Search Results - "Wu, Ying‐Yann"
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Reactivities of Interstitial Hydrides in a Cu11 Template: En Route to Bimetallic Clusters
Published in Angewandte Chemie International Edition (10-01-2022)“…In sharp contrast to surface hydrides, reactivities of interstitial hydrides are difficult to explore. When treated with a metal ion (Cu+, Ag+, and Au+), the…”
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2
Controlled Shell and Kernel Modifications of Atomically Precise Pd/Ag Superatomic Nanoclusters
Published in Chemistry : a European journal (02-06-2023)“…The first 8‐electron Pd/Ag superatomic alloys with an interstitial hydride [PdHAg19(dtp)12] (dtp=S2P(OiPr)2−) 1 and [PdHAg20(dtp)12]+ 2 are reported. The…”
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3
Hydride‐Containing Pt‐doped Cu‐rich Nanoclusters: Synthesis, Structure, and Electrocatalytic Hydrogen Evolution
Published in Chemistry : a European journal (01-03-2024)“…A structurally precise hydride‐containing Pt‐doped Cu‐rich nanocluster [PtH2Cu14{S2P(OiPr)2}6(CCPh)6] (1) has been synthesized. It consists of a bicapped…”
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4
Synergistic Catalysis by Brønsted Acid/Carbodicarbene Mimicking Frustrated Lewis Pair‐Like Reactivity
Published in Angewandte Chemie International Edition (01-09-2021)“…Carbodicarbene (CDC), unique carbenic entities bearing two lone pairs of electrons are well‐known for their strong Lewis basicity. We demonstrate herein, upon…”
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5
Glycolipids of monogalactosyldiacylglycerol in Phalaenopsis leaves during growth and spike induction periods form mixed liposomes that enhance the inhibition of Escherichia coli growth
Published in Journal of the Chinese Chemical Society (Taipei) (01-02-2024)“…Chemical components in the hexane‐extract mixture from Phalaenopsis leaves were isolated and identified during the spike induction process. Several lipophilic…”
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6
A Facile NMR Method for Pre‐MRI Evaluation of Trigger‐Responsive T1 Contrast Enhancement
Published in Small methods (01-10-2024)“…There is a growing interest in developing paramagnetic nanoparticles as responsive magnetic resonance imaging (MRI) contrast agents, which feature switchable…”
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7
Hydride-Containing Eight-Electron Pt/Ag Superatoms: Structure, Bonding, and Multi-NMR Studies
Published in Journal of the American Chemical Society (15-06-2022)“…Recent reports on hydride-doped noble metal nanoclusters strongly suggest that the encapsulated hydride is a part of the superatom core, but no accurate…”
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8
Reactivities of Interstitial Hydrides in a Cu 11 Template: En Route to Bimetallic Clusters
Published in Angewandte Chemie International Edition (10-01-2022)“…In sharp contrast to surface hydrides, reactivities of interstitial hydrides are difficult to explore. When treated with a metal ion (Cu , Ag , and Au ), the…”
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9
Diselenophosphate Ligands as a Surface Engineering Tool in PdH-Doped Silver Superatomic Nanoclusters
Published in Inorganic chemistry (05-02-2024)“…The first hydride-doped Pd/Ag superatoms stabilized by selenolates are reported: [PdHAg19(dsep)12] [dsep = Se2P(O i Pr)2] 1 and [PdHAg20(dsep)12]+ 2. 1 was…”
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10
A heteroleptic Pt-doped Cu-rich hydrides nanocluster
Published in Polyhedron (15-05-2024)“…Modification of μ4-H trigonal pyramidal (tp) geometry in PtH2Cu14-dtp into μ5-H trigonal bipyramidal (tbp) in PtH2Cu14-dtc can be achieved through the…”
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11
Hydride Doping Effects on the Structure and Properties of Eight-Electron Rh/Ag Superatoms: The [RhH x @Ag21–x {S2P(O n Pr)2}12] (x = 0–2) Series
Published in Journal of the American Chemical Society (02-08-2023)“…Three hitherto unknown eight-electron rhodium/silver alloy nanoclusters, [RhAg21{S2P(O n Pr)2}12] (1), [RhHAg20{S2P(O n Pr)2}12] (2), and [RhH2Ag19{S2P(O n…”
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12
Controlled aggregation of Pt/PtH/Rh/RhH doped silver superatomic nanoclusters into 16-electron supermolecules
Published in Chemical science (Cambridge) (22-08-2024)“…The assembly of discrete superatomic nanoclusters into larger constructs is a significant stride towards developing a new set of artificial/pseudo-elements…”
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13
Linear and cyclic tetranuclear copper(I) complexes containing anions of N,N'-bis(pyrimidine-2-yl)formamidine
Published in Dalton transactions : an international journal of inorganic chemistry (01-01-2005)“…The reaction of Kpmf (pmf = anion of N,N[prime or minute]-bis(pyrimidyl-2-yl)formamidine, Hpmf) with CuSCN afforded the complexes K[Cu4(pmF)3(SCN)2], 1, and…”
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14
A Facile NMR Method for Pre-MRI Evaluation of Trigger-Responsive T 1 Contrast Enhancement
Published in Small methods (08-03-2024)“…There is a growing interest in developing paramagnetic nanoparticles as responsive magnetic resonance imaging (MRI) contrast agents, which feature switchable T…”
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15
A Copper(I) Homocubane Collapses to a Tetracapped Tetrahedron Upon Hydride Insertion
Published in Inorganic chemistry (05-09-2011)“…The hydrido copper(I) and silver(I) clusters incorporating 1,1-dicyanoethylene-2,2-dithiolate (i-MNT) ligands are presented in this paper. Reactions of M(I) (M…”
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16
Exploring the Acid-Catalyzed Reactions of 10,11-Epoxy-Dibenzo[a,d]cycloheptan-5-ol as the Synthetic Modules toward Polycyclic Aromatic Scaffolds
Published in ACS omega (28-06-2022)“…The structural diversity of polycyclic aromatic hydrocarbons (PAHs) offers exciting opportunities for their applications. Yet, selective synthesis of such…”
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17
NMR investigation of magnesium chelation and cation-induced signal shift effect of testosterone
Published in Steroids (01-11-2016)“…[Display omitted] •13C NMR provides a sensitive tool for analyzing cation chelation on testosterone.•Testosterone/Mg2+ chelation are mediated by the oxygen and…”
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Innentitelbild: Reactivities of Interstitial Hydrides in a Cu11 Template: En Route to Bimetallic Clusters (Angew. Chem. 2/2022)
Published in Angewandte Chemie (10-01-2022)“…Je nach M+ verhalten sich die Hydride des H2Cu11‐Reaktanten unterschiedlich. Im Falle von M=Cu oder Ag wirken sie als reguläre 2‐Elektronen‐Liganden und bilden…”
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19
Reactivities of Interstitial Hydrides in a Cu11 Template: En Route to Bimetallic Clusters
Published in Angewandte Chemie (10-01-2022)“…In sharp contrast to surface hydrides, reactivities of interstitial hydrides are difficult to explore. When treated with a metal ion (Cu+, Ag+, and Au+), the…”
Get full text
Journal Article -
20
Synergistic Catalysis by Brønsted Acid/Carbodicarbene Mimicking Frustrated Lewis Pair‐Like Reactivity
Published in Angewandte Chemie (01-09-2021)“…Carbodicarbene (CDC), unique carbenic entities bearing two lone pairs of electrons are well‐known for their strong Lewis basicity. We demonstrate herein, upon…”
Get full text
Journal Article