Search Results - "Yang, Dong Jin"

Holistic Prediction of the pKa in Diverse Solvents Based on a Machine‐Learning Approach by Yang, Qi, Li, Yao, Yang, Jin‐Dong, Liu, Yidi, Zhang, Long, Luo, Sanzhong, Cheng, Jin‐Pei

“…While many approaches to predict aqueous pKa values exist, the fast and accurate prediction of non‐aqueous pKa values is still challenging. Based on the iBonD…”
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Chemoselective catalytic hydrodefluorination of trifluoromethylalkenes towards mono-/gem-di-fluoroalkenes under metal-free conditions by Zhang, Jingjing, Yang, Jin-Dong, Cheng, Jin-Pei

“…Fluorine-containing moieties show significant effects in improving the properties of functional molecules. Consequently, efficient methods for installing them…”
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A Nucleophilicity Scale for the Reactivity of Diazaphospholenium Hydrides: Structural Insights and Synthetic Applications by Zhang, Jingjing, Yang, Jin‐Dong, Cheng, Jin‐Pei

“…Nucleophilicity parameters (N, sN) of a group of representative diazaphospholenium hydrides were derived by kinetic investigations of their hydride transfer to…”
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Exploration of the Synthetic Potential of Electrophilic Trifluoromethylthiolating and Difluoromethylthiolating Reagents by Zhang, Jingjing, Yang, Jin‐Dong, Zheng, Hanliang, Xue, Xiao‐Song, Mayr, Herbert, Cheng, Jin‐Pei

“…The electrophilicity parameters (E) of some trifluoromethylthiolating and difluoromethylthiolating reagents were determined by following the kinetics of their…”
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Diazaphosphinyl radical-catalyzed deoxygenation of α-carboxy ketones: a new protocol for chemo-selective C-O bond scission via mechanism regulation by Zhang, Jingjing, Yang, Jin-Dong, Cheng, Jin-Pei

“…C-O bond cleavage is often a key process in defunctionalization of organic compounds as well as in degradation of natural polymers. However, it seldom occurs…”
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Prediction of Bond Dissociation Energy for Organic Molecules Based on a Machine‐Learning Approach by Liu, Yidi, Li, Yao, Yang, Qi, Yang, Jin‐Dong, Zhang, Long, Luo, Sanzhong

“…Comprehensive Summary Bond dissociation energy (BDE), which refers to the enthalpy change for the homolysis of a specific covalent bond, is one of the basic…”
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Hydroxylamine‐Mediated C(sp2)−H Trifluoromethylation of Terminal Alkenes by Zhao, Xiao, Zhong, Bing, Dong, Likun, Zhang, Yu‐Shan, Luo, Hai‐Tian, Yang, Jin‐Dong, Cheng, Jin‐Pei

“…Introduction of the trifluoromethyl (CF3) group into organic compounds has garnered substantial interest because of its significant role in pharmaceuticals and…”
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Bonding Energetics of Palladium Amido/Aryloxide Complexes in DMSO: Implications for Palladium‐Mediated Aniline Activation by Wu, Jun‐Yan, Li, Zhen, Yang, Jin‐Dong, Cheng, Jin‐Pei

“…Thermodynamic knowledge of the metal–ligand (M−L) σ‐bond strength is crucial to understanding metal‐mediated transformations. Here, we developed a method for…”
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Diazaphosphinanes as hydride, hydrogen atom, proton or electron donors under transition-metal-free conditions: thermodynamics, kinetics, and synthetic applications by Zhang, Jingjing, Yang, Jin-Dong, Cheng, Jin-Pei

“…Exploration of new hydrogen donors is in large demand in hydrogenation chemistry. Herein, we developed a new 1,3,2-diazaphosphinane 1a , which can serve as a…”
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Exploiting the radical reactivity of diazaphosphinanes in hydrodehalogenations and cascade cyclizations by Zhang, Jingjing, Yang, Jin-Dong, Cheng, Jin-Pei

“…The remarkable reducibility of diazaphosphinanes has been extensively applied in various hydrogenations, based on and yet limited by their well-known hydridic…”
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Pd−X Bond Homolysis Dissociation Free Energy (BDFE) Scales of [(tmeda)Pd(4‐F−C6H4)X] (X=OR, NHAr) in DMSO by Wu, Jun‐Yan, Yang, Jin‐Dong, Cheng, Jin‐Pei

