Search Results - "Wilson, Scott R."

Unsaturated, Mixed-Valence Diiron Dithiolate Model for the Hox State of the [FeFe] Hydrogenase by Justice, Aaron K, Rauchfuss, Thomas B, Wilson, Scott R

“…Chemists are closing in on functional and structural models for the [FeFe] hydrogenases. Oxidation of [Fe2(S2C2H4)(CO)3(PMe3)(dppv)] (dppv=cis‐1,2‐C2H2(PPh2)2)…”
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Role of the Azadithiolate Cofactor in Models for [FeFe]-Hydrogenase: Novel Structures and Catalytic Implications by Olsen, Matthew T, Rauchfuss, Thomas B, Wilson, Scott R

“…This paper summarizes studies on the redox behavior of synthetic models for the [FeFe]-hydrogenases, consisting of diiron dithiolato carbonyl complexes bearing…”
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Ferrous Carbonyl Dithiolates as Precursors to FeFe, FeCo, and FeMn Carbonyl Dithiolates by Carroll, Maria E, Chen, Jinzhu, Gray, Danielle E, Lansing, James C, Rauchfuss, Thomas B, Schilter, David, Volkers, Phillip I, Wilson, Scott R

“…Reported are complexes of the formula Fe­(dithiolate)­(CO)2(diphos) and their use to prepare homo- and heterobimetallic dithiolato derivatives. The starting…”
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Chelate Control of Diiron(I) Dithiolates Relevant to the [Fe−Fe]- Hydrogenase Active Site by Justice, Aaron K, Zampella, Giuseppe, De Gioia, Luca, Rauchfuss, Thomas B, van der Vlugt, Jarl Ivar, Wilson, Scott R

“…The reaction of Fe2(S2C2H4)(CO)6 with cis-Ph2PCHCHPPh2 (dppv) yields Fe2(S2C2H4)(CO)4(dppv), 1(CO)4, wherein the dppv ligand is chelated to a single iron…”
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Characterization of a Diferrous Terminal Hydride Mechanistically Relevant to the Fe-Only Hydrogenases by van der Vlugt, Jarl Ivar, Rauchfuss, Thomas B, Whaley, C. Matthew, Wilson, Scott R

“…Reduction of diferrous dithiolato complexes with hydride donor reagents affords the first example of the previously elusive terminal diferrous hydride,…”
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Isomerization of the hydride complexes [HFe2(SR)2(PR3)(x)(CO)(6-x)]+ (x = 2, 3, 4) relevant to the active site models for the [FeFe]-hydrogenases by Barton, Bryan E, Zampella, Giuseppe, Justice, Aaron K, De Gioia, Luca, Rauchfuss, Thomas B, Wilson, Scott R

“…The stepwise formation of bridging (mu-) hydrides of diiron dithiolates is discussed with attention on the pathway for protonation and subsequent…”
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Crystal Polymorphism of Protein GB1 Examined by Solid-State NMR Spectroscopy and X-ray Diffraction by Frericks Schmidt, Heather L, Sperling, Lindsay J, Gao, Yi Gui, Wylie, Benjamin J, Boettcher, John M, Wilson, Scott R, Rienstra, Chad M

“…The study of micro- or nanocrystalline proteins by magic-angle spinning (MAS) solid-state NMR (SSNMR) gives atomic-resolution insight into structure in cases…”
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Coordination Chemistry of a Model for the GP Cofactor in the Hmd Hydrogenase:  Hydrogen-Bonding and Hydrogen-Transfer Catalysis by Royer, Aaron M, Rauchfuss, Thomas B, Wilson, Scott R

“…Cp*M2+ complexes (M = Rh, Ir; Cp* = C5Me5) are described for 6-(carboxymethyl)-4-methyl-2-hydroxypyridine (cmhpH2), an analogue of the guanylylpyridone…”
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A Robust Microporous Zinc Porphyrin Framework Solid by Smithenry, Dennis W, Wilson, Scott R, Suslick, Kenneth S

“…A robust microporous zinc(II) metalloporphyrin framework solid has been synthesized. The proposed structural model developed from X-ray single crystal data has…”
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Coordination Networks of 3,3‘-Dicyanodiphenylacetylene and Silver(I) Salts:  Structural Diversity through Changes in Ligand Conformation and Counterion by Hirsch, Keith A, Wilson, Scott R, Moore, Jeffrey S

