Search Results - "Young, Kenneth J.H."
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Perspectives on some challenges and approaches for developing the next generation of selective, low temperature, oxidation catalysts for alkane hydroxylation based on the CH activation reaction
Published in Journal of molecular catalysis. A, Chemical (27-09-2004)“…Challenges and approaches to the de novo, rational development of the next generation of organometallic, alkane functionalization catalysts based on the CH…”
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2
Design and study of homogeneous catalysts for the selective, low temperature oxidation of hydrocarbons
Published in Journal of molecular catalysis. A, Chemical (17-05-2006)“…The direct, low temperature conversion of hydrocarbons to functionalized products using novel, single site catalysts could lead to technological advances that…”
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3
Acceleration of Nucleophilic CH Activation by Strongly Basic Solvents
Published in Journal of the American Chemical Society (15-09-2010)“…(IPI)Ru(II)(OH) n (H2O) m , 2, where IPI is the NNN-pincer ligand, 2,6-diimidizoylpyridine, is shown to catalyze H/D exchange between hydrocarbons and strongly…”
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Stoichiometric Oxy Functionalization and CH Activation Studies of Cyclometalated Iridium(III) 6-Phenyl-2,2‘-Bipyridine Hydrocarbyl Complexes
Published in Organometallics (23-04-2007)“…A well-defined, thermal-, air-, and protic-stable, bis-bidentate, cyclometalated Ir(III) complex, Ir(NC)(NNtBu)CH3OTf, (2-CH 3 ; NC =…”
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5
CH Activation with an O-Donor Iridium−Methoxo Complex
Published in Journal of the American Chemical Society (19-10-2005)“…A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometric, intermolecular C−H activation of benzene with…”
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Cyclometalation of 6-Phenyl-2,2′-Bipyridine and Iridium: Synthesis, Characterization, and Reactivity Studies
Published in Organometallics (22-06-2009)“…Heating the potential tridentate 6-(4-R-phenyl)-2,2′-bipyridine ligand 1a (R = H), and derivatives 1b (R = CMe3) and 1c (R = OH), with IrCl3 hydrate in…”
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Synthesis, characterization, and cyclometalation studies of benzo[1,2-h: 5,4-h′]diquinolines with palladium and platinum
Published in Journal of organometallic chemistry (15-12-2011)“…Benzo[1,2-h: 5,4-h′]diquinoline( 1a) represents a new family of tridentate NCN pincer ligand. We report the synthesis of the parent ligand ( 1a) and its…”
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Heterolytic Benzene C−H Activation by a Cyclometalated Iridium(III) Dihydroxo Pyridyl Complex: Synthesis, Hydrogen−Deuterium Exchange, and Density Functional Study
Published in Organometallics (28-09-2009)“…We report the synthesis of the pincer-cyclometalated (NNC t-Bu)Ir(III) dihydroxo pyridyl complex 6, which catalyzes hydrogen−deuterium (H/D) exchange between…”
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Heterolytic CH Activation and Catalysis by an O-Donor Iridium−Hydroxo Complex
Published in Organometallics (09-10-2006)“…A well-defined, O-donor ligated iridium hydroxide complex is reported that is competent for benzene CH activation and long-lived catalytic H/D exchange between…”
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Heterolytic CH Activation with a Cyclometalated Platinum(II) 6-Phenyl-4,4‘-di-tert-butyl-2,2-Bipyridine Complex
Published in Organometallics (25-09-2006)“…The more electron-rich, thermally, air, and protic stable, cyclometalated Pt(II)(NNC) trifluoroacetate complex (3) (NNC =…”
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Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer
Published in Journal of the American Chemical Society (19-07-2006)“…The facile conversion of M−R to M−OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a…”
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Journal Article -
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Synthesis of osmium and ruthenium complexes bearing dimethyl (S,S)-2,2′-(pyridine-2,6-diyl)-bis-(4,5-dihydrooxazol-4-carboxylate) ligand and application to catalytic H/D exchange
Published in Journal of molecular catalysis. A, Chemical (01-04-2011)“…Using tridentate, neutral PyBox ligands, several new osmium and ruthenium complexes [M(PyBox)Cl 2(C 2H 4), where M = Ru, Os] have been prepared, all thermally…”
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Variable solid state aggregations in a series of (isocyanide)gold(I) halides with the novel trimethylamine-isocyanoborane adduct
Published in Dalton transactions : an international journal of inorganic chemistry (07-02-2005)“…This paper provides evidence that the degree of aurophilic character and resulting solid state arrangement observed in (isocyanide)gold(I) halides is in part…”
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