“…Transition metal intermediates bearing M−X σ‐bonds are ubiquitous in metal‐mediated C−X bond transformations. Thermodynamic knowledge of M−X bond cleavage is…”
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Predicting Absolute Rate Constants for Huisgen Reactions of Unsaturated Iminium Ions with Diazoalkanes by Zhang, Jingjing, Chen, Quan, Mayer, Robert J., Yang, Jin‐Dong, Ofial, Armin R., Cheng, Jin‐Pei, Mayr, Herbert

“…The kinetics and stereochemistry of the reactions of iminium ions derived from cinnamaldehydes and MacMillan's imidazolidinones with diphenyldiazomethane and…”
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9,10-Dicyanoanthracene Catalyzed Decarboxylative Alkynylation of Carboxylic Acids under Visible-Light Irradiation by Yang, Chen, Yang, Jin-Dong, Li, Yi-He, Li, Xin, Cheng, Jin-Pei

“…A metal-free, visible-light-induced photocatalytic procedure for decarboxylative alkynylation of carboxylic acids was reported. With 9,10-dicyano­anthracene as…”
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A Systematic Evaluation of the N–F Bond Strength of Electrophilic N–F Reagents: Hints for Atomic Fluorine Donating Ability by Yang, Jin-Dong, Wang, Ya, Xue, Xiao-Song, Cheng, Jin-Pei

“…The recent discovery of the radical reactivity of a few traditionally electrophilic N–F reagents has sparked a renaissance of radical fluorination. A knowledge…”
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Computational I(III)—X BDEs for Benziodoxol(on)e‐based Hypervalent Iodine Reagents: Implications for Their Functional Group Transfer Abilities by Yang, Jin‐Dong, Li, Man, Xue, Xiao‐Song

“…Summary of main observation and conclusion The first comprehensive I(III)―X (X = F, Br, CN, N3, CF3, etc.) bond dissociation energy (BDE) scales for…”
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A New Adaptive DS-Based Finite-Time Neural Tracking Control Scheme for Nonstrict-Feedback Nonlinear Systems by Jin, Dong-Yang, Niu, Ben, Wang, Huan-Qing, Yang, Dong

“…This article addresses the problem of adaptive finite-time neural tracking control for nonstrict-feedback nonlinear systems via dynamic surface (DS) technique…”
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Asymmetric [3+2] annulations of 1,4-di-thiane-2,5-diol and oxindole ketimines by Feng, Bo-Xu, Yang, Jin-Dong, Li, Jiuyuan, Li, Xin

“…[Display omitted] •An asymmetric [3+2] annulation of 1,4-di-thiane-2,5-diol and N-Boc ketimines was realized.•A number of chiral spiro-aminooxindole…”
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Anoctamin 1 Contributes to Inflammatory and Nerve-Injury Induced Hypersensitivity by Lee, Byeongjun, Cho, Hawon, Jung, Jooyoung, Yang, Young Duk, Yang, Dong-Jin, Oh, Uhtaek

“…Background: Various pathological conditions such as inflammation or injury can evoke pain hypersensitivity. That represents the response to innocuous stimuli…”
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Amination of 3‑Substituted Benzofuran-2(3H)‑ones Triggered by Single-Electron Transfer by Yang, Chen, Liu, Yang, Yang, Jin-Dong, Li, Yi-He, Li, Xin, Cheng, Jin-Pei

“…An efficient amination reaction of 3-substituted benzofuran-2­(3H)-ones promoted by cesium carbonate was developed. A putative mechanism involving a…”
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Counterintuitive solvation effect of ionic-liquid/DMSO solvents on acidic C-H dissociation and insight into respective solvation by Luo, Wenzhi, Mao, Chong, Ji, Pengju, Wu, Jun-Yan, Yang, Jin-Dong, Cheng, Jin-Pei

“…How would acidic bond dissociation be affected by adding a small quantity of a weakly polar ionic liquid IL (the "apparent" or "measured" dielectric constant…”
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