Search Results - "Young, Charles G."
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Reactivity Studies of Oxo–Mo(IV) Complexes Containing Potential Hydrogen-Bond Acceptor/Donor Phenolate Ligands
Published in Inorganic chemistry (05-03-2012)“…Reactivity studies of oxo–Mo(IV) complexes, Tp iPrMoO{2-OC6H4C(O)R-κ2 O,O′} (R = Me, Et, OMe, OEt, OPh, NHPh), containing chelated hydrogen-bond…”
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2
Scorpionate Complexes as Models for Molybdenum Enzymes
Published in European journal of inorganic chemistry (01-06-2016)“…Scorpionate ligands have supported the development of a number of important synthetic models for pterin‐containing molybdenum enzymes. These ligands stabilize…”
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3
Paramagnetic Active Site Models for the Molybdenum−Copper Carbon Monoxide Dehydrogenase
Published in Journal of the American Chemical Society (22-02-2006)“…New paramagnetic, heterobimetallic Mo/Cu complexes featuring the Mo(O)(μ-S)Cu core of O. carboxidovorans carbon monoxide dehydrogenase have been synthesized…”
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Mechanistic Investigation of the Oxygen-Atom-Transfer Reactivity of Dioxo-molybdenum(VI) Complexes
Published in Chemistry : a European journal (25-09-2006)“…The oxygen‐atom‐transfer (OAT) reactivity of [LiPrMoO2(OPh)] (1, LiPr=hydrotris(3‐isopropylpyrazol‐1‐yl)borate) with the tertiary phosphines PEt3 and PPh2Me in…”
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5
Synthesis, Iodometric Analysis, and IR Spectroscopy of the Peroxide Double Salt [Zn(NH3)4][Mo(O2)4]
Published in Journal of chemical education (14-04-2020)“…This paper describes an upper-division undergraduate exercise involving the synthesis and iodometric and infrared spectroscopic analysis of the peroxide double…”
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6
Synthesis and Iodometric Analysis of the Polyiodide Salt (NMe4)[I5]
Published in Journal of chemical education (14-04-2020)“…This paper describes a first-year undergraduate exercise involving the synthesis of an “unknown” polyiodide salt, (NMe4)[I5], and the determination of its…”
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7
Chemical systems modeling the d1 Mo(V) states of molybdenum enzymes
Published in Journal of inorganic biochemistry (01-09-2016)“…This review focuses on the synthesis, properties and electron paramagnetic resonance (EPR), electron spin echo envelope modulation (ESEEM) and electron-nuclear…”
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Toward Multifunctional Mo(VI−IV) Complexes: cis-Dioxomolybdenum(VI) Complexes Containing Hydrogen-Bond Acceptors or Donors
Published in Inorganic chemistry (04-02-2008)“…The complexes cis-Tp i PrMoVIO2(OAr-R) (Tp i Pr = hydrotris(3-isopropylpyrazol-1-yl)borate, -OAr-R = hydrogen-bonding phenolate derivative) are formed upon…”
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9
Synthesis, Structural Characterization, and Multifrequency Electron Paramagnetic Resonance Studies of Mononuclear Thiomolybdenyl Complexes
Published in Inorganic chemistry (02-04-2007)“…Reaction of Tp*MoVSCl2 with a variety of phenols and thiols in the presence of triethylamine produces mononuclear, thiomolybdenyl complexes Tp*MoVSX2 [Tp* =…”
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10
Synthesis, characterization and X-ray crystal structure of TpWII{(R)-(+)-NHCH(Me)Ph}(CO)2
Published in Inorganica Chimica Acta (01-01-2021)“…The chiral complex Tp*WII{(R)-(+)-NHCH(Me)Ph}(CO)2 has been synthesized and spectroscopically and structurally characterized. It has the potential to reduce…”
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11
