Search Results - "Young, Kenneth J. H"

Acceleration of Nucleophilic CH Activation by Strongly Basic Solvents by Hashiguchi, Brian G, Young, Kenneth J. H, Yousufuddin, Muhammed, Goddard, William A, Periana, Roy A

“…(IPI)Ru(II)(OH) n (H2O) m , 2, where IPI is the NNN-pincer ligand, 2,6-diimidizoylpyridine, is shown to catalyze H/D exchange between hydrocarbons and strongly…”
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CH Activation with an O-Donor Iridium−Methoxo Complex by Tenn, William J, Young, Kenneth J. H, Bhalla, Gaurav, Oxgaard, Jonas, Goddard, William A, Periana, Roy A

“…A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometric, intermolecular C−H activation of benzene with…”
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Heterolytic CH Activation and Catalysis by an O-Donor Iridium−Hydroxo Complex by Tenn, William J, Young, Kenneth J. H, Oxgaard, Jonas, Nielsen, Robert J, Goddard, William A, Periana, Roy A

“…A well-defined, O-donor ligated iridium hydroxide complex is reported that is competent for benzene CH activation and long-lived catalytic H/D exchange between…”
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Carboxylic Solvents and O-Donor Ligand Effects on CH Activation by Pt(II) by Ziatdinov, Vadim R, Oxgaard, Jonas, Mironov, Oleg A, Young, Kenneth J. H, Goddard, William A, Periana, Roy A

“…We report on the design of more efficient C−H activation catalysts based on DFT calculations. The first examples of well-defined, N,O-donor ligated platinum…”
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Facile Functionalization of a Metal Carbon Bond by O-Atom Transfer by Conley, Brian L, Ganesh, Somesh K, Gonzales, Jason M, Tenn, William J, Young, Kenneth J. H, Oxgaard, Jonas, Goddard, William A, Periana, Roy A

“…The facile conversion of M−R to M−OR that could be useful for the functionalization of electron-rich metal alkyl intermediates is shown to proceed via a…”
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Design and study of homogeneous catalysts for the selective, low temperature oxidation of hydrocarbons by Conley, Brian L., Tenn, William J., Young, Kenneth J.H., Ganesh, Somesh K., Meier, Steven K., Ziatdinov, Vadim R., Mironov, Oleg, Oxgaard, Jonas, Gonzales, Jason, Goddard, William A., Periana, Roy A.

“…The direct, low temperature conversion of hydrocarbons to functionalized products using novel, single site catalysts could lead to technological advances that…”
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Variable solid state aggregations in a series of (isocyanide)gold(I) halides with the novel trimethylamine-isocyanoborane adduct by Humphrey, Simon M, Mack, Hans-Georg, Redshaw, Carl, Elsegood, Mark R J, Young, Kenneth J H, Mayer, Hermann A, Kaska, William C

“…This paper provides evidence that the degree of aurophilic character and resulting solid state arrangement observed in (isocyanide)gold(I) halides is in part…”
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Cyclometalation of 6-Phenyl-2,2′-Bipyridine and Iridium: Synthesis, Characterization, and Reactivity Studies by Young, Kenneth J. H, Yousufuddin, Muhammed, Ess, Daniel H, Periana, Roy A

“…Heating the potential tridentate 6-(4-R-phenyl)-2,2′-bipyridine ligand 1a (R = H), and derivatives 1b (R = CMe3) and 1c (R = OH), with IrCl3 hydrate in…”
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Heterolytic Benzene C−H Activation by a Cyclometalated Iridium(III) Dihydroxo Pyridyl Complex: Synthesis, Hydrogen−Deuterium Exchange, and Density Functional Study by Meier, Steven K, Young, Kenneth J. H, Ess, Daniel H, Tenn, William J, Oxgaard, Jonas, Goddard, William A, Periana, Roy A

“…We report the synthesis of the pincer-cyclometalated (NNC t-Bu)Ir(III) dihydroxo pyridyl complex 6, which catalyzes hydrogen−deuterium (H/D) exchange between…”
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Heterolytic CH Activation with a Cyclometalated Platinum(II) 6-Phenyl-4,4‘-di-tert-butyl-2,2-Bipyridine Complex by Young, Kenneth J. H, Meier, Steven K, Gonzales, Jason M, Oxgaard, Jonas, Goddard, William A, Periana, Roy A

