Search Results - "Yan, James J."

K- and L-edge X-ray absorption spectroscopy (XAS) and resonant inelastic X-ray scattering (RIXS) determination of differential orbital covalency (DOC) of transition metal sites by Baker, Michael L., Mara, Michael W., Yan, James J., Hodgson, Keith O., Hedman, Britt, Solomon, Edward I.

“…•Directly probe metal oxidation state, geometry and coordination number.•Quantify differential orbital covalency.•Spectroscopic access to highly-covalent…”
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L‑Edge X‑ray Absorption Spectroscopic Investigation of {FeNO}6: Delocalization vs Antiferromagnetic Coupling by Yan, James J, Gonzales, Margarita A, Mascharak, Pradip K, Hedman, Britt, Hodgson, Keith O, Solomon, Edward I

“…NO is a classic non-innocent ligand, and iron nitrosyls can have different electronic structure descriptions depending on their spin state and coordination…”
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Oxidation of Naphthalene with a Manganese(IV) Bis(hydroxo) Complex in the Presence of Acid by Jeong, Donghyun, Yan, James J., Noh, Hyeonju, Hedman, Britt, Hodgson, Keith O., Solomon, Edward I., Cho, Jaeheung

“…Naphthalene oxidation with metal–oxygen intermediates is a difficult reaction in environmental and biological chemistry. Herein, we report that a MnIV…”
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A Mononuclear Nonheme Iron(V)-Imido Complex by Hong, Seungwoo, Sutherlin, Kyle D, Vardhaman, Anil Kumar, Yan, James J, Park, Sora, Lee, Yong-Min, Jang, Soojeong, Lu, Xiaoyan, Ohta, Takehiro, Ogura, Takashi, Solomon, Edward I, Nam, Wonwoo

“…Mononuclear nonheme iron­(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron­(V)-imido complex…”
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Structural characterization of a non-heme iron active site in zeolites that hydroxylates methane by Snyder, Benjamin E. R., Böttger, Lars H., Bols, Max L., Yan, James J., Rhoda, Hannah M., Jacobs, Ariel B., Hu, Michael Y., Zhao, Jiyong, Alp, E. Ercan, Hedman, Britt, Hodgson, Keith O., Schoonheydt, Robert A., Sels, Bert F., Solomon, Edward I.

“…Iron-containing zeolites exhibit unprecedented reactivity in the low-temperature hydroxylation of methane to form methanol. Reactivity occurs at a mononuclear…”
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Resonant inelastic X-ray scattering determination of the electronic structure of oxyhemoglobin and its model complex by Yan, James J., Kroll, Thomas, Baker, Michael L., Wilson, Samuel A., Decréau, Richard, Lundberg, Marcus, Sokaras, Dimosthenis, Glatzel, Pieter, Hedman, Britt, Hodgson, Keith O., Solomon, Edward I.

“…Hemoglobin and myoglobin are oxygen-binding proteins with S = 0 heme {FeO₂}⁸ active sites. The electronic structure of these sites has been the subject of much…”
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Effect of 3d/4p Mixing on 1s2p Resonant Inelastic X‑ray Scattering: Electronic Structure of Oxo-Bridged Iron Dimers by Kroll, Thomas, Baker, Michael L, Wilson, Samuel A, Lundberg, Marcus, Juhin, Amélie, Arrio, Marie-Anne, Yan, James J, Gee, Leland B, Braun, Augustin, Weng, Tsu-Chien, Sokaras, Dimosthenis, Hedman, Britt, Hodgson, Keith O, Solomon, Edward I

“…1s2p resonant inelastic X-ray scattering (1s2p RIXS) has proven successful in the determination of the differential orbital covalency (DOC, the amount of metal…”
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Evaluation of a concerted vs. sequential oxygen activation mechanism in α-ketoglutarate–dependent nonheme ferrous enzymes by Goudarzi, Serra, Iyer, Shyam R., Babicz, Jeffrey T., Yan, James J., Peters, Günther H. J., Christensen, Hans E. M., Hedman, Britt, Hodgson, Keith O., Solomon, Edward I.

“…Determining the requirements for efficient oxygen (O₂) activation is key to understanding how enzymes maintain efficacy and mitigate unproductive, often…”
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Resonant Inelastic X‑ray Scattering on Ferrous and Ferric Bis-imidazole Porphyrin and Cytochrome c: Nature and Role of the Axial Methionine–Fe Bond by Kroll, Thomas, Hadt, Ryan G, Wilson, Samuel A, Lundberg, Marcus, Yan, James J, Weng, Tsu-Chien, Sokaras, Dimosthenis, Alonso-Mori, Roberto, Casa, Diego, Upton, Mary H, Hedman, Britt, Hodgson, Keith O, Solomon, Edward I

“…Axial Cu–S­(Met) bonds in electron transfer (ET) active sites are generally found to lower their reduction potentials. An axial S­(Met) bond is also present in…”
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Mechanism of selective benzene hydroxylation catalyzed by iron-containing zeolites by Snyder, Benjamin E. R., Bols, Max L., Rhoda, Hannah M., Vanelderen, Pieter, Böttger, Lars H., Braun, Augustin, Yan, James J., Hadt, Ryan G., Babicz, Jeffrey T., Hu, Michael Y., Zhao, Jiyong, Alp, E. Ercan, Hedman, Britt, Hodgson, Keith O., Schoonheydt, Robert A., Sels, Bert F., Solomon, Edward I.