“…Coordination networks of 3,3‘-dicyanodiphenylacetylene (3,3‘-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described…”
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Alkali Metal-Templated Assembly of Cyanometalate “Boxes” (NEt4)3{M[CpRh(CN)3]4[Mo(CO)3]4} (M = K, Cs). Selective Binding of Cs by Klausmeyer, Kevin K, Wilson, Scott R, Rauchfuss, Thomas B

“…The box-like cages {M[Cp*Rh(CN)3]4[Mo(CO)3]4}3- form as the sole metal-containing products of the reaction of [Cp*Rh(CN)3]- and (η6-C6H3Me3)Mo(CO)3 in the…”
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Achieving unbiased predictions of national-scale groundwater redox conditions via data oversampling and statistical learning by Wilson, Scott R., Close, Murray E., Abraham, Phillip, Sarris, Theo S., Banasiak, Laura, Stenger, Roland, Hadfield, John

“…An important policy consideration for integrated land and water management is to understand the spatial distribution of nitrate attenuation in the groundwater…”
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Biasing reaction pathways with mechanical force by White, Scott R, Hickenboth, Charles R, Moore, Jeffrey S, Sottos, Nancy R, Wilson, Scott R, Baudry, Jerome

“…During the course of chemical reactions, reactant molecules need to surmount an energy barrier to allow their transformation into products. The energy needed…”
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Redox-Switched Complexation/Decomplexation of K+ and Cs+ by Molecular Cyanometalate Boxes by Boyer, Julie L, Ramesh, Maya, Yao, Haijun, Rauchfuss, Thomas B, Wilson, Scott R

“…The reaction of [N(PPh3)2][CpCo(CN)3] and [Cb*Co(NCMe)3]PF6 (Cb* = C4Me4) in the presence of K+ afforded {K⊂[CpCo(CN)3]4[Cb*Co]4}PF6, [KCo 8 ]PF6. IR, NMR,…”
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Crystal Structures of Aedes aegypti Alanine Glyoxylate Aminotransferase by Han, Qian, Robinson, Howard, Gao, Yi Gui, Vogelaar, Nancy, Wilson, Scott R., Rizzi, Menico, Li, Jianyong

“…Mosquitoes are unique in having evolved two alanine glyoxylate aminotransferases (AGTs). One is 3-hydroxykynurenine transaminase (HKT), which is primarily…”
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Quantifying River‐Groundwater Interactions of New Zealand's Gravel‐Bed Rivers: The Wairau Plain by Wöhling, Thomas, Gosses, Moritz J., Wilson, Scott R., Davidson, Peter

“…New Zealand's gravel‐bed rivers have deposited coarse, highly conductive gravel aquifers that are predominantly fed by river water. Managing their groundwater…”
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Unsaturated, Mixed‐Valence Diiron Dithiolate Model for the H ox State of the [FeFe] Hydrogenase by Justice, Aaron K., Rauchfuss, Thomas B., Wilson, Scott R.

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Radical Polymerization Initiated by Bergman Cyclization by Rule, Joseph D, Wilson, Scott R, Moore, Jeffrey S

“…The diradical generated by the Bergman cyclization of 3,4-benzocyclodec-3-ene-1,5-diyne is shown to initiate the radical polymerization of several monomers…”
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Conceptualising surface water–groundwater exchange in braided river systems by Wilson, Scott R, Hoyle, Jo, Measures, Richard, Di Ciacca, Antoine, Morgan, Leanne K, Banks, Eddie W, Robb, Linda, Wöhling, Thomas

“…Braided rivers can provide substantial recharge to regional aquifers, with flow exchange between surface water and groundwater occurring at a range of spatial…”
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Covalent surface modification of a metal-organic framework: selective surface engineering via Cu(I)-catalyzed Huisgen cycloaddition by Gadzikwa, Tendai, Lu, Guang, Stern, Charlotte L, Wilson, Scott R, Hupp, Joseph T, Nguyen, Sonbinh T

“…A Zn-cornered, mixed-ligand, metal-organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic…”
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