Search Results - "Yang, Binmiao"
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Stereoselective access to [5.5.0] and [4.4.1] bicyclic compounds through Pd-catalysed divergent higher-order cycloadditions
Published in Nature chemistry (01-09-2020)“…Medium-sized rings, including those embedded in bridged and fused bicyclic scaffolds, are common core structures of myriad bioactive molecules. Among various…”
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2
Catalytic Diastereo‐ and Enantioconvergent Synthesis of Vicinal Diamines from Diols through Borrowing Hydrogen
Published in Angewandte Chemie (16-08-2021)“…We present herein an unprecedented diastereoconvergent synthesis of vicinal diamines from diols through an economical, redox‐neutral process. Under cooperative…”
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3
Access to 5,6-Spirocycles Bearing Three Contiguous Stereocenters via Pd-Catalyzed Stereoselective [4 + 2] Cycloaddition of Azadienes
Published in Organic letters (16-04-2021)“…We present herein a highly diastereo- and enantioselective Pd-catalyzed [4 + 2] cycloaddition of benzofuran-derived azadienes with vinyl benzoxazinanones,…”
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4
Desymmetrization of 1,3-Diones by Catalytic Enantioselective Condensation with Hydrazine
Published in Journal of the American Chemical Society (24-03-2021)“…We present herein an unprecedented desymmetrization of meso 1,3-diones by enantioselective intermolecular condensation. Under the catalysis by a chiral…”
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5
Enantioselective Cascade Annulation of α‐Amino‐ynones and Enals Enabled by Gold and Oxidative NHC Relay Catalysis
Published in Angewandte Chemie International Edition (21-03-2022)“…We report herein an unprecedented gold and oxidative NHC relay catalysis that enables highly enantioselective cascade annulation between readily available…”
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6
Organocatalyzed Intermolecular Asymmetric Allylic Dearomatization of Both α- and β‑Naphthols
Published in Organic letters (04-01-2019)“…The first highly stereoselective intermolecular catalytic asymmetric dearomatization (CADA) of α-naphthols through C–C formation and the first asymmetric…”
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Catalytic Asymmetric [4 + 2] Cycloaddition of ortho-Alkenyl Naphthols/Phenols with ortho-Quinone Methides: Highly Stereoselective Synthesis of Chiral 2,3,4-Trisubstituted Chromans
Published in Journal of organic chemistry (17-04-2020)“…Chiral phosphoric acid-catalyzed biomimetic asymmetric [4 + 2] cycloaddition of ortho-alkenyl naphthols/phenols and ortho-quinone methides (o-QMs) has been…”
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8
Rh(II)/Brønsted Acid Catalyzed General and Highly Diastereo- and Enantioselective Propargylation of in Situ Generated Oxonium Ylides and C‑Alkynyl N‑Boc N,O-Acetals: Synthesis of Polyfunctional Propargylamines
Published in Organic letters (01-03-2019)“…The first metal/organo cooperatively catalyzed asymmetric reaction of C-alkynyl N-Boc-protected N,O-acetals with in situ generated oxonium ylides has been…”
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9
Catalytic Diastereo‐ and Enantioconvergent Synthesis of Vicinal Diamines from Diols through Borrowing Hydrogen
Published in Angewandte Chemie International Edition (16-08-2021)“…We present herein an unprecedented diastereoconvergent synthesis of vicinal diamines from diols through an economical, redox‐neutral process. Under cooperative…”
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10
Enantioselective Access to Triaryl-2-pyrones with Monoaxial or Contiguous C–C Diaxes via Oxidative NHC Catalysis
Published in ACS catalysis (17-02-2023)“…We present herein an unprecedented stereoselective synthesis of triaryl-2-pyrones with monoaxial or contiguous diaxes from readily available starting…”
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11
Enantioselective Cascade Annulation of α‐Amino‐ynones and Enals Enabled by Gold and Oxidative NHC Relay Catalysis
Published in Angewandte Chemie (21-03-2022)“…We report herein an unprecedented gold and oxidative NHC relay catalysis that enables highly enantioselective cascade annulation between readily available…”
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