Search Results - "Yin, Guan‐Wu"
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Controllable Si−C Bond Activation Enables Stereocontrol in the Palladium‐Catalyzed [4+2] Annulation of Cyclopropenes with Benzosilacyclobutanes
Published in Angewandte Chemie International Edition (07-01-2020)“…A novel and unusual palladium‐catalyzed [4+2] annulation of cyclopropenes with benzosilacyclobutanes is reported. This reaction occurred through chemoselective…”
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Stereospecific Si-C coupling and remote control of axial chirality by enantioselective palladium-catalyzed hydrosilylation of maleimides
Published in Nature communications (09-06-2020)“…Hydrosilylation of unsaturated carbon-carbon bonds with hydrosilanes is a very important process to access organosilicon compounds and ranks as one of the most…”
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Enantioselective palladium-catalyzed C(sp)-C(sp) σ bond activation of cyclopropenones by merging desymmetrization and (3 + 2) spiroannulation with cyclic 1,3-diketones
Published in Chemical science (Cambridge) (27-10-2021)“…Catalytic asymmetric variants for functional group transformations based on carbon-carbon bond activation still remain elusive. Herein we present an…”
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Asymmetric Disilylation of Spirocyclic Palladacyclopentanes via Tandem Heck/C−H Activation of Aryl Iodides
Published in Asian journal of organic chemistry (01-11-2021)“…The synthesis of chiral organosilicon compounds is highly appealing due to their wide and important applications in synthetic chemistry and medicinal science…”
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Catalytic Asymmetric trans-Selective Hydrosilylation of Bisalkynes to Access AIE and CPL-Active Silicon-Stereogenic Benzosiloles
Published in iScience (24-07-2020)“…Chirality widely exists in a diverse array of biologically active molecules and life forms, and the catalytic constructions of chiral molecules have triggered…”
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Enantioselective Rhodium-Catalyzed Desymmetric Hydrosilylation of Cyclopropenes
Published in ACS catalysis (04-10-2019)“…Catalytic hydrosilylation of alkenes ranks as one of the most important academic and industrial synthetic reactions in homogeneous catalysis and organosilicon…”
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Palladium-catalyzed hydrosilylation of ynones to access silicon-stereogenic silylenones by stereospecific aromatic interaction-assisted Si-H activation
Published in Science China. Chemistry (01-05-2021)“…Hydrosilylation is one of the most important reactions in synthetic chemistry and ranks as a fundamental method to access organosilicon compounds in industrial…”
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Cyclotriphophazene-Centered Six-Arm Eugenol-Linked Low-Dielectric Materials with High Thermostability and Transparency
Published in ACS sustainable chemistry & engineering (03-10-2022)“…Two silicon-containing eugenol-based benzocyclobutene monomers were prepared by a simple solvent-free hydrosilylation reaction. After heat treatment, a series…”
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Frontispiece: Controllable Si−C Bond Activation Enables Stereocontrol in the Palladium‐Catalyzed [4+2] Annulation of Cyclopropenes with Benzosilacyclobutanes
Published in Angewandte Chemie International Edition (07-01-2020)“…Silacycles In their Research Article on page 790, L.‐W. Xu et al. present a stereoselective functionalization of cyclopropenes with benzosilacyclobutanes via…”
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Silicon-mediated enantioselective synthesis of structurally diverse α-amino acid derivatives
Published in Science China. Chemistry (01-08-2020)“…The catalytic asymmetric synthesis of novel and chiral amino acid derivatives with unconventional chemo-, diastereo-, and enantio-selectivity remains a…”
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Swollen-induced in-situ encapsulation of chiral silver catalysts in cross-linked polysiloxane elastomers: Homogeneous reaction and heterogeneous separation
Published in Molecular catalysis (01-10-2021)“…•Swollen-induced in-situ encapsulation of catalysts in cross-linked polysiloxane elastomers polymer.•Silicone rubber-based microchannel reactor was employed…”
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Controllable Si−C Bond Activation Enables Stereocontrol in the Palladium‐Catalyzed [4+2] Annulation of Cyclopropenes with Benzosilacyclobutanes
Published in Angewandte Chemie (07-01-2020)“…A novel and unusual palladium‐catalyzed [4+2] annulation of cyclopropenes with benzosilacyclobutanes is reported. This reaction occurred through chemoselective…”
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Journal Article -
13
Frontispiz: Controllable Si−C Bond Activation Enables Stereocontrol in the Palladium‐Catalyzed [4+2] Annulation of Cyclopropenes with Benzosilacyclobutanes
Published in Angewandte Chemie (07-01-2020)“…Silacyclen In ihrem Forschungsartikel auf S. 800 stellen L.‐W. Xu et al. eine stereoselektive Funktionalisierung von Cyclopropenen mit Benzosilacyclobutanen…”
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14
Anatomical study of endoscope-assisted far lateral keyhole approach to the ventral craniocervical region with neuronavigational guidance
Published in Chinese medical journal (05-05-2013)“…Background Image-guided neurosurgery, endoscopic-assisted neurosurgery and the keyhole approach are three important parts of minimally invasive neurosurgery…”
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