Search Results - "Xia, Peng‐Ju"
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1
Photoinduced Single‐Electron Transfer as an Enabling Principle in the Radical Borylation of Alkenes with NHC–Borane
Published in Angewandte Chemie International Edition (20-04-2020)“…A photoinduced SET process enables the direct B−H bond activation of NHC–boranes. In contrast to common hydrogen atom transfer (HAT) strategies, this…”
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2
Photocatalytic, Phosphoranyl Radical-Mediated N–O Cleavage of Strained Cycloketone Oximes
Published in Organic letters (19-04-2019)“…A photoinduced, phosphoranyl radical-mediated protocol for the direct N–O cleavage of strained cycloketone oximes via a polar/SET crossover process was…”
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3
Photocatalytic Regio‐ and Site‐Selective Alkylamination of Coumarins: Access to 3‐Amino‐ and 4‐Amino Dihydrocoumarins
Published in Advanced synthesis & catalysis (11-04-2023)“…Functionalized dihydrocoumarins, including 3‐amino‐ and 4‐amino dihydrocoumarins serving as α‐ and β‐amino acid derivatives, have been synthesized using…”
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4
Photocatalytic Hydroacylation of Alkenes by Directly Using Acyl Oximes
Published in Journal of organic chemistry (18-09-2020)“…Acyl oximes are directly used as the acyl radical precursors in the hydroacylation reactions for the first time. In this work, acyl radicals can be effectively…”
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5
Mechanochemical Synthesis of 2‐Arylquinoxalines and 3‐Arylquinoxalin‐2(1H)‐ones via Aryldiazonium Salts
Published in Advanced synthesis & catalysis (15-03-2022)“…A green synthesis strategy of 2‐arylquinoxalines and 3‐arylquinoxalin‐2(1H)‐ones via ball milling, which could avoid copious solvent waste, was accomplished in…”
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6
Visible-Light-Induced External Radical-Triggered Annulation To Access CF2‑Containing Benzoxepine Derivatives
Published in Organic letters (02-03-2018)“…A facile and diversified synthesis of functionalized CF2-containing benzoxepine derivatives via photoredox catalysis was achieved in this work. This novel…”
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7
Visible‐Light‐Promoted Synthesis of 1,4‐Dicarbonyl Compounds via Conjugate Addition of Aroyl Chlorides
Published in Chemistry, an Asian journal (02-02-2018)“…A facile visible‐light photocatalytic conjugate addition to prepare 1,4‐dicarbonyl compounds has been developed by employing readily available aroyl chlorides…”
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8
A One‐Pot Ring‐Opening/Ring‐Closure Sequence for the Synthesis of Polycyclic Spirooxindoles
Published in Chemistry : a European journal (27-03-2019)“…One‐pot ring‐opening/ring‐closure process of combining methyleneindolinone with 3‐aminooxindole has been developed in this work. Novel polycyclic…”
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9
Unraveling and Manipulating the Stereospecific Retro-Aldol Reaction in the Organocatalytic Asymmetric Aldol Reaction of Isatin and Cyclohexanone
Published in Organic letters (07-12-2018)“…An l-pyroglutamic acid-derived bifunctional organocatalyst was designed and applied in an organocatalytic asymmetric direct aldol reaction between isatins and…”
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10
Photoredox-Catalyzed Reductive Dimerization of Isatins and Isatin-Derived Ketimines: Diastereoselective Construction of 3,3′-Disubstituted Bisoxindoles
Published in Journal of organic chemistry (07-04-2017)“…Reductive dimerization of isatin and its derivatives can be regarded as a step-economical pathway to construct 3,3′-disubstituted bisoxindoles, which was…”
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11
Unusual Ligand‐to‐Metal‐Ratio‐Controlled Bidirectional Enantioselectivity in Pd‐Catalysed [3+3]‐Annulation of Morita–Baylis–Hillman Acetate
Published in European journal of organic chemistry (15-12-2017)“…An unusual ligand‐to‐palladium‐ratio‐dependent reversal of enantioselectivity was systematically observed in the asymmetric Pd‐catalysed [3+3]‐annulation of…”
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12
Divergent Aerobic Oxidative Ring-Opening Cascades of Isatins with 1,2,3,4-Tetrahydroisoquinoline
Published in European journal of organic chemistry (01-10-2016)“…The unprecedented aerobic oxidative ring‐opening‐initiated cascades of isatins with 1,2,3,4‐tetrahydroisoquinoline were explored, in which the reaction…”
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13
Straightforward Synthesis of Novel Difluorinated 2‐Hydroxyl‐Substituted Dihydroquinolones Through Selectfluor‐triggered Annulation of 2‐Aminoarylenaminones
Published in ChemistrySelect (Weinheim) (31-08-2018)“…A series of novel difluorinated 2‐hydroxyl‐substituted dihydroquinolones have been firstly synthesized via selectfluor‐triggered tandem cyclizations of…”
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14
Photocatalytic 1,2-Iminosulfonylation and Remote 1,6-Iminosulfonylation of Olefins
Published in Organic letters (17-03-2023)“…A new class of iminosulfonylation reagents were developed and extensively used in the 1,2-iminosulfonylation of various olefins. Olefins containing bioactive…”
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15
Photocatalytic Modular Cyanoalkylamination of Alkenes Involving Two Different Iminyl Radicals
Published in Organic letters (04-11-2022)“…The modular cyanoalkylamination of alkenes using bench-stable and easy-to-handle α-imino-oxy acid oxime esters as difunctional reagents creates new synthetic…”
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16
O‑Perfluoropyridin-4-yl Oximes: Iminyl Radical Precursors for Photo- or Thermal-Induced N–O Cleavage in C(sp2)–C(sp3) Bond Formation
Published in Journal of organic chemistry (06-03-2020)“…O-Perfluoropyridin-4-yl group was first installed onto cycloketone oximes as a new electrophore, which was proven to be efficient iminyl radical precursors…”
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17
Photoinduced Difunctionalization of Diazenes Enabled by N–N Radical Coupling
Published in Organic letters (15-09-2023)“…In this study, a metal-free difunctionalization strategy for diazenes was developed using a range of bifunctionalization reagents. This strategy involves a…”
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18
Photoinduced Remote C(sp3)–H Imination Enabled by Vinyl Radical-Mediated 1,5-Hydrogen Atom Transfer
Published in Organic letters (10-03-2023)“…A vinyl radical-mediated 1,5-hydrogen atom transfer strategy for remote C(sp3)–H imination under visible-light-induced photochemical metal-free conditions…”
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19
Photochemical Organocatalytic Aerobic Cleavage of CC Bonds Enabled by Charge-Transfer Complex Formation
Published in Organic letters (10-06-2022)“…A novel visible-light-driven organocatalytic protocol to access aerobic oxidative cleavage of olefins, promoted by sodium benzene sulfinate, is described…”
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20
Photocatalytic C–F Bond Borylation of Polyfluoroarenes with NHC-boranes
Published in Organic letters (06-03-2020)“…The first photoredox-catalyzed defluoroborylation of polyfluoroarenes with NHC-BH3 has been facilely achieved at room temperature via a…”
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