescence by variable…”
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Electronic Structures of Exciplexes and Excited Charge-Transfer Complexes
Published in Journal of the American Chemical Society (01-09-1994)Get full text
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Charge-Induced Luminescence Quenching in Organic Light-Emitting Diodes
Published in Chemistry of materials (16-11-2004)“…We use charge modulation spectroscopy (CMS) in model holes-only devices to address the reason for decreasing quantum efficiency with increasing drive current…”
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Dipole Moments, Energetic Disorder, and Charge Transport in Molecularly Doped Polymers
Published in Journal of physical chemistry (1952) (01-06-1995)Get full text
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Kinetics of Isomerization via Photoinduced Electron Transfer. I. Spectral Analysis and Structural Reorganization of Hexamethyl Dewar Benzene Exciplexes
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (15-05-2003)“…It is well recognized that emission spectra from the reactions of excited-state electron acceptors (A*) with hexamethyl Dewar benzene (D) are typically…”
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