Search Results - "Woltering, Steffen L."
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Molecular Knots
Published in Angewandte Chemie International Edition (04-09-2017)“…The first synthetic molecular trefoil knot was prepared in the late 1980s. However, it is only in the last few years that more complex small‐molecule knot…”
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Synthesis of Cyclo[18]carbon via Debromination of C18Br6
Published in Journal of the American Chemical Society (29-07-2020)“…Cyclo[18]carbon (C18, a molecular carbon allotrope) can be synthesized by dehalogenation of a bromocyclocarbon precursor, C18Br6, in 64% yield, by atomic…”
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A Short History of Cyclocarbons
Published in Bulletin of the Chemical Society of Japan (2021)“…The cyclocarbons constitute a family of molecular carbon allotropes consisting of rings of two-coordinate atoms. Their high reactivities make them difficult to…”
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Masked Alkyne Equivalents for the Synthesis of Mechanically Interlocked Polyynes
Published in Angewandte Chemie International Edition (08-03-2021)“…Polyyne polyrotaxanes, encapsulated cyclocarbon catenanes and other fascinating mechanically interlocked carbon‐rich architectures should become accessible if…”
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Photochemical Unmasking of Polyyne Rotaxanes
Published in Journal of the American Chemical Society (05-08-2020)“…Bulky photolabile masked alkyne equivalents (MAEs) are needed for the synthesis of polyyne polyrotaxanes, as insulated molecular wires and as stabilized forms…”
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Comment on “Coordination‐Driven Self‐Assembly of a Molecular Knot Comprising Sixteen Crossings”
Published in Angewandte Chemie International Edition (17-09-2018)“…The remarkable metalla‐knot obtained by Kim, Jung, Chi and colleagues is an 818 knot, a metalla‐knot that comprises eight crossings, not sixteen. It is the…”
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A Simple and Highly Effective Ligand System for the Copper(I)-Mediated Assembly of Rotaxanes
Published in Angewandte Chemie International Edition (08-12-2014)“…A [2]rotaxane was produced through the assembly of a picolinaldehyde, an amine, and a bipyridine macrocycle around a CuI template by imine bond formation in…”
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Braiding a molecular knot with eight crossings
Published in Science (American Association for the Advancement of Science) (13-01-2017)“…Knots may ultimately prove just as versatile and useful at the nanoscale as at the macroscale. However, the lack of synthetic routes to all but the simplest…”
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Allosteric initiation and regulation of catalysis with a molecular knot
Published in Science (American Association for the Advancement of Science) (24-06-2016)“…Molecular knots occur in DNA, proteins, and other macromolecules. However, the benefits that can potentially arise from tying molecules in knots are, for the…”
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A molecular endless (74) knot
Published in Nature chemistry (01-02-2021)“…Current strategies for the synthesis of molecular knots focus on twisting, folding and/or threading molecular building blocks. Here we report that Zn( ii ) or…”
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Quantum interference enhances the performance of single-molecule transistors
Published in Nature nanotechnology (01-07-2024)“…Quantum effects in nanoscale electronic devices promise to lead to new types of functionality not achievable using classical electronic components. However,…”
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Connections to the Electrodes Control the Transport Mechanism in Single‐Molecule Transistors
Published in Angewandte Chemie International Edition (15-04-2024)“…When designing a molecular electronic device for a specific function, it is necessary to control whether the charge‐transport mechanism is phase‐coherent…”
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13
Synthesis of Cyclo[18]carbon via Debromination of C 18 Br 6
Published in Journal of the American Chemical Society (29-07-2020)“…Cyclo[18]carbon (C , a molecular carbon allotrope) can be synthesized by dehalogenation of a bromocyclocarbon precursor, C Br , in 64% yield, by atomic…”
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14
Connections to the Electrodes Control the Transport Mechanism in Single‐Molecule Transistors
Published in Angewandte Chemie (15-04-2024)“…When designing a molecular electronic device for a specific function, it is necessary to control whether the charge‐transport mechanism is phase‐coherent…”
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Masked Alkyne Equivalents for the Synthesis of Mechanically Interlocked Polyynes
Published in Angewandte Chemie (08-03-2021)“…Polyyne polyrotaxanes, encapsulated cyclocarbon catenanes and other fascinating mechanically interlocked carbon‐rich architectures should become accessible if…”
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A scalable synthesis of 5,5′-dibromo-2,2′-bipyridine and its stepwise functionalization via Stille couplings
Published in Nature protocols (01-11-2012)“…The synthesis of 5,5′-dibromo-2,2′-bipyridine and 5-bromo-2,2′-bipyridine, useful intermediates for elaboration into more complex ligands through…”
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Comment on “Coordination‐Driven Self‐Assembly of a Molecular Knot Comprising Sixteen Crossings”
Published in Angewandte Chemie (17-09-2018)“…Der bemerkenswerte Metallaknoten, den Kim, Jung, Chi und Mitarbeiter erhalten haben, ist ein 818‐Knoten, der aus 8, nicht 16 Überkreuzungen besteht. Es ist der…”
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A Simple and Highly Effective Ligand System for the Copper(I)-Mediated Assembly of Rotaxanes
Published in Angewandte Chemie (08-12-2014)“…A [2]rotaxane was produced through the assembly of a picolinaldehyde, an amine, and a bipyridine macrocycle around a CuI template by imine bond formation in…”
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Molekulare Knoten
Published in Angewandte Chemie (04-09-2017)“…Der erste synthetische Kleeblattknoten wurde in den späten 1980er Jahren hergestellt. Kompliziertere Knotentopologien wurden jedoch erst in den letzten Jahren…”
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Metal Template Synthesis of Novel Interlocked Architectures
Published 01-01-2017“…Molecular knots form spontaneously in natural[1] and synthetic[2] polymers. However, they were not synthesised in small molecule form until the late 1980s…”
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