Aryl(sulfonyl)amino Group: A Convenient and Stable Yet Activated Modification of Amino Group for Its Intramolecular Displacement

Aryl(sulfonyl)amino Group: A Convenient and Stable Yet Activated Modification of Amino Group for Its Intramolecular Displacement

Aryl(sulfonyl)amino groups, readily derived from sulfonyl- or arylamines by standard methods as well as the recently introduced methods of sulfonylation and arylation, proved to be good leaving groups in intramolecular substitution reactions by various nitrogen, oxygen, and carbon nucleophiles.

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Bibliographic Details
Published in:Organic letters Vol. 12; no. 18; pp. 4137 - 4139
Main Authors: Kato, Yuzo, Yen, Dinh Hoang, Fukudome, Yasuhiro, Hata, Takeshi, Urabe, Hirokazu
Format: Journal Article
Language:English
Published: United States American Chemical Society 17-09-2010
Subjects:
Amines - chemistry
Molecular Structure
Sulfides - chemistry
Online Access:Get full text
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Description
Summary:Aryl(sulfonyl)amino groups, readily derived from sulfonyl- or arylamines by standard methods as well as the recently introduced methods of sulfonylation and arylation, proved to be good leaving groups in intramolecular substitution reactions by various nitrogen, oxygen, and carbon nucleophiles.
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol101541p