Search Results - "Wong, Henry N C"
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Chiral Hydroxytetraphenylene-Catalyzed Asymmetric Conjugate Addition of Boronic Acids to Enones
Published in Organic letters (05-07-2019)“…(S)-2,15-Br2-DHTP-catalyzed asymmetric conjugate addition of boronic acids to β-trifluoromethyl α,β-unsaturated ketones and enones was studied. The reaction…”
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2
Synthesis and Chiroptical Properties of Double-Helical (M)- and (P)‑o‑Oligophenylenes
Published in Organic letters (04-09-2015)“…All of the M and P isomers of optically pure oligophenylenes with 6, 8, 10, and 12 phenyl rings were synthesized and fully characterized. The Suzuki…”
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3
Ligand-Free Iron-Catalyzed Carbon (sp2)–Carbon (sp2) Oxidative Homo-Coupling of Alkenyllithiums
Published in Organic letters (01-02-2019)“…A new strategy was developed for the efficient synthesis of di-, tetra-, and hexa-substituted 1,3-butadienes. This one-pot procedure involves lithium–iodine…”
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4
Correction to Total Synthesis of (±)-Gracilioether F
Published in Organic letters (01-04-2016)Get full text
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5
Synthesis and Photophysical Studies of Chiral Helical Macrocyclic Scaffolds via Coordination-Driven Self-Assembly of 1,8,9,16-Tetraethynyltetraphenylene. Formation of Monometallic Platinum(II) and Dimetallic Platinum(II)−Ruthenium(II) Complexes
Published in Journal of the American Chemical Society (24-11-2010)“…This paper is concerned with the synthesis and reactions of enantiopure 1,8,9,16-tetraethynyltetraphenylene (3). We obtained 3 in 34% yield through four steps…”
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Palladium-Catalyzed Asymmetric (3 + 2) Cycloaddition of Vinyl Epoxides with Substituted Propiolates. Enantioselective Formation of 2,3,4-Trisubstituted 2,3-Dihydrofurans
Published in Organic letters (25-02-2022)“…Alkynyl esters are viable dipolarophiles for the palladium-catalyzed asymmetric (3 + 2) cycloaddition with vinyl epoxides. The chiral dihydrofurans are…”
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7
Biomimetic Total Synthesis of (±)-Pallavicinolide A
Published in Angewandte Chemie (International ed.) (01-01-2009)“…Piecing it together: The first total synthesis of naturally occurring diterpene pallavicinolide A was achieved. Notable features are highlighted by three key…”
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8
Total Syntheses of (−)-Deoxoapodine, (−)-Kopsifoline D, and (−)-Beninine
Published in Journal of organic chemistry (17-01-2020)“…The total syntheses of Aspidosperma and Kopsia alkaloids (−)-deoxoapodine, (−)-kopsifoline D, and (−)-beninine are described through a domino…”
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Chiral Rodlike Platinum Complexes, Double Helical Chains, and Potential Asymmetric Hydrogenation Ligand Based on “Linear” Building Blocks: 1,8,9,16-Tetrahydroxytetraphenylene and 1,8,9,16-Tetrakis(diphenylphosphino)tetraphenylene
Published in Journal of the American Chemical Society (06-07-2005)“…This paper is concerned with the synthesis of 1,8,9,16-tetrahydroxytetraphenylene (3a) via copper(II)-mediated oxidative coupling, its resolution to optical…”
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10
Asymmetric Darzens Reaction of Isatins with Diazoacetamides Catalyzed by Chiral BINOL–Titanium Complex
Published in Journal of organic chemistry (01-12-2017)“…An efficient catalytic asymmetric Darzens reaction of N-protected isatins with diazoacetamides using a chiral BINOL/Ti(O i Pr)4 complex as the catalyst has…”
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11
Visible-Light-Driven Difluoromethylation of Isocyanides with S‑(Difluoromethyl)diarylsulfonium Salt: Access to a Wide Variety of Difluoromethylated Phenanthridines and Isoquinolines
Published in Journal of organic chemistry (21-08-2020)“…A highly efficient approach of visible-light-driven radical difluoromethylation of isocyanides to access a wide variety of difluoromethylated phenanthridines…”
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12
Difluoromethylation of Phenols and Thiophenols with the S‑(Difluo-romethyl)sulfonium Salt: Reaction, Scope, and Mechanistic Study
Published in Journal of organic chemistry (20-12-2019)“…A facile and practical approach for the difluoromethylation of phenols and thiophenols was described. Making use of the recently developed bench-stable…”
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13
Air- and Light-Stable S‑(Difluoromethyl)sulfonium Salts: C‑Selective Electrophilic Difluoromethylation of β‑Ketoesters and Malonates
Published in Organic letters (02-11-2018)“…Air- and light-stable electrophilic difluoromethylating reagents, S-(difluoromethyl)-S-phenyl-S-(2,4,6-trialkoxyphenyl) sulfonium salts were successfully…”
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14
PtCl2‑Catalyzed Cycloisomerization of 1,8-Enynes: Synthesis of Tetrahydropyridine Species
Published in Organic letters (17-05-2019)“…The cycloisomerization of 1,8-enynes in the presence of platinum(II) chloride was developed to generate bicyclic nitrogen-containing heterocycle species via…”
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15
Iridium-catalyzed enantioselective alkynylation and kinetic resolution of alkyl allylic alcohols
Published in Chemical science (Cambridge) (30-11-2022)“…Herein, we report an efficient kinetic resolution of alkyl allylic alcohols enabled by an iridium-catalyzed enantioselective alkynylation of alkyl allylic…”
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16
Sustainable and practical formation of carbon-carbon and carbon-heteroatom bonds employing organo-alkali metal reagents
Published in Chemical science (Cambridge) (08-02-2023)“…Metal-catalysed cross-coupling reactions are amongst the most widely used methods to directly construct new bonds. In this connection, sustainable and…”
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17
Stereospecific Iron-Catalyzed Carbon(sp2)–Carbon(sp3) Cross-Coupling with Alkyllithium and Alkenyl Iodides
Published in Organic letters (19-04-2019)“…An efficient synthetic protocol involving iron-catalyzed cross-coupling reactions between organolithium compounds and alkenyl iodides as key coupling partners…”
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18
Ligand-Free Iron-Catalyzed Carbon(sp2)–Carbon(sp2) Cross-Coupling of Alkenyllithium with Vinyl Halides
Published in Journal of organic chemistry (15-06-2018)“…An efficient ligand-free iron-catalyzed cross-coupling reaction involving alkenyllithium and vinyl iodides was developed to form diene species in moderate to…”
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19
Bromine-Mediated Cross-Dehydrogenative Coupling (CDC) Reactions
Published in Bulletin of the Chemical Society of Japan (2018)“…Significant advances in the development of CDC reactions have been made in recent years. However, metal-free CDC reaction remains comparatively…”
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20
Iron-catalysed cross-coupling of organolithium compounds with organic halides
Published in Nature communications (05-02-2016)“…In past decades, catalytic cross-coupling reactions between organic halides and organometallic reagents to construct carbon–carbon bond have achieved a…”
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