Search Results - "Xin, Jinpeng"
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Stabilizing a three-center single-electron metal-metal bond in a fullerene cage
Published in Chemical science (Cambridge) (02-04-2021)“…Trimetallic carbide clusterfullerenes (TCCFs) encapsulating a quinary M 3 C 2 cluster represent a special family of endohedral fullerenes with an open-shell…”
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A stabilization rule for metal carbido cluster bearing μ3-carbido single-atom-ligand encapsulated in carbon cage
Published in Nature communications (02-01-2024)“…Metal carbido complexes bearing single-carbon-atom ligand such as nitrogenase provide ideal models of adsorbed carbon atoms in heterogeneous catalysis…”
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3
Capturing the Long-Sought Dy@C2v(5)-C80 via Benzyl Radical Stabilization
Published in Nanomaterials (Basel, Switzerland) (22-09-2022)“…Endohedral metallofullerenes (EMFs) are one type of intriguing metal/carbon hybrid molecule with the molecule configuration of sphere cavity-encapsulating…”
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Transition Metal/Lanthanide-Nitrogen Double Bonds Co-stabilized in a Carbon Cage
Published in Precision Chemistry (27-05-2024)“…Metal–nitrogen double bonds have been commonly reported for conventional metal complexes, but the coexistence of both transition metal–nitrogen and…”
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TmCN@C82: Monometallic Clusterfullerene Encapsulating a Tm3+ Ion
Published in Inorganics (01-08-2023)“…Metal cyanide clusterfullerenes (CYCFs) are formed via the encapsulation of a single metal atom and a cyanide unit inside fullerene cages, endowing them with…”
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Short Didysprosium Covalent Bond Enables High Magnetization Blocking Temperature of a Direct 4f–4f Coupled Dinuclear Single-Molecule Magnet
Published in Journal of the American Chemical Society (03-07-2024)“…Coupling two magnetic anisotropic lanthanide ions via a direct covalent bond is an effective way to realize high magnetization blocking temperature of…”
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Monometallic Endohedral Azafullerene
Published in Journal of the American Chemical Society (30-11-2022)“…Azafullerenes derived from nitrogen substitution of carbon cage atoms render direct modifications of the cage skeleton, electronic, and physicochemical…”
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Steering Single-Electron Metal–Metal Bonds and Hyperfine Coupling between a Transition Metal-Lanthanide Heteronuclear Bimetal Confined in Carbon Cages
Published in Journal of the American Chemical Society (18-10-2023)“…Metal complexes bearing single-electron metal–metal bonds (SEMBs) exhibit unusual electronic structures evoking strong magnetic coupling, and such bonds can be…”
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Capturing the Missing Carbon Cage Isomer of C84 via Mutual Stabilization of a Triangular Monometallic Cyanide Cluster
Published in Journal of the American Chemical Society (02-06-2021)“…Monometallic cyanide clusterfullerenes (CYCFs) represent a unique branch of endohedral clusterfullerenes with merely one metal atom encapsulated, offering a…”
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10
Bandgap Engineering of Erbium‐Metallofullerenes toward Switchable Photoluminescence
Published in Advanced materials (Weinheim) (01-12-2023)“…Encapsulating photoluminescent lanthanide ions like erbium (Er) into fullerene cages affords photoluminescent endohedral metallofullerenes (EMFs). Few reported…”
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Self-driven carbon atom implantation into fullerene embedding metal-carbon cluster
Published in Proceedings of the National Academy of Sciences - PNAS (27-09-2022)“…Hundreds of members have been synthesized and versatile applications have been promised for endofullerenes (EFs) in the past 30 y. However, the formation…”
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12
Capturing the Missing Carbon Cage Isomer of C 84 via Mutual Stabilization of a Triangular Monometallic Cyanide Cluster
Published in Journal of the American Chemical Society (02-06-2021)“…Monometallic cyanide clusterfullerenes (CYCFs) represent a unique branch of endohedral clusterfullerenes with merely one metal atom encapsulated, offering a…”
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13
Self-driven carbon atom implantation into fullerene embedding metal–carbon cluster
Published in Proceedings of the National Academy of Sciences - PNAS (27-09-2022)“…Hundreds of members have been synthesized and versatile applications have been promised for endofullerenes (EFs) in the past 30 y. However, the formation…”
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14
TmCN@C[sub.82]: Monometallic Clusterfullerene Encapsulating a Tm[sup.3+] Ion
Published in Inorganics (01-07-2023)“…Metal cyanide clusterfullerenes (CYCFs) are formed via the encapsulation of a single metal atom and a cyanide unit inside fullerene cages, endowing them with…”
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15
A stabilization rule for metal carbido cluster bearing μ 3 -carbido single-atom-ligand encapsulated in carbon cage
Published in Nature communications (02-01-2024)“…Metal carbido complexes bearing single-carbon-atom ligand such as nitrogenase provide ideal models of adsorbed carbon atoms in heterogeneous catalysis…”
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Capturing the Long-Sought Dy@IC2v/I-C[sub.80] via Benzyl Radical Stabilization
Published in Nanomaterials (Basel, Switzerland) (01-09-2022)“…Endohedral metallofullerenes (EMFs) are one type of intriguing metal/carbon hybrid molecule with the molecule configuration of sphere cavity-encapsulating…”
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Research on Long-Range Air-to-Air Missile Extended Range Trajectory Guidance Law with Angle Constraint
Published in Hangkong Bingqi (01-08-2022)“…Taking the long-range air-to-air missile as the research object, this paper puts forward an angle-constrained range-extending trajectory planning scheme. Then,…”
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