Search Results - "Xi, Shibo"
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Mechanistic analysis of multiple processes controlling solar-driven H2O2 synthesis using engineered polymeric carbon nitride
Published in Nature communications (17-06-2021)“…Solar-driven hydrogen peroxide (H 2 O 2 ) production presents unique merits of sustainability and environmental friendliness. Herein, efficient solar-driven H…”
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Understanding of Oxygen Redox in the Oxygen Evolution Reaction
Published in Advanced materials (Weinheim) (01-12-2022)“…The electron‐transfer process during the oxygen evolution reaction (OER) often either proceeds solely via a metal redox chemistry (adsorbate evolution…”
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Tuning of lattice oxygen reactivity and scaling relation to construct better oxygen evolution electrocatalyst
Published in Nature communications (28-06-2021)“…Developing efficient and low-cost electrocatalysts for oxygen evolution reaction is crucial in realizing practical energy systems for sustainable fuel…”
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Exceptionally active iridium evolved from a pseudo-cubic perovskite for oxygen evolution in acid
Published in Nature communications (04-02-2019)“…Exploring robust catalysts for water oxidation in acidic electrolyte is challenging due to the limited material choice. Iridium (Ir) is the only active element…”
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Scalable two-step annealing method for preparing ultra-high-density single-atom catalyst libraries
Published in Nature nanotechnology (01-02-2022)“…The stabilization of transition metals as isolated centres with high areal density on suitably tailored carriers is crucial for maximizing the industrial…”
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Synthesis of orthogonally assembled 3D cross-stacked metal oxide semiconducting nanowires
Published in Nature materials (01-02-2020)“…Assemblies of metal oxide nanowires in 3D stacks can enable the realization of nanodevices with tailored conductivity, porous structure and a high surface…”
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Restructuring highly electron-deficient metal-metal oxides for boosting stability in acidic oxygen evolution reaction
Published in Nature communications (28-09-2021)“…The poor catalyst stability in acidic oxidation evolution reaction (OER) has been a long-time issue. Herein, we introduce electron-deficient metal on…”
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Chemical and structural origin of lattice oxygen oxidation in Co–Zn oxyhydroxide oxygen evolution electrocatalysts
Published in Nature energy (01-04-2019)“…The oxygen evolution reaction (OER) is a key process in electrochemical energy conversion devices. Understanding the origins of the lattice oxygen oxidation…”
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Role of lattice oxygen in methane activation on Ni-phyllosilicate@Ce1-xZrxO2 core-shell catalyst for methane dry reforming: Zr doping effect, mechanism, and kinetic study
Published in Applied catalysis. B, Environmental (05-08-2021)“…[Display omitted] •Core-shell Ni-phyllosilicate@Ce1-xZrxO2 catalysts with high coke resistance for DRM.•Optimum Zr doping in shell doubles catalyst activity…”
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In Situ Raman Spectroscopy of Copper and Copper Oxide Surfaces during Electrochemical Oxygen Evolution Reaction: Identification of CuIII Oxides as Catalytically Active Species
Published in ACS catalysis (01-04-2016)“…Scanning electron microscopy, X-ray diffraction, cyclic voltammetry, chronoamperometry, in situ Raman spectroscopy, and X-ray absorption near-edge structure…”
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Modulating Pt-O-Pt atomic clusters with isolated cobalt atoms for enhanced hydrogen evolution catalysis
Published in Nature communications (04-05-2022)“…Platinum is the most efficient catalyst for hydrogen evolution reaction in acidic conditions, but its widespread use has been impeded by scarcity and high…”
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Size‐Dependent Activity and Selectivity of Atomic‐Level Copper Nanoclusters during CO/CO2 Electroreduction
Published in Angewandte Chemie International Edition (04-01-2021)“…As a favorite descriptor, the size effect of Cu‐based catalysts has been regularly utilized for activity and selectivity regulation toward CO2/CO…”
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Metal Atom‐Doped Co3O4 Hierarchical Nanoplates for Electrocatalytic Oxygen Evolution
Published in Advanced materials (Weinheim) (01-08-2020)“…Electrocatalysts based on hierarchically structured and heteroatom‐doped non‐noble metal oxide materials are of great importance for efficient and low‐cost…”
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Materializing efficient methanol oxidation via electron delocalization in nickel hydroxide nanoribbon
Published in Nature communications (16-09-2020)“…Achieving a functional and durable non-platinum group metal-based methanol oxidation catalyst is critical for a cost-effective direct methanol fuel cell. While…”
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A Graphene‐Supported Single‐Atom FeN5 Catalytic Site for Efficient Electrochemical CO2 Reduction
Published in Angewandte Chemie International Edition (14-10-2019)“…Electrochemical conversion of CO2 into valued products is one of the most important issues but remains a great challenge in chemistry. Herein, we report a…”
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Tailoring the Co 3d‑O 2p Covalency in LaCoO3 by Fe Substitution To Promote Oxygen Evolution Reaction
Published in Chemistry of materials (26-12-2017)“…LaCoO3 is an active, stable catalyst in alkaline solution for oxygen evolution reaction (OER). With lower cost, it is a potential alternative to precious metal…”
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Ordered clustering of single atomic Te vacancies in atomically thin PtTe2 promotes hydrogen evolution catalysis
Published in Nature communications (21-04-2021)“…Exposing and stabilizing undercoordinated platinum (Pt) sites and therefore optimizing their adsorption to reactive intermediates offers a desirable strategy…”
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Linkage Effect in the Heterogenization of Cobalt Complexes by Doped Graphene for Electrocatalytic CO2 Reduction
Published in Angewandte Chemie International Edition (16-09-2019)“…Immobilization of planar CoII‐2,3‐naphthalocyanine (NapCo) complexes onto doped graphene resulted in a heterogeneous molecular Co electrocatalyst that was…”
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Enhanced Catalysis of the Electrochemical Oxygen Evolution Reaction by Iron(III) Ions Adsorbed on Amorphous Cobalt Oxide
Published in ACS catalysis (02-02-2018)“…The oxygen evolution reaction (OER) is the bottleneck in the efficient production of hydrogen gas fuel via the electrochemical splitting of water. In this…”
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Enlarged CoO Covalency in Octahedral Sites Leading to Highly Efficient Spinel Oxides for Oxygen Evolution Reaction
Published in Advanced materials (Weinheim) (09-08-2018)“…Cobalt‐containing spinel oxides are promising electrocatalysts for the oxygen evolution reaction (OER) owing to their remarkable activity and durability…”
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