Search Results - "Xu, Weici"
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Access to enantioenriched compounds bearing challenging tetrasubstituted stereocenters via kinetic resolution of auxiliary adjacent alcohols
Published in Nature communications (18-06-2021)“…Contemporary asymmetric catalysis faces huge challenges when prochiral substrates bear electronically and sterically unbiased substituents and when substrates…”
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Restricted Conformation of a Hydrogen Bond Mediated Catalyst Enables the Highly Efficient Enantioselective Construction of an All-Carbon Quaternary Stereocenter
Published in ACS catalysis (04-11-2016)“…A highly active catalyst for the enantioselective Friedel–Crafts alkylation of indoles with β,β-disubstituted nitroalkenes is reported, allowing catalyst…”
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3
Chiral-at-Metal Octahedral Iridium Catalyst for the Asymmetric Construction of an All-Carbon Quaternary Stereocenter
Published in Angewandte Chemie International Edition (23-12-2013)“…Metal‐templated organocatalysis: The enantioselective formation of an all‐carbon quaternary stereocenter is catalyzed by the ligand sphere of an inert…”
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4
Polypyrrole/graphene composite‐coated fiber for the solid‐phase microextraction of phenols
Published in Journal of separation science (01-10-2011)“…A polypyrrole (Ppy)/graphene (G) composite was developed and applied as a novel coating for use in solid‐phase microextraction (SPME) coupled with gas…”
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Asymmetric total synthesis of rotenoids via organocatalyzed dynamic kinetic resolution
Published in Communications chemistry (25-01-2019)“…Increasing effort has been made towards the asymmetric total synthesis of rotenoid natural products owing to their impressive biological and pharmaceutical…”
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Carbene-catalyzed asymmetric Friedel–Crafts alkylation-annulation sequence and rapid synthesis of indole-fused polycyclic alkaloids
Published in Communications chemistry (24-07-2019)“…Organocatalyzed asymmetric Friedel–Craft reactions have enabled the rapid construction of chiral molecules with highly enantioselectivity enriching the toolbox…”
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Low Coordination State Rh I -Complex as High Performance Catalyst for Asymmetric Intramolecular Cyclopropanation: Construction of penta-Substituted Cyclopropanes
Published in Angewandte Chemie International Edition (01-03-2023)“…A simple, broad-scope rhodium(I)/chiral diene catalytic system for challenging asymmetric intramolecular cyclopropanation of various tri-substituted allylic…”
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Low Coordination State RhI‐Complex as High Performance Catalyst for Asymmetric Intramolecular Cyclopropanation: Construction of penta‐Substituted Cyclopropanes
Published in Angewandte Chemie International Edition (01-03-2023)“…A simple, broad‐scope rhodium(I)/chiral diene catalytic system for challenging asymmetric intramolecular cyclopropanation of various tri‐substituted allylic…”
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Frontispiece: Conformational Locking Induced Enantioselective Diarylcarbene Insertion into B−H and O−H Bonds Using a Cationic Rh(I)/Diene Catalyst
Published in Angewandte Chemie International Edition (04-11-2024)“…Homogeneous Catalysis. In their Research Article (e202412193) Ming‐Hua Xu et al. report the rational design of a novel cationic rhodium(I)/chiral diene…”
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Asymmetric Cyclopropanation of Primary N‑Vinylamides via Carbene Transfer Catalyzed by Cationic Rh(I)/Diene Complexes: An Unexpected Outer-Sphere Mechanism
Published in ACS catalysis (21-06-2024)“…A highly enantioselective intermolecular [2 + 1] cycloaddition of primary N-vinylamides with carbene intermediates was developed by taking advantage of…”
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11
Conformational Locking Induced Enantioselective Diarylcarbene Insertion into B−H and O−H Bonds Using a Cationic Rh(I)/Diene Catalyst
Published in Angewandte Chemie International Edition (04-11-2024)“…Transition‐metal‐catalyzed enantioselective transformations of aryl/aryl carbene are inherently challenging due to the difficulty in distinguishing between two…”
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12
Asymmetric Catalysis with an Inert Chiral-at-Metal Iridium Complex
Published in Journal of the American Chemical Society (24-07-2013)“…The development of a chiral-at-metal iridium(III) complex for the highly efficient catalytic asymmetric transfer hydrogenation of β,β′-disubstituted…”
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Low Coordination State Rh I ‐Complex as High Performance Catalyst for Asymmetric Intramolecular Cyclopropanation: Construction of penta ‐Substituted Cyclopropanes
Published in Angewandte Chemie (01-03-2023)“…Abstract A simple, broad‐scope rhodium(I)/chiral diene catalytic system for challenging asymmetric intramolecular cyclopropanation of various tri ‐substituted…”
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14
Metal-Templated Design: Enantioselective Hydrogen-Bond-Driven Catalysis Requiring Only Parts-per-Million Catalyst Loading
Published in Journal of the American Chemical Society (20-07-2016)“…Based on a metal-templated approach using a rigid and globular structural scaffold in the form of a bis-cyclometalated octahedral iridium complex, an…”
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Front Cover: Catalyst‐ and Light‐free S−H Insertion between Phosphorodithioic Acids and Diazo Compounds: Rapid Access to Dialkylphosphorodithioates (Asian J. Org. Chem. 7/2023)
Published in Asian journal of organic chemistry (01-07-2023)“…C−S bond formation has attracted considerable interest for a long time. The cover picture shows a straightforward and efficient C−S bond formation reaction via…”
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Organocatalyzed Kinetic Resolution of α‑Functionalized Ketones: The Malonate Unit Leads the Way
Published in ACS catalysis (06-03-2020)“…Developing a catalytic kinetic resolution (KR) protocol affording enantioenriched α-functionalized ketones with broad substrate scope and high efficiency has…”
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Modular Design of Chiral Conjugate-Base-Stabilized Carboxylic Acids: Catalytic Enantioselective [4 + 2] Cycloadditions of Acetals
Published in Journal of the American Chemical Society (09-09-2020)“…Readily available 1,2-amino alcohols provide the framework for a new generation of chiral carboxylic acid catalysts that rival the acidity of the widely used…”
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Stereodivergent Access to Enantioenriched Epoxy Alcohols with Three Stereogenic Centers via Ruthenium-Catalyzed Transfer Hydrogenation
Published in Organic letters (19-07-2019)“…The resolution technique of stereodivergent reaction on racemic mixtures (stereodivergent RRM) was employed for the first time in ruthenium complex catalyzed…”
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Correction to Stereodivergent Access to Enantioenriched Epoxy Alcohols with Three Stereogenic Centers via Ruthenium-Catalyzed Transfer Hydrogenation
Published in Organic letters (05-06-2020)Get full text
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Low Coordination State RhI‐Complex as High Performance Catalyst for Asymmetric Intramolecular Cyclopropanation: Construction of penta‐Substituted Cyclopropanes
Published in Angewandte Chemie (01-03-2023)“…A simple, broad‐scope rhodium(I)/chiral diene catalytic system for challenging asymmetric intramolecular cyclopropanation of various tri‐substituted allylic…”
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