Search Results - "Woods, Anthony D"

Reactions of Sn(NMe2)2 with MPHCy: The Effects of Alkali Metal Phosphide Coupling (Cy=Cyclohexyl; M=Li, Na, K, Rb) by Alvarez, Paula, García, Felipe, Hehn, Jörg P., Kraus, Florian, Lawson, Gavin T., Korber, Nikolaus, Mosquera, Marta E. G., McPartlin, Mary, Moncrieff, David, Pask, Christopher M., Woods, Anthony D., Wright, Dominic S.

“…The reactions of the SnII base Sn(NMe2)2 with CyPHM (Cy=cyclohexyl) produce a range of products, depending primarily on the alkali metal (M) involved. The 1:3…”
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[Cp2(OC)4Mo2(μ-PH2)(μ-H)] as a Useful Building Block toward Heterometallic Clusters Containing a Naked Phosphorus Atom by Bridgeman, Adam J, Mays, Martin J, Woods, Anthony D

“…The reactivity of the title complex [Cp2(OC)4Mo2(μ-PH2)(μ-H)] toward a variety of metal carbonyls has been investigated. In each case heterometallic clusters…”
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Selection of a Pentameric Host in the Host-Guest Complexes {[{[P(μ-NtBu)]2(μ-NH)}5]⋅I}−[Li(thf)4]+ and [{[P(μ-NtBu)]2(μ-NH)}5]⋅HBr⋅THF by García, Felipe, Goodman, Jonathan M., Kowenicki, Richard A., Kuzu, Istemi, McPartlin, Mary, Silva, María A., Riera, Lucía, Woods, Anthony D., Wright, Dominic S.

“…The structures of the host–guest complexes {[{[P(μ‐NtBu)]2(μ‐NH)}5]I}−⋅[Li(thf)4]+ [2⋅I{Li(thf)4}] and [{[P(μ‐NtBu)]2(μ‐NH)}5]⋅HBr⋅THF (2⋅HBr⋅THF) show that…”
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Quadruple Deprotonation of 2-Aminophenylphosphane with a p-Block-Metal/Alkali-Metal Base by García, Felipe, Humphrey, Simon M., Kowenicki, Richard A., McInnes, Eric J. L., Pask, Christopher M., McPartlin, Mary, Rawson, Jeremy M., Stead, Matthew L., Woods, Anthony D., Wright, Dominic S.

“…An unusual, paramagnetic SnII‐centered cage [{[Sn(L)(NMe2)Li(thf)][Sn(L)Li(thf)3]Sn}2] (see crystal structure) is generated by the treatment of…”
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Synthesis and Properties of a New Range of Mixed-Donor Alkynyl Ferrocenophanes by Woods, Anthony D, Alcalde, German, Golovko, Vladimir B, Halliwell, Catherine M, Mays, Martin J, Rawson, Jeremy M

“…The acid-catalyzed reaction of [1,1‘-Fc{Co2(CO)6(μ:η2-C⋮CCMe2OH)}2] (Fc = Fe(η5-C5H4)2) with a variety of dinucleophiles led to the formation in excellent…”
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Suggestion of a "Twist" Mechanism in the Oligomerisation of a Dimeric Phospha(III)zane: Insights into the Selection of Adamantoid and Macrocyclic Alternatives by Bashall, Alan, Doyle, Emma L., García, Felipe, Lawson, Gavin T., Linton, David J., Moncrieff, David, McPartlin, Mary, Woods, Anthony D., Wright, Dominic S.