“…A direct, catalytic conversion of benzene to phenol would have wide-reaching economic impacts. Fe zeolites exhibit a remarkable combination of high activity…”
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A mononuclear nonheme {FeNO} 6 complex: synthesis and structural and spectroscopic characterization by Hong, Seungwoo, Yan, James J, Karmalkar, Deepika G, Sutherlin, Kyle D, Kim, Jin, Lee, Yong-Min, Goo, Yire, Mascharak, Pradip K, Hedman, Britt, Hodgson, Keith O, Karlin, Kenneth D, Solomon, Edward I, Nam, Wonwoo

“…While the synthesis and characterization of {FeNO} complexes have been well documented in heme and nonheme iron models, {FeNO} complexes have been less clearly…”
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Oxidation of Naphthalene with a Manganese(IV) Bis(hydroxo) Complex in the Presence of Acid by Jeong, Donghyun, Yan, James J., Noh, Hyeonju, Hedman, Britt, Hodgson, Keith O., Solomon, Edward I., Cho, Jaeheung

“…Naphthalene oxidation with metal–oxygen intermediates is a difficult reaction in environmental and biological chemistry. Herein, we report that a MnIV…”
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Effect of 3d/4p Mixing on 1s2p Resonant Inelastic X-ray Scattering: Electronic Structure of Oxo-Bridged Iron Dimers by Kroll, Thomas, Baker, Michael L., Wilson, Samuel A., Lundberg, Marcus, Juhin, Amélie, Arrio, Marie-Anne, Yan, James J., Gee, Leland B., Braun, Augustin, Weng, Tsu-Chien, Sokaras, Dimosthenis, Hedman, Britt, Hodgson, Keith O., Solomon, Edward I.

“…1s2p resonant inelastic X-ray scattering (1s2p RIXS) has proven successful in the determination of the differential orbital covalency (DOC, the amount of metal…”
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Naphthalene Oxidation of a Manganese(IV)-Bis(Hydroxo) Complex in the Presence of Acid by Jeong, Donghyun, Yan, James J., Noh, Hyeonju, Hedman, Britt, Hodgson, Keith O., Solomon, Edward I., Cho, Jaeheung

“…Naphthalene oxidation by metal-oxygen intermediates is one of difficult reactions in environmental and biological chemistry. Herein, we report that a Mn IV…”
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L-Edge X-ray Absorption Spectroscopic Investigation of {FeNO}6: Delocalization vs Antiferromagnetic Coupling by Yan, James J., Gonzales, Margarita A., Mascharak, Pradip K., Hedman, Britt, Hodgson, Keith O., Solomon, Edward I.

“…NO is a classic non-innocent ligand, and iron nitrosyls can have different electronic structure descriptions depending on their spin state and coordination…”
Get full text

Mechanism of selective benzene hydroxylation catalyzed by iron-containing zeolites by Snyder, Benjamin E. R., Bols, Max L., Rhoda, Hannah M., Vanelderen, Pieter, Böttger, Lars H., Braun, Augustin, Yan, James J., Hadt, Ryan G., Babicz, Jeffrey T., Hu, Michael Y., Zhao, Jiyong, Alp, E. Ercan, Hedman, Britt, Hodgson, Keith O., Schoonheydt, Robert A., Sels, Bert F., Solomon, Edward I.

“…A direct, catalytic conversion of benzene to phenol would have wide-reaching economic impacts. Fe zeolites exhibit a remarkable combination of high activity…”
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A mononuclear nonheme {FeNO}6 complex: synthesis and structural and spectroscopic characterizationElectronic supplementary information (ESI) available: Tables S1-S6 for crystallographic data, Mössbauer parameters, XAS data and computational geometric parameters and Fig. S1-S11. CCDC 1574430, 1574431. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc01962b by Hong, Seungwoo, Yan, James J, Karmalkar, Deepika G, Sutherlin, Kyle D, Kim, Jin, Lee, Yong-Min, Goo, Yire, Mascharak, Pradip K, Hedman, Britt, Hodgson, Keith O, Karlin, Kenneth D, Solomon, Edward I, Nam, Wonwoo

“…While the synthesis and characterization of {FeNO} 7,8,9 complexes have been well documented in heme and nonheme iron models, {FeNO} 6 complexes have been less…”
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A mononuclear nonheme {FeNO}6 complex: synthesis and structural and spectroscopic characterization† †Electronic supplementary information (ESI) available: Tables S1–S6 for crystallographic data, Mössbauer parameters, XAS data and computational geometric parameters and Fig. S1–S11. CCDC 1574430, 1574431. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc01962b by Hong, Seungwoo, Yan, James J., Karmalkar, Deepika G., Sutherlin, Kyle D., Kim, Jin, Lee, Yong-Min, Goo, Yire, Mascharak, Pradip K., Hedman, Britt, Hodgson, Keith O., Karlin, Kenneth D., Solomon, Edward I., Nam, Wonwoo

“…X-ray structures of nonheme {FeNO} 6 and iron( iii )-nitrito complexes bearing a tetraamido macrocyclic ligand are reported along with three different…”
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AMPLIFIED PROINFLAMMATORY CYTOKINE EXPRESSION AND TOXICITY IN MICE COEXPOSED TO LIPOPOLYSACCHARIDE AND THE TRICHOTHECENE VOMITOXIN (DEOXYNIVALENOL) by Zhou, H R, Harkema, J R, Yan, D, Pestka, J J

“…A single oral exposure to the trichothecene vomitoxin (VT) has been previously shown in the mouse to increase splenic mRNA levels for several cytokines in as…”
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