Search Results - "Xu, Shutao"
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Molecular elucidating of an unusual growth mechanism for polycyclic aromatic hydrocarbons in confined space
Published in Nature communications (26-02-2020)“…Extension and clustering of polycyclic aromatic hydrocarbons (PAHs) are key mechanistic steps for coking and deactivation in catalysis reactions. However, no…”
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Pentacoordinated Al3+‐Stabilized Active Pd Structures on Al2O3‐Coated Palladium Catalysts for Methane Combustion
Published in Angewandte Chemie International Edition (26-08-2019)“…Supported Pd catalysts are active in catalyzing the highly exothermic methane combustion reaction but tend to be deactivated owing to local hyperthermal…”
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3
Group-velocity-locked vector solitons and dissipative solitons in a single fiber laser with net-anomalous dispersion
Published in Scientific reports (27-04-2022)“…Laser cavities which can generate different types of ultrashort pulses are attractive for practical applications and the study of pulse dynamics. Here, we…”
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Direct Mechanism of the First Carbon–Carbon Bond Formation in the Methanol‐to‐Hydrocarbons Process
Published in Angewandte Chemie International Edition (24-07-2017)“…In the past two decades, the reaction mechanism of C−C bond formation from either methanol or dimethyl ether (DME) in the methanol‐to‐hydrocarbons (MTH)…”
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Acid-Promoter-Free Ethylene Methoxycarbonylation over Ru-Clusters/Ceria: The Catalysis of Interfacial Lewis Acid–Base Pair
Published in Journal of the American Chemical Society (21-03-2018)“…The interface of metal-oxide plays pivotal roles in catalytic reactions, but its catalytic function is still not clear. In this study, we report the high…”
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Hydrogenolysis of Glycerol to 1,3-propanediol under Low Hydrogen Pressure over WOx-Supported Single/Pseudo-Single Atom Pt Catalyst
Published in ChemSusChem (21-04-2016)“…Single/pseudo‐single atom Pt catalyst was prepared on mesoporous WOx. The large surface area and abundant oxygen vacancies of WOx improve the Pt dispersion and…”
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Nanosize-Enhanced Lifetime of SAPO-34 Catalysts in Methanol-to-Olefin Reactions
Published in Journal of physical chemistry. C (25-04-2013)“…In this work, we systematically investigated the size effect of silicoaluminophosphate molecular sieve catalysts SAPO-34 on the catalytic performance of…”
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Origin and Structural Characteristics of Tri-coordinated Extra-framework Aluminum Species in Dealuminated Zeolites
Published in Journal of the American Chemical Society (29-08-2018)“…Post-synthetic dealumination treatment is a common tactic adopted to improve the catalytic performance of industrialized zeolitic catalysts through…”
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9
Electrolyte Solvation Manipulation Enables Unprecedented Room‐Temperature Calcium‐Metal Batteries
Published in Angewandte Chemie International Edition (27-07-2020)“…Calcium‐metal batteries (CMBs) provide a promising option for high‐energy and cost‐effective energy‐storage technology beyond the current state‐of‐the‐art…”
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New protocol of copper-catalyzed oxidative C(CO)C bond cleavage of aryl and aliphatic ketones to organic acids using O2 as the terminal oxidant
Published in Journal of catalysis (01-02-2017)“…[Display omitted] •Cu(NO3)2 could catalyze the oxidative CC cleavage of ketones to acids.•A wide range of ketones have good to excellent yields.•In situ NMR…”
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Rationalizing kinetic behaviors of isolated boron sites catalyzed oxidative dehydrogenation of propane
Published in Nature communications (16-10-2023)“…Boron-based catalysts exhibit high alkene selectivity in oxidative dehydrogenation of propane (ODHP) but the mechanistic understanding remains incomplete. In…”
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A Bottom‐Up Strategy for the Synthesis of Highly Siliceous Faujasite‐Type Zeolite
Published in Advanced materials (Weinheim) (01-07-2020)“…High‐silica zeolite Y is a desired catalytic material for oil refining and the petrochemical industry. However, its direct synthesis remains a symbolic…”
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Role of 12-Ring Channels of Mordenite in DME Carbonylation Investigated by Solid-State NMR
Published in Journal of physical chemistry. C (06-10-2016)“…In this work, we have studied the role of the 12-ring channel of mordenite in DME carbonylation. Upon modification with pyridine, the catalytic lifetime of…”
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14
Cavity Controls the Selectivity: Insights of Confinement Effects on MTO Reaction
Published in ACS catalysis (06-02-2015)“…Organic reaction intermediates confined in zeolite cavities are very important for product formation during methanol-to-olefins (MTO) conversion; however,…”
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Spatial confinement effects of cage-type SAPO molecular sieves on product distribution and coke formation in methanol-to-olefin reaction
Published in Catalysis communications (10-02-2014)“…Three kinds of 8-membered ring silicoaluminophosphate (SAPO) molecular sieves with different cage structures, SAPO-34, SAPO-18 and SAPO-35, were employed in…”
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Water‐Induced Structural Dynamic Process in Molecular Sieves under Mild Hydrothermal Conditions: Ship‐in‐a‐Bottle Strategy for Acidity Identification and Catalyst Modification
Published in Angewandte Chemie International Edition (09-11-2020)“…Water is the most important substance in nature. Imitating the formation of natural materials, molecular sieves have been synthesized under hydrothermal…”
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Methanol to Olefins Reaction over Cavity-type Zeolite: Cavity Controls the Critical Intermediates and Product Selectivity
Published in ACS catalysis (07-12-2018)“…Methanol to olefins (MTO) reaction over H-RUB-50 zeolite, an eight-membered ring (8-MR) and cavity-type zeolite, presents higher selectivity for ethene. The…”
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Oriented control of Al locations in the framework of Al-Ge-ITQ-13 for catalyzing methanol conversion to propene
Published in Journal of catalysis (01-12-2016)“…[Display omitted] •Framework Al distribution of Al-Ge-ITQ-13 has remarkable effects on its MTP catalytic properties.•Al locations in the Al-Ge-ITQ-13 framework…”
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Direct quantification of surface barriers for mass transfer in nanoporous crystalline materials
Published in Communications chemistry (08-04-2019)“…Mass transfer of guest molecules in nanoporous crystalline materials has gained attention in catalysis, separation, electrochemistry, and other fields. Two…”
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Fast detection and structural identification of carbocations on zeolites by dynamic nuclear polarization enhanced solid-state NMR
Published in Chemical science (Cambridge) (21-11-2018)“…Acidic zeolites are porous aluminosilicates used in a wide range of industrial processes such as adsorption and catalysis. The formation of carbocation…”
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