“…The reaction of the dimeric phospha(III)zane [ClP(μ‐Npy)]2 (1) (py=2‐pyridyl) with pyNHLi (2:1 equivalents, respectively) in THF/Et3N leads to rapid formation…”
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Reactivity and Theoretical Studies of the Unusual Phosphaalkenes cis/trans-[Cp2(OC)4Mo2{μ-η1:η2-P(Ph)C(H)Me}] by Bridgeman, Adam J, Mays, Martin J, Woods, Anthony D

“…The title complexes provide rare examples of the coordination of a phosphaalkene to a binuclear transition-metal fragment, and the reactivity of these…”
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Reactions of Sn(NMe2)2 with Primary Aryl Phosphides, ArPH-:  Synthesis and Structures of the Heteroleptic Cages [{(PhP−PPh)Sn(μ-PPh)}2(Na·PMDETA)4 and [{Sn(μ3-Ppy)}3{Sn(μ3,μ1-pyP−Ppy)}3] by García, Felipe, Hopkins, Alexander D, Kowenicki, Richard A, McPartlin, Mary, Pask, Christopher M, Stead, Matthew L, Woods, Anthony D, Wright, Dominic S

“…The reaction of Sn(NMe2)2 with the primary phosphido alkali metal complex PhPHNa (1:2 equiv, respectively) in the presence of the Lewis base donor PMDETA…”
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Synthesis and Structure of [{Sn2(μ-PMes)3}K2·3THF]∞, Exhibiting Multifunctional Coordination of [Sn2(μ-PMes)3]2- Anions to K by García, Felipe, Hopkins, Alexander D, Humphrey, Simon M, McPartlin, Mary, Pask, Christopher M, Woods, Anthony D, Wright, Dominic S

“…The reaction of Sn(NMe2)2 with MesPHK (1:2) in THF gives the title compound [{Sn2(μ-PMes)3}K 2·3THF]∞ (1), having a polymeric structure in the solid state in…”
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Methyl Group Transfer from ZnMe2 to Arsenic(III), an Alternative Pathway to Deprotonation of [CyNHAs(μ-NCy)]2 by Bond, Andrew D, Hopkins, Alexander D, Rothenberger, Alexander, Wolf, Robert, Woods, Anthony D, Wright, Dominic S

“…Attempted metalation of the dimer [CyNHAs(μ-NCy)]2 (1) with ZnMe2 gives the novel complex [{MeAs(NHCy)(NCy)}ZnMe]2 (2), a reaction formally involving transfer…”
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Formation of Double Cubanes [Sn7(NR)8] in the Reactions of Pyridyl and Pyrimidinyl Amines with Sn(NMe2)2:  A Synthetic and Theoretical Study by Armstrong, David R, Benevelli, Francesca, Bond, Andrew D, Feeder, Neil, Harron, Eilis A, Hopkins, Alexander D, McPartlin, Mary, Moncrieff, David, Sáez, David, Quadrelli, Elsje A, Woods, Anthony D, Wright, Dominic S

“…In contrast to the reactions of Sn(NMe2)2 with unfunctionalized primary amines (RNH2), which yield the simple imido SnII cubanes [SnNR]4, the reactions of…”
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Reaction of [Cp2(CO)3Mo2(μ-η2-P2)(PPh2)]- with the Cumulenes 3-ClC6H4NCO, PhNCS, and CS2 and with Michael Acceptors:  Synthesis and Reactivity of [Cp2(CO)3Mo2(μ-η3-Ph2PC(H)SP2S)], a Complex Containing an Unusual CSP2S Five-Membered Ring by Davies, John E, Feeder, Neil, Mays, Martin J, Tompkin, Peter K, Woods, Anthony D

“…Deprotonation of the complex [Cp2(CO)3Mo2(μ-η2-P2)(PPh2H)] (1) yields the anion [Cp2(CO)3Mo2(μ-η2-P2)(PPh2)]- (2). Reaction of 2 with cumulenes such as…”
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Formation and decomposition of the Sb(III)/Li cage [{Sb(P-t-Bu)3}2Li6·6THF] by Bashall, Alan, García, Felipe, Lawson, Gavin T, McPartlin, Mary, Rothenberger, Alexander, Woods, Anthony D, Wright, Dominic S

“…The heterometallic Sb(III)/Li cage complex [{Sb(P-t-Bu) 3 } 2 Li 6 ·6THF] ( 1 ) is obtained by the low-temperature (<0°C) reaction of Sb(NMe 2 ) 3 with…”
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A Li10 Cage Containing the [C6H11P⋅⋅⋅-C(Ph)⋅⋅⋅-N]2− Ion: Umpolung in the Oligomerization of a Nitrile by Feeder, Neil, Lawson, Yvonne G., Raithby, Paul R., Rawson, Jeremy M., Steiner, Alexander, Wood, Jody A., Woods, Anthony D., Wright, Dominic S.