“…The more electron-rich, thermally, air, and protic stable, cyclometalated Pt(II)(NNC) trifluoroacetate complex (3) (NNC =…”
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Synthesis of osmium and ruthenium complexes bearing dimethyl (S,S)-2,2′-(pyridine-2,6-diyl)-bis-(4,5-dihydrooxazol-4-carboxylate) ligand and application to catalytic H/D exchange by Young, Kenneth J.H., Lokare, Kapil S., Leung, Chin Hin, Cheng, Mu-Jeng, Nielsen, Robert J., Petasis, Nicos A., Goddard, William A., Periana, Roy A.

“…Using tridentate, neutral PyBox ligands, several new osmium and ruthenium complexes [M(PyBox)Cl 2(C 2H 4), where M = Ru, Os] have been prepared, all thermally…”
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The Synthesis, X-ray Crystal Structure, and Molecular Structure of Rhenium Tetra- carbonylbromidetrimethylamineisocyanoborane by Andersen, Wendy C, Mitchell, Daniel R, Young, Kenneth J. H, Bu, Xianhui, Lynch, Vincent M, Mayer, Hermann A, Kaska, William C

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Stoichiometric Oxy Functionalization and CH Activation Studies of Cyclometalated Iridium(III) 6-Phenyl-2,2‘-Bipyridine Hydrocarbyl Complexes by Young, Kenneth J. H., Mironov, Oleg A., Periana, Roy A.

“…A well-defined, thermal-, air-, and protic-stable, bis-bidentate, cyclometalated Ir(III) complex, Ir(NC)(NNtBu)CH3OTf, (2-CH 3 ; NC =…”
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Synthesis, characterization, and cyclometalation studies of benzo[1,2-h: 5,4-h′]diquinolines with palladium and platinum by Young, Kenneth J.H., Bu, Xianhui, Kaska, William C.

“…Benzo[1,2-h: 5,4-h′]diquinoline( 1a) represents a new family of tridentate NCN pincer ligand. We report the synthesis of the parent ligand ( 1a) and its…”
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Acceleration of Nucelophilic CH Activation by Strongly Basic Solvents by Hashiguchi, Brian G, Young, Kenneth J. H., Yousufuddin, Muhammed, Goddard, William A, Periana, Roy A

“…(IPI)Ru(II)(OH){sub n}(H{sub 2}O){sub m}, 2, where IPI is the NNN-pincer ligand, 2,6-diimidizoylpyridine, is shown to catalyze H/D exchange between…”
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Synthesis and Characterization of the κ 2 -acac- O , O Complex Os IV (acac) 2 PhCl and Study of CH Activation with Benzene by Young, Kenneth J. H., Mironov, Oleg A., Nielsen, Robert J., Cheng, Mu-Jeng, Stewart, Timothy, Goddard, William A., Periana, Roy A.

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Synthesis of osmium and ruthenium complexes bearing dimethyl (S,S)-2,2'-(pyridine-2,6-diyl)-bis-(4,5-dihydrooxazol-4-carboxylate) ligand and application to catalytic H/D exchange by Young, Kenneth J. H., Lokare, Kapil S., Leung, Chin Hin, Cheng, Mu-Jeng, Nielsen, Robert J., Petasis, Nicos A., Goddard, William A., Periana, Roy A.

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Perspectives on some challenges and approaches for developing the next generation of selective, low temperature, oxidation catalysts for alkane hydroxylation based on the CH activation reaction: Heterogeneous Catalysis for Selective Oxidation by PERIANA, Roy A, BHALLA, Gaurav, TENN, William J, YOUNG, Kenneth J. H, XIANG YANG LIU, MIRONOV, Oleg, JONES, C. J, ZIATDINOV, Vadim R

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Synthesis and Characterization of the κ2-acac-O,O Complex OsIV(acac)2PhCl and Study of CH Activation with Benzene by Young, Kenneth J. H, Mironov, Oleg A, Nielsen, Robert J, Cheng, Mu-Jeng, Stewart, Timothy, Goddard, William A, Periana, Roy A

“…We have synthesized and fully characterized the air-stable complex (κ2-acac-O,O)2OsIV(Ph)Cl (Cl-1-Ph; acac-O,O = acetylacetonate), which reacts with C6D6 to…”
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