Search Results - "Yian Shi"
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Catalytic Diamination of Olefins via N–N Bond Activation
Published in Accounts of chemical research (16-12-2014)“…Vicinal diamines are important structural motifs present in various biologically and chemically significant molecules. Direct diamination of olefins provides…”
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2
Organocatalytic Oxidation. Asymmetric Epoxidation of Olefins Catalyzed by Chiral Ketones and Iminium Salts
Published in Chemical reviews (01-09-2008)“…Advancements on the asymmetric epoxidation of olefins as an approach for preparing chiral expoxides are discussed. Chiral ketones and chiral iminum salts are…”
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3
A Pd-Catalyzed Site-Controlled Isomerization of Terminal Olefins
Published in Organic letters (06-03-2020)“…An effective Pd-catalyzed isomerization of olefins with 2-PyPPh2 as the ligand is described. A wide variety of trans-2-olefins bearing various functional…”
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4
Organocatalytic Asymmetric Epoxidation of Olefins by Chiral Ketones
Published in Accounts of chemical research (01-08-2004)“…Chiral ketones have been shown to be effective organocatalysts for asymmetric epoxidation of olefins with broad substrate scope. High enantioselectivity has…”
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5
Catalytic Asymmetric Allylic and Homoallylic Diamination of Terminal Olefins via Formal C−H Activation
Published in Journal of the American Chemical Society (09-07-2008)“…This paper describes a catalytic asymmetric diamination process for terminal olefins at allylic and homoallylic carbons via formal C−H activation using…”
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6
Synthetic and Mechanistic Studies on Pd(0)-Catalyzed Diamination of Conjugated Dienes
Published in Journal of the American Chemical Society (17-03-2010)“…Various dienes and a triene can be regioselectively diaminated at the internal double bond with good yields and high diastereoselectivity using…”
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7
Progress in asymmetric biomimetic transamination of carbonyl compounds
Published in Chemical Society reviews (07-04-2015)“…Transamination of α-keto acids with transaminases and pyridoxamine phosphate is an important process to form optically active α-amino acids in biological…”
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8
Enantioselective Bromocyclization of Olefins Catalyzed by Chiral Phosphoric Acid
Published in Organic letters (16-12-2011)“…A chiral phosphoric acid catalyzed enantioselective bromocyclization of olefins is described. Various cis-, trans-, or trisubstituted γ-hydroxy-alkenes and…”
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9
Enantioselective oxysulfenylation and oxyselenenylation of olefins catalyzed by chiral Brønsted acids
Published in Tetrahedron (25-03-2012)“…This paper describes Brønsted acid catalyzed enantioselective oxysulfenylation and oxyselenenylation of olefins. Enantiomerically enriched tetrahydrofurans are…”
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10
A Facile Pd(0)-Catalyzed Regio- and Stereoselective Diamination of Conjugated Dienes and Trienes
Published in Journal of the American Chemical Society (31-01-2007)“…This paper describes a novel diamination process using di-t-butyldiaziridinone as the nitrogen source and Pd(PPh3)4 as catalyst. A wide variety of conjugated…”
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11
Copper-Catalyzed Oxidative Homo- and Cross-Coupling of Grignard Reagents Using Diaziridinone
Published in Organic letters (05-12-2014)“…Transition-metal-catalyzed cross-coupling reactions are among the most powerful synthetic transformations. This paper describes an efficient copper-catalyzed…”
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12
Enantioselective Bromoaminocyclization of Allyl N‑Tosylcarbamates Catalyzed by a Chiral Phosphine–Sc(OTf)3 Complex
Published in Journal of the American Chemical Society (05-06-2013)“…An effective enantioselective bromoaminocyclization of allyl N-tosylcarbamates catalyzed by a chiral phosphine–Sc(OTf)3 complex is described. A wide variety of…”
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13
Total Synthesis of the Proposed Structure of Marineosin A
Published in Organic letters (06-05-2016)“…A total synthesis of a proposed structure of marineosin A has been achieved. The key steps involve Lewis acid catalyzed spirocyclizaton, ring-closing…”
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14
An efficient synthesis of optically active trifluoromethyl aldimines via asymmetric biomimetic transamination
Published in Chemical communications (Cambridge, England) (01-01-2013)“…This communication describes a chiral base-catalyzed asymmetric [1,3]-proton shift of trifluoromethyl ketimines, giving a wide variety of trifluoromethyl…”
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15
Enantioselective 6-exo-Bromoaminocyclization of Homoallylic N‑Tosylcarbamates Catalyzed by a Novel Monophosphine-Sc(OTf)3 Complex
Published in Organic letters (21-08-2015)“…A highly enantioselective 6-exo-bromoaminocyclization of (E)-homoallylic N-tosylcarbamates catalyzed by a novel monophosphine-Sc(OTf)3 complex is described,…”
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16
Cu(I)-Catalyzed Diamination of Conjugated Olefins with Tunable Anionic Counterions. A Possible Approach to Asymmetric Diamination
Published in Journal of organic chemistry (06-11-2009)“…Various achiral and chiral Cu(I) salts have been prepared from mesitylcopper(I) and investigated for the diamination of conjugated olefins with…”
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17
Chiral N-Heterocyclic Carbene−Pd(0)-Catalyzed Asymmetric Diamination of Conjugated Dienes and Triene
Published in Journal of organic chemistry (18-01-2008)“…Studies show that a variety of conjugated dienes and triene can be enantioselectively diaminated using di-tert-butyldiaziridinone as nitrogen source and chiral…”
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18
Catalytic Asymmetric Intermolecular Bromoesterification of Unfunctionalized Olefins
Published in Organic letters (18-07-2014)“…An asymmetric intermolecular bromoesterification of unfunctionalized olefins catalyzed by (DHQD)2PHAL is described. Optically active bromoesters can be…”
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19
Catalytic Asymmetric Synthesis of Cyclic Sulfamides from Conjugated Dienes
Published in Organic letters (15-02-2013)“…This paper describes the catalytic asymmetric diamination of alkyl dienes using N,N′-di-tert-butylthiadiaziridine 1,1-dioxide in the presence of Pd(0) and a…”
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20
Phosphine Oxide–Sc(OTf)3 Catalyzed Highly Regio- and Enantioselective Bromoaminocyclization of (E)‑Cinnamyl Tosylcarbamates. An Approach to a Class of Synthetically Versatile Functionalized Molecules
Published in Organic letters (04-03-2016)“…A highly regio- and enantioselective bromoaminocyclization of (E)-cinnamyl tosylcarbamates catalyzed by a chiral phosphine oxide–Sc(OTf)3 complex is…”
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