“…Two types of anion are present in the lithium aggregate [{{[C6H11PC(Ph)N]Li2}{[H(PhCN)3(C6H11P)2]Li3}(thf)3}2]⋅2 C6H5CH3⋅2 THF obtained by the addition of…”
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Reaction of Group 15 Trichlorides ECl3 with the Anion [Mo2Cp2(CO)4(μ-PH2)]−; Synthesis and Characterization of the First Complexes Featuring a Hetero μ,η2-PE ligand (E=As, Sb) by Davies, John E., Kerr, Lesley C., Mays, Martin J., Raithby, Paul R., Tompkin, Peter K., Woods, Anthony D.

“…An Me2PE tetrahedrane framework is seen in complexes 2 a–c (E=P, As, Sb), which are prepared from the appropriate trichlorides and 1 in THF. The structures of…”
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Templating and Selection in the Formation of Macrocycles Containing [{P(μ-NtBu)2}(μ-NH)]n Frameworks: Observation of Halide Ion Coordination by Bashall, Alan, Bond, Andrew D., Doyle, Emma L., García, Felipe, Kidd, Sara, Lawson, Gavin T., Parry, Mark C., McPartlin, Mary, Woods, Anthony D., Wright, Dominic S.

“…Amination of [ClP(μ‐NtBu)]2 (1) using NH3 in THF gives the cyclophospha(III)zane dimer [H2NP(μ‐NtBu)]2 (2), in good yield. 31P NMR spectroscopic studies of the…”
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Templating and selection in the formation of macrocycles containing [[P(micro-NtBu)(2)](micro-NH)](n) frameworks: observation of halide ion coordination by Bashall, Alan, Bond, Andrew D, Doyle, Emma L, García, Felipe, Kidd, Sara, Lawson, Gavin T, Parry, Mark C, McPartlin, Mary, Woods, Anthony D, Wright, Dominic S

“…Amination of [ClP(micro-NtBu)](2) (1) using NH(3) in THF gives the cyclophospha(III)zane dimer [H(2)NP(micro-NtBu)](2) (2), in good yield. (31)P NMR…”
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Thermodynamic/Kinetic Control in the Isomerization of the [{tBuNP(μ-NtBu)}2]2− Ion by Bond, Andrew D., Doyle, Emma L., García, Felipe, Kowenicki, Richard A., Moncrieff, David, McPartlin, Mary, Riera, Lucía, Woods, Anthony D., Wright, Dominic S.

“…The unique structure of [(tBuN)2PK]∞ (2) (containing [(tBuN)2P]− monoanions) is in stark contrast to the previously reported Li+ analogue…”
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Selection of a pentameric host in the host-guest complexes [[[[P(mu-NtBu)]2(mu-NH)]5].I]-[Li(thf)4]+ and [[[P(mu-NtBu)]2(mu-NH)]5].HBr.THF by García, Felipe, Goodman, Jonathan M, Kowenicki, Richard A, Kuzu, Istemi, McPartlin, Mary, Silva, María A, Riera, Lucía, Woods, Anthony D, Wright, Dominic S

“…The structures of the host-guest complexes [[[P(mu-NtBu)]2(mu-NH)]5]I]-.[Li(thf)4]+ [2.I[Li(thf)4]] and [[[P(mu-NtBu)]2(mu-NH)]5].HBr.THF (2.HBr.THF) show that…”
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thermodynamic/kinetic control in the isomerization of the [[tBuNP(mu-NtBu)]2]2- ion by Bond, Andrew D, Doyle, Emma L, García, Felipe, Kowenicki, Richard A, Moncrieff, David, McPartlin, Mary, Riera, Lucía, Woods, Anthony D, Wright, Dominic S

“…The unique structure of [(tBuN)(2)PK]( infinity ) (2) (containing [(tBuN)(2)P](-) monoanions) is in stark contrast to the previously reported Li(+) analogue…”
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