Search Results - "Wootsch, A"
-
1
Preferential CO oxidation in hydrogen (PROX) on ceria-supported catalysts, Part I: Oxidation state and surface species on Pt/CeO2 under reaction conditions
Published in Journal of catalysis (2006)“…The CO content of hydrogen feed to proton-exchange membrane fuel cells (PEMFCs) must be kept under 1-100 ppm for their proper operation. This can be achieved…”
Get full text
Journal Article -
2
Preferential oxidation of carbon monoxide in the presence of hydrogen (PROX) over ceria–zirconia and alumina-supported Pt catalysts
Published in Journal of catalysis (25-07-2004)“…One crucial requirement for the operation of proton exchange membrane fuel cells (PEMFC) is to feed carbon monoxide free hydrogen to the anode. This need can…”
Get full text
Journal Article -
3
Preferential CO oxidation in hydrogen (PROX) on ceria-supported catalysts, Part II: Oxidation states and surface species on Pd/CeO2 under reaction conditions, suggested reaction mechanism
Published in Journal of catalysis (2006)“…The aim of the PROX reaction is to reduce the CO content of hydrogen feed to proton-exchange membrane fuel cells (PEMFCs) by selective oxidation of CO in the…”
Get full text
Journal Article -
4
Preferential CO oxidation in hydrogen (PROX) on unsupported PtSn catalyst
Published in Applied catalysis. A, General (16-01-2012)“…[Display omitted] ► Unsupported PtSn was more active catalyst in PROX than Pt black. ► Pretreatment by H 2 and by O 2–H 2 increased activity. ► PROX activity…”
Get full text
Journal Article -
5
Structural properties of an unsupported model Pt–Sn catalyst and its catalytic properties in cyclohexene transformation
Published in Applied catalysis. A, General (04-01-2011)“…Unsupported PtSn powder was prepared by direct reduction of a solution containing both H 2PtCl 6 and SnCl 4 using hydrazine as the reducing agent. The dark…”
Get full text
Journal Article -
6
Partial pressure dependent in situ spectroscopic study on the preferential CO oxidation in hydrogen (PROX) over Pt/ceria catalysts
Published in Journal of catalysis (25-07-2007)“…Platinum supported on ceria can oxidize CO in excess hydrogen selectively (PROX process). In situ DRIFTS and high-pressure ( ∼ 1 mbar ) XPS experiments were…”
Get full text
Journal Article -
7
Preparation, physical characterization and catalytic properties of unsupported Pt–Rh catalyst
Published in Journal of catalysis (10-09-2007)“…Rh was deposited on a parent platinum black catalyst by an underpotential deposition method. Mean particle size and bulk composition of this Rh–Pt sample was…”
Get full text
Journal Article -
8
Bridging the pressure and materials gap: in-depth characterisation and reaction studies of silver-catalysed acrolein hydrogenation
Published in Journal of catalysis (15-08-2005)“…The gas-phase hydrogenation of acrolein over silver was studied in a broad pressure range from ∼2 mbar to 20 bar and with various silver materials (single…”
Get full text
Journal Article -
9
Oxygen-induced activation of silica supported silver in acrolein hydrogenation
Published in Applied catalysis. A, General (15-06-2008)“…Acrolein hydrogenation has been studied over Ag/SiO 2 catalysts in a pressure range from 266 mbar to 10 bar. Oxygen pre-treatment of the catalysts enhances…”
Get full text
Journal Article -
10
XPS, EM, and Catalytic Studies of the Accumulation of Carbon on Pt Black
Published in Journal of catalysis (25-01-2001)“…Pt black samples were exposed to 2,4-hexadiene (24HD) at 603 and 693 K, alone or in the presence of excess hydrogen. The 24HD underwent C=C double-bond shift,…”
Get full text
Journal Article -
11
Characterization and catalytic study of PtGe/Al2O3 catalysts prepared by organometallic grafting
Published in Journal of catalysis (15-02-2006)Get full text
Journal Article -
12
Pt/Graphite Nanofiber Catalyst in n-Hexane Test Reaction
Published in Journal of catalysis (01-07-2000)“…Five percent Pt on a “platelet-type” graphite nanofiber was active in skeletal reactions of n-hexane at lower temperature than Pt/SiO2. The turnover…”
Get full text
Journal Article -
13
Effect of hydrogen pressure on intentional deactivation of unsupported Pt catalyst: Catalytic properties and physical characterization
Published in Applied catalysis. A, General (17-07-2006)“…Unsupported Pt black reduced by hydrazine looked like an agglomeration of elongated Pt particles, as confirmed by electron microscopy. Cyclic voltammetry…”
Get full text
Journal Article -
14
Ceria as a new support of noble metal catalysts for hydrocarbon reactions: chemisorption and catalytic studies
Published in Solid state ionics (01-05-2001)“…Metal/cerium-oxide systems were practically not studied in hydrocarbon reactions. Chemisorption properties—in temperature programmed reduction, hydrogen…”
Get full text
Journal Article -
15
Specific Behavior of Tailor-Made Pt–Ge/Al2O3 Catalysts in Transformation of Hydrocarbons
Published in Journal of catalysis (10-06-2002)“…Germanium in amounts corresponding nominally to 2 or 1/8 monolayers was added to a 1% Pt/Al2O3 catalyst by controlled surface reaction. These catalysts, noted…”
Get full text
Journal Article -
16
Removal of Carbonaceous Residues by Deuterium from Pt Catalysts
Published in Journal of catalysis (10-06-2002)“…Mixtures of hexane (nH) and hydrogen (H2) were reacted over EUROPT-1 (6.3% Pt/SiO2) and Pt black. In addition to gas-phase products, including isomers,…”
Get full text
Journal Article -
17
Intentional carbonization of Pt black: a model spectroscopic and catalytic study
Published in Catalysis today (01-02-2001)“…Pt black was exposed to trans- trans-2,4-hexadiene at two different pressures at 603 K. The surface composition and valence state of carbon upon carbonization…”
Get full text
Journal Article -
18
Alkyne hydrogenation over Pd catalysts: A new paradigm
Published in Journal of catalysis (15-08-2006)“…The hydrogenation of 1-pentyne over various palladium catalysts was studied under various conditions. In the regime of selective hydrogenation, as observed by…”
Get full text
Journal Article -
19
Preferential CO oxidation in hydrogen (PROX) on unsupported PtSn catalyst
Published in Applied catalysis. A, General (2012)Get full text
Journal Article -
20