Search Results - "Ye, Tian‐Nan"
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Discovery of hexagonal ternary phase Ti2InB2 and its evolution to layered boride TiB
Published in Nature communications (23-05-2019)“…M n+1 AX n phases are a large family of compounds that have been limited, so far, to carbides and nitrides. Here we report the prediction of a compound, Ti 2…”
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Vacancy-enabled N2 activation for ammonia synthesis on an Ni-loaded catalyst
Published in Nature (London) (16-07-2020)“…Ammonia (NH 3 ) is pivotal to the fertilizer industry and one of the most commonly produced chemicals 1 . The direct use of atmospheric nitrogen (N 2 ) had…”
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Stable single platinum atoms trapped in sub-nanometer cavities in 12CaO·7Al2O3 for chemoselective hydrogenation of nitroarenes
Published in Nature communications (24-02-2020)“…Single-atom catalysts (SACs) have attracted significant attention because they exhibit unique catalytic performance due to their ideal structure. However,…”
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Contribution of Nitrogen Vacancies to Ammonia Synthesis over Metal Nitride Catalysts
Published in Journal of the American Chemical Society (19-08-2020)“…Ammonia is one of the most important feedstocks for the production of fertilizer and as a potential energy carrier. Nitride compounds such as LaN have recently…”
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Palladium-bearing intermetallic electride as an efficient and stable catalyst for Suzuki cross-coupling reactions
Published in Nature communications (11-12-2019)“…Suzuki cross-coupling reactions catalyzed by palladium are powerful tools for the synthesis of functional organic compounds. Excellent catalytic activity and…”
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Dipole Coupling Accelerated H2O Dissociation by Magnesium‐Based Intermetallic Catalysts
Published in Angewandte Chemie International Edition (11-03-2024)“…The water (H2O) dissociation is critical for various H2O‐associated reactions, including water gas shift, hydrogen evolution reaction and hydrolysis corrosion…”
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Dissociative and Associative Concerted Mechanism for Ammonia Synthesis over Co-Based Catalyst
Published in Journal of the American Chemical Society (18-08-2021)“…The current catalytic reaction mechanism for ammonia synthesis relies on either dissociative or associative routes, in which adsorbed N2 dissociates directly…”
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Strongly Veined Carbon Nanoleaves as a Highly Efficient Metal-Free Electrocatalyst
Published in Angewandte Chemie International Edition (01-07-2014)“…Effective integration of one‐dimensional carbon nanofibers (CNF) and two‐dimensional carbon sheets into three‐dimensional (3D) conductive frameworks is…”
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Approach to Chemically Durable Nickel and Cobalt Lanthanum‐Nitride‐Based Catalysts for Ammonia Synthesis
Published in Angewandte Chemie International Edition (21-11-2022)“…Metal nitride complexes have recently been proposed as an efficient noble‐metal‐free catalyst for ammonia synthesis utilizing a dual active site concept…”
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Enabling Sustainable Ammonia Synthesis: From Nitrogen Activation Strategies to Emerging Materials
Published in Advanced materials (Weinheim) (01-10-2024)“…Ammonia (NH3) is one of the most important precursors of various chemicals and fertilizers. Given that ammonia synthesis via the traditional Haber–Bosch…”
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Intermetallic Copper‐Based Electride Catalyst with High Activity for C–H Oxidation and Cycloaddition of CO2 into Epoxides
Published in Small (Weinheim an der Bergstrasse, Germany) (01-09-2022)“…Inorganic electrides have been proved to be efficient hosts for incorporating transition metals, which can effectively act as active sites giving an…”
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Multiple reaction pathway on alkaline earth imide supported catalysts for efficient ammonia synthesis
Published in Nature communications (11-10-2023)“…The tunability of reaction pathways is required for exploring efficient and low cost catalysts for ammonia synthesis. There is an obstacle by the limitations…”
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Discovery of Self‐Assembled 2D Ru/Si Superlattices Boosting Hydrogen Evolution
Published in Small (Weinheim an der Bergstrasse, Germany) (01-10-2024)“…2D heterostructuring is a versatile methodology for designing nanoarchitecture catalytic systems that allow for reconstruction and modulation of interfaces and…”
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Efficient Ammonia Synthesis over Phase-Separated Nickel-Based Intermetallic Catalysts
Published in Journal of physical chemistry. C (31-12-2020)“…Ammonia is one of the most important industrial intermediates due to the mass-demand for the production of various chemicals. Since the development of the…”
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Effects of Activator Types on Degradation Mechanisms of Metakaolin Geopolymer Mortars Exposed to High Temperature
Published in Journal of materials in civil engineering (01-12-2020)“…AbstractIn this study, we investigated the degradation process of metakaolin-based geopolymers exposed to high temperatures up to 1,000°C. The changes in…”
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Intermetallic ZrPd3‑Embedded Nanoporous ZrC as an Efficient and Stable Catalyst of the Suzuki Cross-Coupling Reaction
Published in ACS catalysis (18-12-2020)“…The Suzuki cross-coupling reaction, which is generally catalyzed by Pd-based materials, is a practical approach to create C–C bonds. Although heterogeneous…”
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Ternary intermetallic LaCoSi as a catalyst for N2 activation
Published in Nature catalysis (22-01-2018)“…Activating high-energy multiple bonds using earth-abundant metals is one of the most significant challenges in catalysis. Here, we show that LaCoSi—a ternary…”
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Electronic interactions between a stable electride and a nano-alloy control the chemoselective reduction reaction
Published in Chemical science (Cambridge) (01-01-2016)“…Controlling the electronic structure of heterogeneous metal catalysts is considered an efficient method to optimize catalytic activity. Here, we introduce a…”
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Effects and mechanisms of surfactants on physical properties and microstructures of metakaolin-based geopolymer
Published in Journal of Zhejiang University. A. Science (01-02-2021)“…In this study, the effects of five different ionic and nonionic surfactants on the physical properties and microstructures of a metakaolin-based geopolymer…”
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Chlorine‐Tolerant Ruthenium Catalyst Derived Using the Unique Anion‐Exchange Properties of 12 CaO⋅7 Al2O3 for Ammonia Synthesis
Published in ChemCatChem (09-08-2017)“…Poisoning is defined as deactivation by the strong adsorption of, usually, impurities on active sites, which is a serious problem in many important catalytic…”
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