Mercury Lα1 High Energy Resolution Fluorescence Detected X‑ray Absorption Spectroscopy: A Versatile Speciation Probe for Mercury
Published in Inorganic chemistry (04-04-2022)“…Mercury is in some sense an enigmatic element. The element and some of its compounds are a natural part of the biogeochemical cycle; while many of these can be…”
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12
Tungsten Ligand-Based Sulfur-Atom-Transfer Catalysts: Synthesis, Characterization, Sustained Anaerobic Catalysis, and Mode of Aerial Deactivation
Published in Inorganic chemistry (07-12-2020)“…The synthesis, properties, X-ray structures, and catalytic sulfur-atom-transfer (SAT) reactions of W2(μ-S)(μ-S2)(dtc)2(dped)2 [1; dtc = S2CNR2 –, where R =…”
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13
Mononuclear Sulfido-Tungsten(V) Complexes: Completing the TpMEXY (M = Mo, W; E = O, S) Series
Published in Inorganic chemistry (01-05-2017)“…Orange Tp*WSCl2 has been synthesized from the reactions of Tp*WOCl2 with boron sulfide in refluxing toluene or Tp*WS2Cl with PPh3 in dichloromethane at room…”
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14
Photoinduced Ligand Isomerization in Dimethyl Sulfoxide Complexes of Ruthenium(II)
Published in European journal of inorganic chemistry (01-06-2000)“…Abstract only…”
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15
Facets of early transition metal–sulfur chemistry: Metal–sulfur ligand redox, induced internal electron transfer, and the reactions of metal–sulfur complexes with alkynes
Published in Journal of inorganic biochemistry (01-11-2007)“…Metal–sulfur ligand redox interplay, induced internal electron transfer reactions, and the generation of dithiolene and organosulfur ligands in the reactions…”
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16
Influence of the oxygen atom acceptor on the reaction coordinate and mechanism of oxygen atom transfer from the dioxo-Mo(VI) complex, Tp(iPr)MoO(2)(OPh), to tertiary phosphines
Published in Inorganic chemistry (07-06-2010)“…The oxygen atom transfer reactivity of the dioxo-Mo(VI) complex, Tp(iPr)MoO(2)(OPh) (Tp(iPr) = hydrotris(3-isopropylpyrazol-1-yl)borate), with a range of…”
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17
Models for aerobic carbon monoxide dehydrogenase: synthesis, characterization and reactivity of paramagnetic Mo V O(μ-S)Cu I complexes
Published in Chemical science (Cambridge) (28-01-2018)“…Reaction of [CoCp ][Tp MoOS(OAr)] [Cp = η -cyclopentadienyl; Tp = hydrotris(3-isopropylpyrazol-1-yl)borate; OAr = phenolate or derivative thereof] with…”
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18
Formation of Mono(dithiolene)−Thiocarboxamido Complexes in Reactions of Thio(dithiocarbamato)−Mo/W Complexes and Dimethyl Acetylenedicarboxylate
Published in Inorganic chemistry (10-01-2005)“…Reactions of Tp*MS(S2CNEt2) with dimethyl acetylenedicarboxylate in dichloromethane produce olive green/black Tp*M{S2C2(CO2Me)2}(SCNEt2-κ2 S,C) (M = Mo (1), W…”
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Synthesis, characterization and metal ion complexation and extraction capabilities of calix[4]arene Schiff base compounds
Published in Tetrahedron (14-10-2013)“…The syntheses, characterization and metal ion complexation and extraction capabilities of six new calix[4]arene Schiff base compounds, 5–10, are reported. The…”
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20
d(1) Oxosulfido-Mo(V) Compounds: First Isolation and Unambiguous Characterization of an Extended Series
Published in Inorganic chemistry (06-07-2015)“…Reaction of Tp(iPr)Mo(VI)OS(OAr) with cobaltocene in toluene results in the precipitation of brown, microcrystalline oxosulfido-Mo(V) compounds,…”
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